ELEMENTAL SULFUR IMPREGNATED WITH IRON AS A FERTILIZER SOURCE FOR KENTUCKY BLUEGRASS

Elemental sulfur (S) impregnated with Fe (S-Fe) fertilizer was evaluated on Kentucky bluegrass (KBG; Poa pratensis L.) in three glasshouse studies: (1) with/without Fe as S-Fe, ferrous sulfate (FS), or iron-ethylenediamine-N,N’-bis(2-hydroxyphenylacetic acid) (Fe-EDDHA) to soil (49 kg Fe ha^?1), or foliar Fe-EDDHA (5 kg Fe ha^?1) on two cultivars; (2) 0, 49, 197, or 592 kg Fe ha^?1 of S-Fe deep mixed or surface mixed on two soils; (3) 0 or 49 kg Fe ha^?1 applied as S-Fe on four cultivars. A field study comparing 0 and 49 kg Fe ha^?1 applied as S-Fe to KBG was also conducted. Soil applied S-Fe was assimilated in shoots as efficiently as Fe-EDDHA applied to soil or foliage. Shoot Fe increased significantly with increasing S-Fe in a curvilinear response when deep mixed with soil and in a linear response when surface applied. However, no Fe source tested impacted yield or verdure in these studies.     

High soil Mn and Al,as well as low leaf P concentration,may explain for low natural rubber productivity on a tropical acid soil in Vietnam

The aim of the current study was to identify major soil and leaf factors accounting for low natural rubber (NR, Hevea brasiliensis) productivity on tropical acid Acrisols in Vietnam. Twenty NR plots were measured with NR productivity, leaf factors (N, P, K, Ca, Mg, Mn, Cu, Fe, and Zn), soil factors (pH, particle size distribution, total C, N, P, K, exchangeable K, Ca, Mg, Al, Mn, Fe, Zn, available P). Cluster analysis showed that NR productivity could be separated into three clusters with low (23.2), medium (38.2), and high (61.3 g tree^?1 harvest^?1) yield. High-yield cluster had higher leaf P concentration and soil pH, while low-yield cluster had higher leaf Mn, soil exchangeable Al, and Mn concentration. Simple and multiple linear regression analysis applied with backward elimination procedure suggested that leaf and soil toxic concentration may be responsible for low NR productivity in the study soil.     

RESPONSE OF ‘GRANNY SMITH’ APPLE TREES TO FOLIAR TITANIUM SPRAYS UNDER CONDITIONS OF LOW SOIL AVAILABILITY OF IRON,MANGANESE, AND ZINC

The aim of the study was to examine impact of foliar titanium (Ti) sprays on vegetative and reproductive response of apple (Malus domestica Borkh.) trees under conditions of low soil availability of iron (Fe), manganese (Mn), and zinc (Zn). The experiment was conducted during 2005–2006 at a Experimental Station in Isparta region, Turkey, on mature ‘Granny Smith’ apple trees/M.9, planted at a spacing of 3.5 × 1.5 m, on fine-textured soil with neutral reaction, medium status of organic matter, high amounts of available phosphorus (P), potassium (K), and magnesium (Mg), and low availability of Fe, Mn, and Zn. The trees were sprayed with Ti-ascorbate at the green and pink bud stage, petal fall, and 3, 6, and 9 weeks after full bloom, at a rate of 3 g Ti ha^?1 per spray. The efficiency of Ti sprays was compared to combined sprays of Fe, Mn, and Zn [chelated with ethylenediaminetetraacetic acid (EDTA)], applied at the same terms as Ti sprays, at rate of 36 g, 36 g and 24 g per spray, respectively. Trees unsprayed with Ti, Fe, Mn, and Zn served as the control. It was shown that summer leaf Ti concentrations of the trees untreated with Ti were high, varying from 34 to 36 mg kg^?1 dry matter. Foliar Ti sprays increased leaf status of this nutrient but they had no effect on nutrition of essential macro- and microelements, tree vigor, and fruit yield. Mean apple weight, coloring, firmness, soluble solids concentration, and titratable acidity of fruit were not also influenced by Ti sprays. Foliar sprays of Fe, Mn, and Zn improved leaf status of nitrogen (N), Mg, Fe, Mn, and Zn; leaves of the trees sprayed with those micronutrients were also greener, and contained more Fe²⁺ than those of the control plants. Combined sprays of Fe, Mn, and Zn improved tree vigor and fruit yield.     

Influence of Liming on Soil Chemical Properties and Plant Growth of Pineapple (Ananas Comusus L.Merr.) On Red Acid Soil,Lampung, Indonesia

ABSTRACT

Red acid soil is generally distributed in humid tropical areas under high rainfall. The main constraint is usually the extremely low pH of the soil due to the very intensive leaching of the bases from the soil. At the same time, however, the soluble micro elements, such as iron, are high. This can cause plant toxicity. The liming of acidic soils is normally performed to reduce the iron toxicity as the first step toward providing a balanced nutrition for cultivated plants. The objective of this study is to determine the effects of liming on the soil pH, on the decrease of iron in the soil and on the growth of the pineapple. The research was done in the Greenhouse of the Research and Development Department, PT Great Giant Pineapple, Lampung, Indonesia, from November 2015 to April 2016. The design of the experiment was arranged as a completely randomized design with seven treatments and three replications, consisting of: No dolomite (D0), dolomite 1 t ha^?1 (D1), dolomite 2 t ha^?1 (D2), dolomite 3 t ha^?1 (D3), dolomite 4 t ha^?1 (D4), dolomite 5 t ha^?1 (D5) with added Fe-EDTA and for the control treatment, no dolomite and no Fe-EDTA (C0). The results showed that an increase in the dolomite dose can increase the pH, potassium (K), calcium (Ca) and magnesium (Mg) in the soil and can decrease the iron (Fe) in the soil significantly. Increasing the pH, K, Ca and Mg and decreasing the Fe in the soil were seen to influence the growth of the pineapple. In particular, the leaf area of the pineapple plant increased considerably. The other parameters also increased, but not significantly.     

Remediation of Atrazine-contaminated Soil and Water by Nano Zerovalent Iron

Atrazine-contaminated soil may require remediation to mitigate ground and surface water contamination. We determined the effectiveness of nano zerovalent iron (nano ZVI) to dechlorinate atrazine (2-chloro-4ethylamino-6-iso-propylamino-1,3,5-triazine) in contaminated water and soil. This study determined the effects of iron sources, solution pH, Pd catalyst and presence of Fe or Al sulfate salts on the destruction of atrazine in water and soil. Our results indicate nano ZVI can be successfully used to remediate atrazine in water and soil. Aqueous solution of atrazine (30 mg l^?1) was treated with 2% (w/v) of nano ZVI and 5% (w/v) of commercial ZVI. Although, iron dose in nano ZVI treatment was less than that in commercial ZVI treatment, atrazine destruction kinetic rate (k _obs) of nano ZVI treatment (1.39 days^?1) was around seven times higher than that of commercial ZVI treatment (0.18 days^?1). Reductive dechlorination was the major process in destruction of atrazine by nano ZVI. The dechlorination product was 2-ethyl-amino-4-isopropylamino-1,3,5-triazine. Lowering the pH from 9 to 4 increased the destruction kinetic rates of atrazine by nano ZVI. Moreover, nano ZVI/Pd enhanced destruction kinetic rates of atrazine (3.36 day^?1). Pd played the important role as a catalyst during treatment of atrazine by nano ZVI. Atrazine destruction kinetic rates were greatly enhanced in both contaminated water and soil treatments by nano ZVI when sulfate salts of Fe(II), Fe(III) or Al(III) was add with the following order of removal rates: Al (III) (2.23 day^?1) > Fe (III) (2.04 day^?1) > Fe(II) (1.79 day^?1). The same results were found in atrazine-nano ZVI-soil incubation experiments.     

Effect of phosphogypsum application and bacteria co-inoculation on biochemical properties and nutrient availability to maize plants in a saline soil

Phosphogypsum (PG), which contains Ca, P and S and has an acidic effect, may be applied to manage soil constraints such as alkalinity and salinity. For increasing nutrients bioavailability, biofertilizers are commonly applied. Therefore, the aim of this study was to assess PG effect either alone or in combination with the mixed co-inoculation of plant growth promoting rhizobacteria on a saline soil. In a greenhouse pot experiment with maize (Zea mays L.), the inoculated and non-inoculated saline soils were treated with PG at 10 g kg^?1 (PG10), 30 g kg^?1 (PG30), and 50 g kg^?1 (PG50). The soil pH, electrical conductivity (EC_e), and macro-(NPK) and micronutrients (Fe, Mn, Zn, and Cu) availability to mays were examined. Applying PG reduced soil pH and co-inoculation induced significant decreases in soil EC_e. Applying PG increased significantly soil available P. Applying PG combined with co-inoculation effectively increased the soil available K. The soil available micronutrients decreased significantly with PG. However, the inoculated maize treated with PG showed significant higher dry weight (82.1–127.4%) and nutrients uptake than the control. It could be concluded that PG along with co-inoculation may be an important approach for alleviating negative effects of salinity on plant growth.     

Vegetative Growth,Yield and Leaf Mineral Composition in Strawberry (Fragaria × Ananassa DUCH. CV. Pajaro) as Influenced using Nickel Sulfate and Urea Sprays

In this study, interactions of nickel sulfate and urea sprays on vegetative growth, yield and leaf mineral contents in strawberry were investigated. Rooted Pajaro strawberry plants were potted in 3 liter pots filled with soil, leaf mold and sand (1:1:1, v/v/v). Established plants were foliar sprayed with nickel sulfate at 0, 150, 300 and 450 mg L^?1 and urea 0 and 2 g L^?1 concentrations. Results indicated that nickel (Ni; 300 mg L^?1) plus urea (2 g L^?1) significantly increased the yield and runner numbers. Nickel sulfate at the rate of 300 and 150 mg L^?1and urea (2 g L^?1) significantly increased the crown numbers. The greatest root fresh and dry weights were obtained from untreated plants. Urea at 2 g L^?1 without nickel significantly increased shoot fresh and dry weights. Nickel at 450 mg L^?1 without urea significantly increased Ni concentration in leaves. Overall, nickel sulfate at 150 and 300 mg L^?1 along with urea at 2 g L^?1 were the best treatments.     

Temporal variations of crop residue effects on soil N transformation depend on soil properties as well as residue qualities

Purple soils (Eutric Regosols) are widely distributed in humid subtropical Southwest China. They are characterized by high nitrification activities, with risks of severe NO₃^? leaching. Incorporation of crop residues is considered an effective method to reduce NO₃^? loss. In the present study, we compared the effects of alfalfa, rice straw, and sugarcane bagasse on gross N transformation turnover in a purple soil (purple soil, pH 7.62) compared with those in an acid soil (acid soil, pH 5.26), at 12 h, 3 months, and 6 months after residue incorporation. The gross N transformation rates were determined by ¹⁵N tracing. All tested crop residues stimulated the gross N mineralization rates, but reduced the net mineralization rates in both soils at 12 h after residue incorporation; however, the extent of the effect varied with the crop residue qualities, with rice straw having the strongest effects. Crop residues reduced net nitrification rates by depressing gross autotrophic nitrification rates and stimulating NO₃^? immobilization rates in the purple soil, particularly after rice straw incorporation (net nitrification rate decreased from 16.72 mg N kg^?1 d^?1 in the control to ??29.42 mg N kg^?1 d^?1 at 12 h of residue incorporation); however, crop residues did not affect the gross autotrophic nitrification rates in the acid soil. Crop residue effects subsided almost completely within 6 months, with sugarcane bagasse showing the longest lasting effects. The results indicated that crop residues affected the N transformation rates in a temporal manner, dependent on soil properties and residue qualities.     

Study of Heavy Metal Accumulation and Residual Toxicity in Soil Saturated with Phosphate Processing Wastewater

The effects of phosphate processing wastewater (PPWW) on heavy metal accumulation in a Mediterranean soil (Tunisia, North Africa) were investigated. Moreover, the residual toxicities of PPWW-irrigated soils extracts were assessed. Results showed that heavy metal accumulation was significantly higher in PPWW-irrigated soil extracts than in control soil. The heavy metal accumulation increased over time in treated soil samples and their average values followed the following order: Iron (Fe 252.72 mg l^?1) > Zinc (Zn 152.95 mg l^?1) > Lead (Pb 128.35 mg l^?1) > Copper (Cu 116.82 mg l^?1) > Cadmium (Cd 58.03 mg l^?1). The residual microtoxicity and phytotoxicity of the various treated soil samples extracts were evaluated by monitoring the bioluminescence inhibition (BI %) of Vibrio ficheri and the measurement of the germination indexes (GI %) of Lepidium sativum and Medicago sativa seeds. The results showed an important increase of residual toxicities of PPWW-treated soil extracts over time.     

Fulvic acid in foliar spray is more effective than humic acid via soil in improving coffee seedlings growth

ABSTRACT

Humic (HA) and fulvic (FA) acids improve the nutrient availability and uptake by plants but some aspects of their agronomic use still need to be clarified. The effects of HA soil application and FA foliar application on the growth, Zn and B uptake by coffee seedlings were evaluated. HA was added to an Oxisol at concentrations 0, 10, 25, 50, 75 and 100 mg kg^?1 (C-HA), in both limed (pH 6.2) and overlimed (pH 7.2) conditions. FA (0, 0.2, 0.5 and 1 g L^?1 C-FA) was applied to coffee leaves in three different application modes (M): with 0.3% Zn and 0.6% B supplied via foliar (M₁), 0.6% B and 1.2% Zn supplied via foliar (M₂) and 1.2 mg kg^?1 B and 6 mg kg^?1 Zn supplied via soil (M₃). HA addition in soil significantly (p < 0.05) reduced leaf B and Zn accumulation and coffee growth in both pH conditions. In the M₁ and M₂, FA application significantly (p < 0.05) increased the shoot growth at 0.59 and 0.45 g L^?1 and B accumulation at 0.96 and 0.45 g L^?1 C-FA. Foliar application of C-FA, instead soil application of C-HA, is a suitable practice to improve coffee seedlings growth and nutrition on Oxisol.     

Soybean Growth on Calcareous Soil as Affected by Three Iron Sources

Abstract

Iron (Fe) chlorosis is a common symptom in many soybean (Glycine max L. Merr.) producing areas throughout the United States. On the Blackland soils found in northeast Texas, Fe chlorosis occasionally appears during vegetative growth, but often abates by the time plants flower. However, it is not clear whether preplant additions of Fe will enhance soybean growth or yield on this soil or whether different sources of Fe give different responses. In a greenhouse study, soil from a pH 8.4 Houston Black clay (fine, smectitic, thermic Udic Haplusterts), with a DTPA‐extractable concentration of 11.7 mg Fe kg^?1, was treated with FeSO₄ (0, 3, 10, 30, and 100 ppm Fe), sodium ferric diethylenetriamine pentaacetate (FeDTPA) (0, 0.3, 1.0, 3, and 10 ppm Fe) or sodium ferric ethylenediamine‐di (o‐hydroxyphenylacetate) (FeEDDHA) (0, 0.3, 1.0, 3, and 10 ppm Fe). Pot size was 19 L and soil dry mass was 10 kg. Soybean (cv. Hutcheson) seed were planted in November 2000 and seedlings were thinned to three per pot at the first true leaf stage. The third uppermost fully expanded leaf of each plant was harvested at growth stage R3 for nutrient analysis. Between 20 and 100 days after planting, six nondestructive leaf chlorophyll readings were obtained from the third uppermost fully expanded leaf. Entire plants were harvested at R6 (mid podfill) for nutrient and biomass yield determination. Leaf blade Fe concentration ranged from 79 to 87 mg kg^?1 in the untreated check plants to a high of 109 mg kg^?1 for the 10 ppm FeDTPA‐Fe treatment, all of which were greater than the acknowledged critical level of 60 mg kg^?1. No visible Fe‐deficiency symptoms appeared during the study. Chlorophyll (SPAD 502) values during the R3 to R5 growth stages were greater for all of the FeSO₄ treatments than for the 0 ppm treatment. The 10 ppm FeDTPA‐Fe treatment and the 3 ppm FeEDDHA‐Fe treatment exhibited higher leaf chlorophyll readings than the untreated checks during the R3 to R5 growth stage. The average seed yield from the 12 Fe fertilized treatments at growth stage R6 was only 12% greater (not significant) than the untreated check. Total biomass (root plus shoot) was not affected by the treatments. There was no evidence that the higher rates of Fe caused reduced growth. Overall, our results do not suggest that soil‐applied Fe will consistently stimulate soybean growth or yield on this soil, at least when DTPA‐extractable soil Fe is at 12 mg kg^?1 or higher. However, because of the trends for increased seed yield in some of the Fe treatments, field studies using soil‐ and/or foliar‐applied Fe are warranted.     

Determination of unsaturated soil hydraulic properties at different applied tensions and water qualities

Irrigation with low-quality water may change soil hydraulic properties due to excessive electrical conductivity (EC_w) and sodium adsorption ratio (SAR_w). Field experiments were conducted to determine the effects of water quality (EC_w of 0.5–20 dS m^?1 and SAR_w of 0.5–40 mol^0.5 l^?0.5) on the hydraulic properties of a sandy clay loam soil (containing ～421 g gravel kg^?1 soil) at applied tensions of 0–0.2 m. The mean unsaturated hydraulic conductivity [K(ψ)], sorptive number (α) and sorptivity coefficient (S) varied with change in EC_w and SAR_w as quadratic or power equations, whereas macroscopic capillary length, λ, varied as quadratic or logarithmic equations. The maximum value of K(ψ) was obtained with a EC_w/SAR_w of 10 dS m^?1/20 mol^0.5 l^?0.5 at tensions of 0.2 and 0.15 m, and with 10 dS m^?1/10 mol^0.5 l^?0.5 at other tensions. Changes in K(ψ) due to the application of EC_w and SAR_w decreased as applied tension increased. Analysis indicated that 13.7 and 86.3% of water flow corresponded to soil pore diameters <1.5 and >1.5 μm, respectively, confirming that macropores are dominant in the studied soil. The findings indicated that use of saline waters with an EC of <10 dS m^?1 can improve soil hydraulic properties in such soils. Irrigation waters with SAR_w < 20 mol^0.5 l^?0.5 may not adversely affect hydraulic attributes at early time; although higher SAR_w may negatively affect them.     

Effects of polymeric slow release fertilizer on Chinese cabbage growth and soil nutrients

One pot experiment was conducted to study the effects of a new polymeric slow release fertilizer (PRF) on Chinese cabbage growth and soil nutrients. The experiment comprised three kinds of fertilizer (common compound fertilizer, 21% and 45% solubility of PRF in 25°C water, all fertilizers with N:P₂O₅:K₂O = 10:5.7:20) and three fertilizer levels (0, 21.6 and 43.2 g m^?2). Results showed that the high water-soluble PRFs (PRFHH and PRFHL) fit nutrient requirements of Chinese cabbage, and the high fertilization level significantly increased yield and improved quality of Chinese cabbage. Although the PRFHL treatment at 21.6 g fertilizer m^?2 had one-half less supplied nutrient than that of common compound fertilizer treatment (43.2 g fertilizer m^?2), the yield of Chinese cabbage with PRFHH and PRFHL was 8.0% more. The soluble sugar, vitamin C and leaf chlorophyll contents of Chinese cabbage can be effectively improved with PRFHH (43.2 g m^?2), PRFHL (21.6 g m^?2) and PRFLH (low water-soluble PRF, 43.2 g m^?2). The PRF treatment reduced the nitrate content and improved soil capacity of supplying nutrient effectively, and there were no changes in values of pH and electrical conductivity of soil.     

RESPONSE OF ‘BURLAT’ SWEET CHERRY TREES TO POSTHARVEST SPRAYS OF NITROGEN,BORON AND ZINC

The aim of the study was to examine effects of postharvest sprays of nitrogen (N), boron (B), and zinc (Zn) on reproductive response of sweet cherry (Prunus avium L.) trees, fruit quality and plant nutrition. The experiment was conducted during 2007–2009 in central Poland on mature ‘Burlat’ sweet cherry trees/F12, grown on a coarse-textured soil with low level of organic matter, and optimal soil reaction. Soil status of phosphorus (P), potassium (K), magnesium (Mg), calcium (Ca), iron (Fe), manganese (Mn), Zn and copper (Cu) was optimal, whereas B – low. Sweet cherry trees were sprayed with boric acid-B, ethylenediaminetetraacetic acid (EDTA)-Zn, and urea-N at 30–40 d prior to initiation of leaf fall according to following schema: i) spray of N at a rate of 23 kg ha^?1; ii) spray of B and Zn at a dose of 1.1 kg ha^?1 and 0.5 kg ha^?1, respectively; and iii) spray of N, B and Zn at the same rates as in the above spray combinations. The trees sprayed with water served as the control. The results showed that fall spray treatments had no influence on cold damage of flower buds, plant N status and soluble solids concentration in fruit. Postharvest spray of N and combined spray of N, B and Zn injured leaves in the fall but did not cause defoliation. Sprays of B and Zn with or without N increased status of Zn and B in fall leaves, and B in flowers and midsummer leaves. Those sprays also improved fruit set and yield. In one out of two years of the study, fall sprays of N with or without B and Zn decreased mean fruit weight. The above results indicate that only leaf-applied B in the fall improved reproductive response of sweet cherry trees. It is concluded that under conditions of B shortage in a soil and/or plant tissues, postharvest B sprays can be recommended in sweet cherry orchards to improve reproductive growth of the trees.     

Predicting potassium fertilizer requirement using exchange isotherm approach in relation to soil characteristics

Determining potassium (K) fertilizer requirement using sorption isotherms is considered more accurate than conventional soil K tests. A total of 59 surface soil samples were used to establish K exchange isotherm. To evaluate K requirement sorption test, a glasshouse experiment using perennial ryegrass (Lolium perenne, cv. Roper) was carried out on 10 soil samples. The experiment was laid out as a completely randomized design with four replications and four K levels (K₀, K₂₀, K₄₀, K₈₀). Concentrations of K in solution established by adding K in the pots estimated from the sorption curve ranged from 20 to 80 mg K l^?1 including check treatment (no K). Dry matter yield of ryegrass in most soils approached maximum as adjusted K levels were increased to 20 mg K l^?1. The amounts of K required to bring the soils to 20 mg l^?1 in soil solution varied among soils and ranged from 99 to 399 mg kg^?1, on average 205 mg kg^?1 soil. It was found that a useful regression model for the prediction of standard K requirement (K₂₀) included the combination of plant available K extracted by NH₄OAc (Av-K) and clay content: K₂₀ = ?41 ? 0.63 Av-K + 9.0 Clay (R² = 0.61, p < 0.001, n = 59).     

Effects of organic fertilizers on yam productivity and some soil properties of a nutrient-depleted tropical Alfisol

Field experiments were conducted at Owo, southwest Nigeria to select organic fertilizer treatments most suitable for sustaining high soil fertility and yam productivity on a nutrient-depleted tropical Alfisol. Eight organic fertilizer treatments were applied at 20 t ha^?1 with a reference treatment inorganic fertilizer (NPK 15–15–15) at 400 kg ha^?1 and natural soil fertility (control), laid out in a randomized complete block design with three replications. Results showed that organic fertilizers significantly increased (p = 0.05) tuber weight and growth of yam, soil and leaf N, P, K, Ca and Mg, soil pH and organic C concentrations compared with the NSF (control). The oil palm bunch ash + poultry manure treatment increased tuber weight, vine length, number of leaves and leaf area of yam by 66, 25, 21 and 52%, respectively, compared with inorganic fertilizer (NPK) and 37, 22, 19 and 44%, respectively, compared with poultry manure alone. Sole or mixed forms of organic fertilizers showed significant improvement in soil physical conditions compared with IF (NPK) and NSF (control). Synergistic use of oil palm bunch ash + poultry manure at 10 t ha^?1 each was most effective for sustainable management of soils and for improving agronomic productivity of yam.     

SOIL ALKALINITY. II THE EFFECTS OF Na2CO3 ON IRON AND MANGANESE SUPPLY TO TOMATOES

Sodium carbonate added to nutrient solution in sand culture depressed the growth of tomatoes both by the influence of high pH and HCO₃^? causing chlorosis and by the effect of Na⁺. Foliar sprays of iron and manganese removed chlorosis and increased growth but did not remove the effect of Na. In a sandy soil Na₂CO₃ did not cause chlorosis but Na⁺ depressed yield. Chelated Fe and Mn in the soil solutions (up to 7.3 × 10^?4 M Fe and 2.6 × 10^?5 M Mn at pH 9.0) were sufficient to supply the crop needs as shown by a second sand culture experiment where plants were fed with nutrient solution plus extracted soil solution.     

Effects of soil pH and salt on N2O production in adjacent forest and grassland soils in central Alberta, Canada

Purpose

The effects of soil pH manipulation and KCl addition on N₂O production in adjacent forest and grassland soils in central Alberta were studied in a 16-day laboratory incubation experiment.

Materials and methods

The soils were subjected to four pH and two salt treatments: CK (control)—no addition of acid or alkali solution (pH 4.50 and 4.48 for the forest and grassland soils, respectively; same below); HCl—addition of HCl solution to lower soil pH (3.95 and 3.75); L-KOH and H-KOH—addition of 6 mL of 0.2 (5.36 and 5.57) and 0.4 (6.41 and 6.72)?mol?L^?1 KOH solution, respectively, to increase soil pH to two different levels. In order to differentiate between the effect of a change in pH and of changed salt concentrations on N₂O production, 6 mL of 0.2 (L-KCl) (4.56 and 4.41) or 0.4 mol?L^?1 (H-KCl) (4.59 and 4.42) KCl solutions were also applied as treatments to create two levels of salt application rates.

Results and discussion

Increasing pH promoted gross nitrification and cumulative N₂O production in both soils, particularly in the forest soil. However, cumulative N₂O production decreased in the forest soil but increased in the grassland soil when pH decreased. Cumulative N₂O production in the grassland soil was 36 times higher in the L-KCl treatment (1,442 μg?N?kg^?1) than in the CK (40 μg?N?kg^?1), whereas the H-KCl treatment reduced cumulative N₂O production. In contrast, in the forest soil, both KCl treatments reduced cumulative N₂O production.

Conclusions

(1) The most important factor to increase N₂O production in this study was increasing soil pH, suggesting that careful soil pH management could be used as a tool to control soil N₂O production; (2) salt effect was also involved in affecting N₂O production.     

Effect of sulphur on biochemical parameters of rapeseed (Brassica campestris L.) in grey terrace soil

An experiment was conducted to study the biochemical response of rapeseed (Brassica campestris L.) to sulphur (S) fertilization at grey terrace soil. There were five treatments: S₀ (control), S₁ (20 kg S ha^?1), S₂ (40 kg S ha^?1), S₃ (60 kg S ha^?1) and S₄ (80 kg S ha^?1). Chlorophyll content in the leaf was determined at 30, 40, 50 and 60 days after emergence (DAE). The biochemical properties were found responsive to S. The highest chlorophyll content of mustard leaves was found in 60 kg S ha^?1 at 50 DAE. The same treatment also showed the maximum N content in the leaves at 45 DAE. The highest oil content was recorded in 60 kg S ha^?1. Other chemical characters such as acid value, peroxide and saponification values were lowest in 60 kg S ha^?1 while iodine value was found highest in the same S level. Non-essential fatty acids such as palmitic, stearic and erucic acid were increased in the rapeseed with decrease in S level, whereas essential fatty acids were maximum in 60 kg S ha^?1. Therefore, 60 kg S ha^?1 can be recommended to produce quality rapeseed in grey terrace soil of Bangladesh.     

EFFECTIVENESS OF DIFFERENT FOLIAR IRON APPLICATIONS TO CONTROL IRON CHLOROSIS IN ORANGE TREES GROWN ON A CALCAREOUS SOIL

The effectiveness on controlling Fe chlorosis in orange trees grown on calcareous soils was tested. The treatments were Fe(II) sulfate (500 mg Fe L^?1), sulfuric acid (0.5 mM H₂SO₄), Fe(III)-chelate (Hampiron 654 GS, 120 mg Fe L^?1) and distilled water as a control. A non-ionic wetting agent was used in all treatments. The use of frequent foliar sprays alleviated Fe chlorosis in orange trees. Sprays of Fe(II) sulfate increased the concentrations of chlorophyll, Fe and zinc in leaves and improved fruit size and quality compared to fruits of control trees. Sprays of Fe(III)-chelate also increased leaf chlorophyll and Fe concentrations and improved fruit quality, but did not increase fruit size. Sprays of sulfuric acid alone slightly increased leaf chlorophyll and Fe concentrations, without improving fruit size and quality. These results suggest that foliar sprays with Fe could help to avoid yield and quality losses caused by Fe chlorosis in citrus orchards. Furthermore, these treatments could be done with relatively cheap materials such as solutions containing Fe(II) sulfate.