氧化铁的存在方式对土壤和黏土矿物胶体动电电位的影响

土壤表面带有电荷是土壤胶体的基本特征,也是土壤具有保肥能力的主要原因。可变电荷土壤由于矿物组成的特点,其表面电荷特征与恒电荷土壤有很大不同。在通常的pH条件下这类土壤中的硅酸盐矿物带负电荷,而铁、铝氧化物带正电荷,因此,可变电荷土壤中存在两类带相反电荷的胶体颗粒,两者之间存在相互作用。Qafoku和Sumner[1]发现当用很稀的CsCl溶液(0.5mmol L-1)对美国老成土进行淋溶实验时,淋出液中Cs+和Cl-的浓度在开始阶段几乎保持不变,而且较加入的淋溶液低很多,淋出液的电导率(EC)较加入的淋溶液的电导率也低得多。此现象无法用传统的离子交换理论和形成离子对模型来解释,他们提出可变电荷     

胶体悬液中白云母与铁铝氧化物表面双电层的相互作用

白云母是一种原生矿物,也是土壤中常见的层状硅酸盐矿物,其负电荷主要由四面体结构中的Al置换Si而来[1]。在通常的pH条件下,白云母带负电荷,可变电荷土壤中的铁、铝氧化物带正电荷。当白云母与铁、铝氧化物存在于同一悬液     

低分子量有机酸对可变电荷土壤吸附NO3-的影响的初步研究

在我国南方热带、亚热带地区分布有大面积的酸性红黄壤，这类土壤的一个重要特征是它们的表面既带正电荷又带负电荷，而且电荷数量随环境条件而变化。可变电荷土壤既可吸附阳离子又可吸附阴离子，而且对某些离子具有一定程度的专性吸附。研究结果表明，NO3^-是一个以电性吸附为主的阴离子，共存于体系中的阴离子如Cl^-和SO4^2-都会抑制土壤对NO3^-的吸附，     

恒电荷土壤与可变电荷土壤对Cl~-和NO_3~-吸附的差异及其机理

对 3种可变电荷土壤和 4种恒电荷土壤在不同 pH、不同浓度、不同相伴阴阳离子下混合体系中Cl-和NO3-的吸附进行了测定。结果表明 ,在Cl-和NO3- 共存体系中 ,Cl-比例增大使可变电荷土壤Na+吸附量及OH-释放量增加 ,而对恒电荷土壤影响不大。Cl-和NO3-吸附量随平衡Cl-和NO3-浓度增加而增大 ,随pH升高而减少。但恒电荷土壤在上述各种条件下对Cl-和NO3-吸附均相同 ,而可变电荷土壤对Cl-吸附量大于NO3-的吸附量 ;NO3-、Cl-的选择系数为 0.51～0.78,Cl-和NO3-的相对吸附量分别为56.9%和 43.1%。在不同相伴阳离子下 ,可变电荷土壤平衡溶液Cl-/NO3-比值均小于 1,且为Na+K+Ca2+Mg2+Fe3+;而恒电荷土壤Cl-/NO3-比值为 1左右 ,且不受阳离子类型的影响。由此认为 ,Cl-和NO3-在两类土壤中均以电性吸附为主 ,恒电荷土壤对Cl-和NO3-的亲合力及吸附机理相同 ;而可变电荷土壤对Cl-的亲合力 NO3- ,Cl-存在着专性吸附     

恒电荷土壤及可变电荷土壤与离子间相互作用的研究 Ⅱ.共存体系中Cl-的吸附特性

对 3种可变电荷土壤和 4种恒电荷土壤在陪伴阳离子分别为Na 、K 、NH 4 、Mg2 、Ba2 、Al3 和共存SO2 -4下Cl- 的吸附量进行了测定。结果表明 ,供试土壤的Cl-吸附量顺序均为AlCl3>BaCl2 和MgCl2 >KCl和NH4 Cl>NaCl,其中可变电荷土壤的差异较大。不同电解质溶液中Cl- 吸附量的顺序与土壤所带正电荷量的顺序一致。Langmuir方程的K值较小 ,且在不同介质中的差异不大。随SO2 -4浓度的增大 ,可变电荷土壤对Cl- 的吸附量减少 ,平衡液的pH值增大 ,而恒电荷土壤则变化甚微 ,说明共存的SO2 -4使可变电荷土壤的表面负电荷增加 ,但对恒电荷土壤则影响不大。这些结果说明 ,Cl- 以电性吸附的机理不因介质而变。可变电荷土壤在一价阳离子存在时 ,除土壤本身所带的正电荷外 ,还有一价阳离子吸附后产生的正电荷以及由此引起的对Cl- 的协同吸附。在二、三价阳离子存在时 ,还有Cl- 的离子对吸附 ,而恒电荷土壤在所有介质中 ,似乎总是以与Cl- 的协同吸附为主     

恒电荷土壤及可变电荷土壤与离子间相互作用的研究 Ⅰ.共存离子对NO3-吸附的影响

研究了我国典型3种可变电荷土壤和4种恒电荷土壤在陪伴阳离子分别为K+、Na+、Ca2+时和1mmolL-1KCl、K2SO4支持电解质中NO-3的吸附.结果表明,NO-3吸附量随pH的增加而减小.在添加相同浓度NO-3时,3种可变电荷土壤对NO-3的吸附量顺序为Ca(NO3)2＞KNO3＞NaNO3＞KNO3+KCl＞KNO3+K2SO4;在初始NO-3浓度0.5～5mmolL-1的范围内,吸附量随浓度变化的关系符合Langmuir等温吸附式.由此求出与NO-3吸附结合能有关的常数(K)在不同共存离子存在下数值较小且差异不大,因此认为不同陪伴阳离子和不同伴随阴离子对NO-3吸附的电性机理影响不大,只是改变了土壤表面的正电荷数量从而使吸附量发生变化.4种恒电荷土壤对NO-3的吸附量通常很小,其中在Ca(NO3)2介质中较在其他介质中稍大,最大吸附量仅为1.5mmolkg-1左右,约为可变电荷土壤的1/10,且在浓度较低时常观察到负吸附.     

土壤中水合氧化物型表面的化学区分Ⅰ.表面电荷

本文研究了氧化物对土壤、粘土和合成无定形铝硅酸盐的表面电荷的贡献.结果表明,水合氧化物型表面可进一步区分为电荷性质完全不同的两类亚表面.在所研究的样本中,氧化铁和氧化铝是带可变正电荷的亚表面,而氧化硅是带可变负电荷的亚表面.     

有机质含量对棕壤表面电荷及NH4+的吸附解吸特性的影响

对棕壤在去除有机质前后表面电荷及NH4 的吸附解吸特性进行测定,结果表明:(1)去除有机质后,土壤胶体表面正电荷量增加,可变负电荷量减少,永久负电荷量增加。这可能是由于有机质带有大量的可变负电荷,掩蔽了一部分永久负电荷点位,同时中和了一部分土壤表面正电荷所致。(2)土壤对NH4 的吸附量和解吸量的变化与土壤表面电荷数量的变化呈现良好的一致性,有机质可以增加土壤对NH4 的吸附量,并降低其对NH4 的吸附结合能。土壤去除有机质后,其对NH4 的最大吸附量下降,吸附结合能增加,解吸率降低。     

我国几种地带性土壤无机胶体的表面电荷特性

研究了用返滴定法测定我国七个不同地带土壤无机胶体的表面电荷特性。结果表明 :( 1 )返滴定法测定的供试土壤无机胶体可变电荷量随纬度升高而逐渐上升。这主要与供试土壤粘土矿物、铁铝氧化物组成及含量有关。一般来说 ,土壤层状硅酸盐粘土含量越多 ,永久负电荷量和其可变负电荷量越大 ;铁铝氧化物含量越高 ,可变负电荷量越低。( 2 )七个地带性土壤无机胶体的Qv pH曲线上在pH5左右有一峰值 ,这可能与供试土壤胶体中铁铝氧化物的ZPC及供试土样层状硅酸盐的边面Si OH基吸附H 及Al OH基离解H 有关     

可变电荷土壤中特殊化学现象及其微观机制的研究进展

综述了近年来可变电荷土壤化学研究的进展,着重总结了可变电荷土壤中的盐吸附、铁铝氧化物对土壤自然酸化的抑制作用和离子强度对离子专性吸附的影响等特殊化学现象及其微观机制的研究进展。用颗粒表面扩散层重叠导致有效电荷数量减小的原理解释了盐吸附现象和铁铝氧化物对土壤自然酸化的抑制作用。阐明了可变电荷土壤和矿物中介质离子强度影响离子专性吸附的机制,用四层吸附模型解释了离子专性吸附随离子强度增大而增加的现象,并根据胶体zeta电位随离子强度改变而变化的趋势进一步证明了离子强度增大使胶体专性吸附面上静电电位的绝对值减小,是离子专性吸附随离子强度增大而增加的主要原因。带电颗粒表面双电层结构和双电层相互作用的深入研究,有助于阐明可变电荷土壤中一些特殊化学现象的微观机理,从而进一步完善土壤化学理论。     

安阳市水保工程建管方式及存在的问题与建议

安阳市近10年来建成的水土保持工程的主要建设管理方式可分为3种,即:乡村组织治理,完成后分配给农户分散经营;乡村组织治理,由村成立专业队代表村集体管理;把小流域或荒山承包给个体或私人经济组织,由其自行治理和经营管护。3种建管方式中以后者为最优,其经济效益是分散经营管理的5倍、专业队经营管理的3.5倍。针对水保工程建设管理中存在的问题和适应农村税费改革等要求,提出了加快安阳市水保生态建设的建议。     

我国滑坡、崩塌的区域特征、成因分析及其防御

论述了我国滑坡、崩塌的区域分布特征，滑坡和崩塌的危害程度，滑坡和崩塌类型和成因分析，并且提出了灾害的防御措施，以期达到环境保护成为社会发展过程中的一个重要组成部分。     

生产建设项目水土保持“天地一体化”监管存在问题及建议

根据"天地一体化"技术在生产建设项目水土保持监管中的应用情况,对"天地一体化"技术在水土保持信息化应用中存在的防治责任范围图件不规范、合规性鉴定困难、未批先建等问题进行了归纳总结,并提出相应的建议,以期能为"天地一体化"水土保持监管工作逐步走向成熟提供参考,全面提升水土保持信息化建设水平,加快推进水土保持监管信息化进程。     

Hydroxy-Al complexes of montmorillonite and vermiculite and identification of intergrades of montmorillonite-chlorite and vermiculite-chlorite in soils

Much evidence has indicated that the occurrence of montmorillonite and vermiculite containing Al-interlayers is very common in solis, particularly acid soils. Viewed in the light of soil clay minerology, it would be required to investigate the properties of their original minerals. For the latter purpose, the Al-interlayer has been removed prior to the Mg-glycerol,K-saturation and heating tests for identification of montmorillonite and vermiculite. Its removal has been accomplished in sevsral ways; KOH plus KCl (1), NH₄F, KCl plus HCl (2), Na-citrate (3),400C de hydroxylation-NaOH (4) dissolution. Although these methods are effective for the removal of Al-interlayers, they seem drastically to affect the minerals or are time-consuming. Inthe course of the study of hydroxy-Al interlaid complexes of expanding 2:1 layer lattice clay minerals, the authors have noticed the difference between the (001) spacings of hydroxy-Al complexes of montmorillonite and vermiculite; the former exhibited the 20 A basal spacing at room temperature against the 14 A spacing of the latter. This difference might be useful for differentiating montnmorillonite-chlorite intergrades in soils.     

硒、钴单施和配施对苜蓿生长及产量的效应研究

为探讨硒、钴在提高苜蓿生长影响,在河南省沿黄滩区,开展了硒、钴单施和配施下对紫花苜蓿生长以及产量和品质影响研究。结果表明,硒、钴单施和配合基施均能够显著提高苜蓿从现蕾到开花期的净光合能力,降低呼吸消耗,提高单位叶面积干物质的生产速率,有利于苜蓿花前青干草生产和果实发育;其中,以硒570 g/hm2、钴762g/hm2配施下效果显著,青干草增产8.06%,种子千粒重可提高12.85%。单施钴和硒钴配施还能促进0—20 cm耕层苜蓿根瘤菌的生长和积累,增强苜蓿的固氮能力。说明硒钴合理基施对苜蓿青干草和优质种子生产具有很好的应用效果。     

Separation and analysis of diastereomers and enantiomers of cypermethrin and cyfluthrin by gas chromatography

Synthetic pyrethroid (SP) insecticides are of environmental significance because of their high aquatic toxicity. Due to their chirality, SP compounds contain multiple diastereomers and enantiomers. However, due to great structural similarities and lack of isomer standards, gas chromatographic (GC) analysis of SP diastereomers or enantiomers is poorly developed. In this study, we used a HP-5 column to separate the diastereomers and a beta-cyclodextrin-based enantioselective column (BGB-172) to separate the enantiomers of cypermethrin (CP) and cyfluthrin (CF). Resolved peaks were identified by comparing chromatograms of isomer-enriched CP products. Diastereomers of both CP and CF were separated on the HP-5 column. On the BGB-172 column, enantiomers of all cis diastereomers were separated, while those of trans diastereomers were not separated. The elution order appears to be regulated by configuration, a finding which may allow peak identification in the absence of isomer standards. When coupled with electron capture detection, the developed methods had low detection limits and may be used for analysis of SP diastereomers and enantiomers in environmental samples.     

铁铝氧化物和高岭石对转化酶的吸附及活性的影响

Experiments were conducted to study the influences of synthetic bayerite, non-crystalline aluminum oxide (N-AlOH), goethite, non-crystalline iron oxide (N-FeOH) and kaolinite on the adsorption, activity, kinetics and thermal stability of invertase. Adsorption of invertase on iron, aluminum oxides fitted Langmuir equation. The amount of invertase held on the minerals followed the sequence kaolinite > goethite > N-AlOH > bayerite > N-FeOH. No correlation was found between enzyme adsorption and the specific surface area of minerals examined. The differences in the surface structure of minerals and the arrangement of enzymatic molecules on mineral surfaces led to the different capacities of minerals for enzyme adsorption. The adsorption of invertase on bayerite, N-AlOH, goethite, N-FeOH and kaolinite was differently affected by pH. The order for the activity of invertase adsorbed on minerals was N-FeOH > N-AlOH > bayerite > reak goethite > kaolinite. The inhibition effect of minerals on enzyme activity was kaolinite > crystalline oxides > non-crystalline oxides. The pH optimum of iron oxide- and aluminum oxide-invertase complexes was similar to that of free enzyme (pH 4.0), whereas the pH optimum of kaolinite-invertase complex was one pH unit higher than that of free enzyme. The affinity to substrate and the maximum reaction velocity as well as the thermal stability of combined invertase were lower than those of the free enzyme.     

濂溪区水土保持区划与防治布局研究

水土保持区划可为区域水土保持规划与宏观管理、水土保持生态文明建设提供重要的参考。在《江西省水土保持区划及防治布局研究》确立的原则与方法的基础上,根据全国、全省和九江市水土保持区划划分方法,分析濂溪区各乡镇地形地貌、水土流失特点、水土流失防治及经济社会发展等的区域差异,将全区划分为城市人居环境维护区、平原农田防护水质维护区、丘陵保土生态维护区3个五级区,同时基于水土保持功能,提出了各分区的详细水土流失防治布局,为濂溪区及其他区域的水土保持规划与宏观决策,加快推进各地生态文明建设提供重要的参考和借鉴。     

Phytoavailability and toxicity of beryllium and vanadium

Greenhouse and laboratory studies were conducted to evaluate the toxic effects of Be and V on collards (Brassica oleracea, var. acephala L.). In the laboratory germination study, incremental increases in the Be concentrations of the growing medium induced a steady decline in the radicle length of seven-day-old collard seedling. Beryllium concentrations greater than or equal to 8 mg Be L^?1 totally inhibited seed germination. The presence of V in the growing medium had no effect on collard germination; however, it had a profound effect on subsequent radicle elongation. Concentrations of V less than 1 mg V L^?1 stimulated radicle elongation, while concentrations greater than or equal to 3 mg V L^?1 caused severe toxicity. In the greenhouse study, Be toxicity was observed in collards grown in a Blanton sand (Grossarenic Paleudult) received treatments greater than or equal to 150 mg Be kg ^?1 (as BeSO₄). Irrespective of treatment level, 97% of the Be taken up by the plants remained in the roots while only 3% was translocated to aboveground plant parts. Vanadium tissue concentrations and toxicity to collards varied with soil type. Additions as low as 80 mg V kg^?1 to the Blanton sand significantly reduced collard biomass while additions as high as 100 mg V kg^?1 to an Orangebury loamy sand (Typic Paleudult) had no effect on plant biomass. The differential response was attributed to greater accumulation of V by plants grown in the Blanton soil.     

中国水土保持生态环境建设现状与社会经济可持续发展对策

水土流失是中国头号生态环境问题,已成为社会经济可持续发展的制约因素。从防灾减灾的角度出发,分析了中国水土流失的现状、存在问题,总结了中国水土保持工作的成绩、经验,提出了新形势下进一步加强水土保持生态环境建设的对策。