EFFECT OF LONG-TERM SEWAGE SLUDGE APPLICATION ON THE DISTRIBUTION OF NUTRIENTS IN MAIZE (ZEA MAYS L.)

The distribution of the nutrients nitrogen (N), phosphorus (P), potassium (K), calcium (Ca), magnesium (Mg), and iron (Fe) in maize (Zea mays L.) was studied in a long-term sewage sludge field application in an acid coarse sandy soil at Bordeaux, France. Sewage sludge had been applied since 1974 at 100 t (dry weight) ha^?1 per 2 years (SS 100) in plots cultivated annually with maize. Treatment with farmyard manure (FYM) at 10 t (dry weight) ha^?1 per year and mineral fertilization served as control. Five plants per treatment were investigated at six different growth stages. The plants were separated into their different organs and the distribution of nutrients was determined in up to 12 different plant parts. Sludge application did not significantly influence the nutrient partitioning in maize, but improved slightly the plants' nutrient status compared with the FYM treatment. Grain yield was similar for both treatments. The values for N, P, K, Ca, Mg and Fe content in sludge-treated plants were in the recommended range for optimal growth. Thus, sewage sludge would be a valuable source for maize nutrition even after long-term application, if the critically high copper (Cu) and zinc (Zn) concentrations, previously reported in these sludge-amended plants, could be avoided by the use of sludge low in these elements.     

Effect of sewage sludge and its biochar on chemical properties of two calcareous soils and maize shoot yield

Little information is available regarding the effect of sewage sludge biochar on soil properties and crop yield. Thus, our objective was to evaluate the effect of sewage sludge (S) and its biochar (B) on maize shoot yield, nutrients and heavy metals uptake in two calcareous soils. The amendments were applied at the rates of 0, 10, 20 and 40 Mg ha^?1. Moreover, NK treatment was included to compare the effects of S and B with conventional fertilization. At harvest time, plant shoots and soil samples were collected for yield, nutrients uptake and chemical analyses. The highest shoot dry matter was obtained in the S treatment. The B application in the clay loam and loam soils resulted in 5.2% increment and 17.7% decrement of shoot dry matter relative to the control, respectively. Shoot dry matter in the NK treatment was significantly higher than in the control. B application decreased Fe, Zn, Mn, Cu and Pb uptake by maize shoot. DTPA-extractable Pb in B-amended soils was lower than in control, while an inverse trend was obtained for available Fe, Zn, Mn and Cu. Biochar application at the rate of 7.3 Mg ha^?1 might be suggested for maize cultivation in clay loam soils.     

Phytoavailability of Some Micronutrients (Zn and Cu), Heavy Metals (Pb,Cd), and Yield of Rice Affected by Sewage Sludge Perennial Application

A study was conducted as a split-plot arrangement based on a randomized complete block design with three replications to test sewage sludge (SS) influence on yield and phytoavailability of lead (Pb), cadmium (Cd), zinc (Zn), and copper (Cu) by rice. The results indicated that fertilizer (main factor) and application periods (subfactor) affected studied traits. Three years of application of 40 ton ha^?1 SS + 50% chemical fertilizer (CF) gave the greatest paddy yield. The greatest Cu uptake by grain (10.38 ppm) occurred with 3 years application of 20 ton ha^?1 SS. With application of 40 ton ha^?1 SS + 50% CF, the greatest contents of Cd in root and Pb in shoots were recorded. The greatest accumulations of Cd in shoot and Zn in grain (30.56 and 25.81 ppm, respectively) were determined with the 20 ton ha^?1 SS treatment, as well. The greatest concentrations of Pb and Cd in grain (102.2 and 14.78 ppm, respectively) and Pb in root (552.2 ppm) were obtained with 3 years of application of 40 ton ha^?1 SS + 50% CF.     

Effects of controlled-release urea combined with conventional urea on nitrogen uptake,root yield,and quality of Platycodon grandiflorum

Field experiments were conducted with four nitrogen fertilizer treatments to study the effects of controlled-release urea combined with conventional urea on the nitrogen uptake, root yield, and contents of protein, soluble sugar, saponin, zinc (Zn), iron (Fe), magnesium (Mg), and copper (Cu) in Platycodon grandiflorum. Field experiments were conducted with four nitrogen (N) fertilizer treatments: no N fertilization; conventional urea with N rate of 175 kg N ha^?1; conventional urea with N rate of 160 kg N ha^?1; controlled-release urea combined with conventional urea with N rate of 160 kg N ha^?1; controlled-release urea combined with conventional urea with N rate of 135 kg N ha^?1. The results showed that nitrogen application significantly increased the yield of P. grandiflorum compared with the control. Treatment with controlled-release urea combined with conventional urea at 160 kg N ha^?1 provided the highest yield of 7329.58 kg ha^?1. Nitrogen application also increased the contents of soluble sugar, total saponin, protein, Zn, Fe, and Mg but decreased Cu content. Protein, saponin, and Zn contents were significantly higher, but Cu content was lower in P. grandiflorum fertilized with controlled-release urea combined with conventional urea than those fertilized with conventional urea alone. The combination of controlled-release urea with conventional urea at 160 kg N ha^?1 was the optimal treatment under the experimental condition investigated in this study.     

Long-term changes in soil and plant metal concentrations in an acidic dredge disposal site receiving sewage sludge

A long-term experiment was conducted to determine the distribution of sludge-borne metals applied to a revegetated acidic dredge spoil disposal site. The initial soil was infertile and highly acidic (pH 2.4). Sewage sludge and lime were applied in 1974 at the rates of 100 and 23 mt ha^?1, respectively, and tilled into the soil to a depth of 20 cm. In 1974 an adjacent site was also revegetated with topsoil and lime but without sludge. Soil and plants were sampled 2, 4 and 16 yr following seeding. After 16 yr the total and DTPA-extractable Cu, Zn, Cr, Pb, Ni and Cd decreased in soils to nearly the levels of the control soils. Concentrations of metals in plants also decreased. Decreases in tissue concentrations ranged from 40 to 70% for Cu, Cr, Pb, Ni and Cd and up to 90% for Zn. The results showed that a single 100 mt ha^?1 application of sewage sludge containing high concentrations of metals was a cost-effective method for improving plant growing conditions on highly acidic soils.

     

Nitrogen fertilization does not affect micronutrient uptake in grain maize (Zea mays L.)

Abstract

Due to continuous single nitrogen fertilization, we hypothesized a built-up deficiency of micronutrients in crops that would limit plant growth and crop quality. In 2-year field experiments using urea-N fertilized grain maize (Zea mays L.), hybrid KWS 2376 at 0, 120 and 240 kg N ha^?1 crop uptake of Zn, Mn, Cu and Fe was studied at DC 32, DC 61 and in the grain harvested. Micronutrient contents at DC 32 stage – 1st node (aboveground phytomass) and DC 61 – flowering (ear leaf) were all at levels indicative of adequate micronutrient supply to the crop. At both sampling occasions the Fe:Zn and Fe:Mn ratios were adequate implying that Fe did not inhibit the uptake of Zn and Mn. The application of nitrogen increased the Fe content at the 1st sampling in both years; in the second year the same was also the case for the Zn content. Nitrogen nutrition increased the contents of Mn and Fe at the 2nd sampling only in year 2; in the other treatments no changes were observed in the micronutrient contents. Micronutrient correlations in the grain were discovered between Zn and Mn contents and between Fe and Mn contents. In the second year the highest N-rate significantly increased the Fe and Zn content of the grain compared with the lower rates of nitrogen fertilization. Grain yields were not affected by the rate of nitrogen and ranged between 13.65 and 14.34 t ha^?1 (1st year) and between 13.68 and 14.18 t ha^?1 (2nd year). Nitrogen fertilization did not reduce the content of micronutrients in the plant or grain of maize. It is evident that the continuous single use of N fertilization so far has not resulted in a micronutrient deficiency of the plants limiting the nutrient density of the grain or reducing its quality.     

Yield response of crops amended with sewage sludge in the field is more affected by sludge properties than by final soil metal concentration

Adverse effects on crop yield or quality have been reported in sewage‐sludge treated soils at soil total metal concentrations below those of the current EU directives. A field trial was set up in Belgium (2002–2004) to assess crop response to the application of sewage sludge below these soil thresholds but with sludge metal concentrations either above (high‐metal) or below (low‐metal) sludge metal limits. Two lime‐stabilized and two raw, dewatered sludges were applied annually at rates of 10, 25 and 50 t dry matter (dm) ha^?1 for 3 years with four rates of N‐fertilizer as a reference. Final soil metal concentrations increased to maximums of 1.6 mg Cd kg^?1 and 225 mg Zn kg^?1 through sludge applications. Maize yield was marginally affected by treatments in year 1, whereas wheat and barley grain yields in subsequent years increased up to threefold with increasing sludge or fertilizer rates and were mainly explained by grain‐N. However, the grain yield of winter wheat in year 2 was reduced by about 14% in lime‐stabilized high‐metal sludge treatments compared with wheat receiving N‐fertilizer at equivalent grain‐N. Wheat grain and straw analysis showed no nutrient deficiencies but Zn concentrations in grain and straw were greater than in N‐fertilizer and lime‐stabilized, low‐metal sludge treatments, suggesting Zn toxicity. Sludge properties other than Cd concentration (e.g. electrical conductivity) affected crop Cd in the first year (maize), whereas significant correlations between Cd application and wheat grain Cd were found in the second year. Wheat grain Cd concentrations reached the international trade guideline of 0.1 mg Cd kg^?1 fresh weight in the plots amended with lime‐treated, high‐metal sludge even though soil Cd remained below EU limits. In the third year, barley grain Cd remained largely below EU limits. We discuss the possibility that sludge properties rather than soil total metal concentrations are related to effects on crops in the initial years after sludge applications. In none of the 3 years were any adverse effects on crops found for sludge meeting current EU regulations.     

Influence of compost/sludge application on sugarcane yield and nitrogen requirement on a sand soil

Mineral soils in southern Florida are very low in organic matter content and most of the nitrogen (N) for sugarcane (Saccharum spp.) must be supplied in split fertilizer applications. Information is needed regarding how the interaction of organic amendments and fertilizer N influences sugarcane yields. A field study on a sand soil (Alfisol) was established to determine (1) potential sugarcane yield benefits of a compost/sludge amendment, and (2) the influence of the amendment on N fertilizer requirement. A split-plot Latin square design was used with five N rates (main plots) and presence or absence of compost/sludge broadcast at 113 m³ ha^?1 (subplots). Annual N rates were 0, 67, 134, 202, and 269 kg N ha^?1. Compost/sludge application increased cumulative t sucrose ha^?1 by 36% averaged across N rates. The amendment also lowered annual N requirement by an average of 38%, but maintenance applications of compost/sludge will be required every four years.     

Biochar from Different Carbonaceous Waste Materials: Ecotoxicity and Effectiveness in the Sorption of Metal(loid)s

In this study, biochar produced by pyrolysis of urban pruning wood (Bpw) and sewage sludge (Bss) were characterized and investigated as adsorbents for the removal of Cu(II), Pb(II), Zn(II), and As(V) from contaminated solutions. Both types of biochars showed different physical-chemical properties and metal(loid) content. In Bss, Cu, Zn, and Pb concentrations exceeded the upper limit of the common ranges in soils. However, when they were tested for their effect on soil invertebrates, neither of the biochar was expected to exert negative effects as long as the dose applied as an amendment was ≤?4.8 t ha^?1. For an assessment of the effectiveness of biochar in the immobilization of metal(loid)s, three contaminated solutions with acidic pH and different pollutant concentrations were added to both types of biochar. Precipitation as oxy-hydroxides and the formation of complexes with active functional groups of the organic matter were the main mechanisms of metal(loid) fixation by the biochar, with increased precipitation and a rising pH. Both types of biochar were effective at immobilizing Pb and Cu, while Zn showed less effectiveness in this regard and As the least. The high P content of the biochar from sewage sludge favored Pb fixation, presumably forming complexes with phosphates, while competition between phosphate and arsenate ions decreased As adsorption by Fe compounds. The metal(loid)s immobilized by biochar from urban pruning wood were more bioavailable than those fixed by biochar from sewage sludge.     

市政污泥直接施用对玉米生长和品质的影响

[目的]研究市政污泥施用后对土壤和作物生长与品质的影响,为市政污泥的直接土地利用提供科学依据。[方法]以玉米为试验材料,利用田间试验研究了污泥不同的施用方式(沟施、撒施、表土下20 cm施用)和施用量(30,90,200 t/hm~2)对玉米生长和品质以及土壤重金属含量的影响。[结果]适量的污泥对玉米个体的生长有促进作用,施用量为30 t/hm~2时株高、单株生物量、叶片叶绿素含量、籽粒蛋白质含量均显著高于对照。表土下20 cm施用污泥在整体上较其他两种施用方式有更高的出苗率和籽粒产量,在施用量为30 t/hm~2时籽粒产量最高,为656.70 kg/667m~2,高出对照29.64%。3种施用方式下,土壤中的Cu,Zn,Pb含量及玉米籽粒中的Cu,Zn含量均随污泥施用量的增加而增加,而玉米籽粒中Pb含量与对照相比差异不显著,土壤和籽粒中重金属含量均未超过国家相关标准。以重金属浓度满足土壤环境质量标准为限制条件,推算出当地的市政污泥施用量为30 t/hm~2可以连续施用5 a。[结论]施用30 t/hm~2的污泥具有良好的效果和环境效应;为了降低污泥在土壤中的局部累积而导致的胁迫效应,表土下20 cm施用和地表撒施是相对较好的方式。     

施用辐照处理的污水污泥对作物产量和土壤氮的影响

A field experiment was conducted to study the feasibility of irradiated and non-irradiated sewage sludge as a fertilizer for the growth of wheat and rice. The irradiated and non-irradiated sewage sludge were applied at rates of 0 (CK), 75, 150, 225 and 300 kg N ha^-1 for wheat, and 0 (CK), 112.5, 225, 337.5 and 450 kg N ha^-1 for rice, respectively. (NH₄)₂SO₄ at a rate of 150 kg N ha^-1 for wheat, and 225 kg N ha^-1 for rice were added to the control treatments. Additionally, 20 kg ¹⁵N ha^-1 in the form of (NH₄)₂SO₄ was added to each treatment for wheat to study the effect of sewage sludge on chemical nitrogen fertilizer recovery. The results showed that the irradiation of sewage sludge by gamma ray at a dosage of 5 kGy increased crop yield by 11%~27% as compared to the non-irradiated treatments. Irradiation stimulated mineralization of organic nitrogen in the sludge and improved seedling growth. It was found that addition of irradiated sludge could reduce the leaching loss of chemical nitrogen fertilizer. Both irradiated and non-irradiated sewage sludge could increase the content of soil total nitrogen. Based on the preliminary results, it was concluded that irradiated sewage sludge could partly substitute for chemical nitrogen fertilizer in crop production.     

Biochar and Sewage Sludge Application Increases Yield and Micronutrient Uptake in Rice (Oryza sativa L.)

A greenhouse experiment was conducted in the Department of Soil Science and Agricultural Chemistry, Institute of Agricultural Sciences, Banaras Hindu University, Varanasi (U.P.), India, during kharif 2013 to find out the effect of biochar and sewage sludge (SS) on growth, yield, and micronutrient uptake in rice crop. Nine treatments were employed using six different doses of biochar (2.5, 5.0, 7.5 10, 15, and 20 t ha^?1) amended with a fixed dose of SS (30 t ha^?1) and 50% recommended dose of nitrogen (50% RDN), i.e., 60 kg ha^?1. Other three treatments were absolute control (no fertilizers), 100% recommended dose of fertilizers (100% RDF) which was 120:60:60 kg ha^?1 as nitrogen (N): phosphorus pentoxide (P₂O₅):dipotassium oxide (K₂O), and 30 t ha^?1SS + 50% RDN. Experimental results showed a significant increase in yield of rice crop with increasing levels of biochar along with SS. Application of biochar at 20 t ha^?1 along with 30 t ha^?1SS increased grain yield to the extent of 2.5 times over absolute control (no fertilizers) and 8.5% over control (100% RDF). The uptake of iron (Fe), copper (Cu), zinc (Zn), and manganese (Mn) (micronutrients) increased significantly with graded doses of biochar application from 2.5 to 20 t ha^?1 in the soil. The maximum micronutrient uptake and grain yield of rice were found in T₉ where 30 t ha^?1SS along with 20 t ha^?1 biochar was applied with only 50% RDN. The maximum availability of micronutrients in soil was found with 30 t ha^?1 of SS + 50% RDN (T₃) followed by conjoint application of 20 t ha^?1 of biochar and 30 t ha^?1 SS + 50% RDN (T₉).     

Dynamics of Organic C Mineralization and the Mobile Fraction of Heavy Metals in a Calcareous Soil Incubated with Organic Wastes

Organic wastes such as sewage sludge and compost increase the input of carbon and nutrients to the soil. However, sewage sludge-applied heavy metals, and organic pollutants adversely affect soil biochemical properties. Therefore, an incubation experiment lasting 90 days was carried out to evaluate the effect of the addition of two sources of organic C: sewage sludge or composted turf and plant residues to a calcareous soil at three rates (15, 45, and 90 t of dry matter ha^–1) on pH, EC, dissolved organic C, humic substances C, organic matter mineralization, microbial biomass C, and metabolic quotient. The mobile fraction of heavy metals (Zn, Cd, Cu, Ni, and Pb) extracted by NH₄NO₃ was also investigated.The addition of sewage sludge decreased soil pH and increased soil salinity to a greater extent than the addition of compost. Both sewage sludge and compost increased significantly the values of the cumulative C mineralized, dissolved organic C, humic and fulvic acid C, microbial biomass C, and metabolic quotient (qCO₂), especially with increasing application rate. Compared to compost, the addition of sewage sludge caused higher increases in the values of these parameters. The values of dissolved organic C, fulvic acid C, microbial biomass C, metabolic quotient, and C/N ratio tended to decrease with time. The soil treated with sewage sludge showed a significant increase in the mobile fractions of Zn, Cd, Cu, and Ni and a significant decrease in the mobile fraction of Pb compared to control. The high application rate of compost resulted in the lowest mobility of Cu, Ni, and Pb. The results suggest that biochemical properties of calcareous soil can be enhanced by both organic wastes. But, the high salinity and extractability of heavy metals, due to the addition of sewage sludge, may limit the application of sewage sludge.     

Enrichment of trace elements from long-range aerosol transport in sandy podzolic soils of southwest France

Total content of trace elements (Cd, Co, Cr, Cu, Mn, Ni, Pb, and Zn), was determined to a depth of about 1 m in the horizons of three representative podzolic soils (i.e., wet moor, dry moor, and dune soil) developed on the coarse sands of the Atlantic face of southwest France. In the aged soils (wet moor and dry moor), Cr, Cu, Ni, Pb and Zn, were highly concentrated in the B horizons whereas Cd accumulated in the litter. An estimate of metal balance was made in the soil profiles, comparing the total amount of metal recovered in the A-B horizons to the amount of indigenous metal determined in a rock matter (C) layer of a similar depth as the A-B horizons. Substantial long-term enrichment of the whole upper part of the profile (A-B horizons) of three representative sites was found for Cd (0.1–0.6 kg ha^?1), Cu (3–12 kg ha^?1), Ni (1–7 kg ha^?1), Pb (20–26 kg ha^?1), and, to a lesser extent, for Co, Mn, and Zn. Since the experimental site was remote from industrial, urban and agricultural activities, the increase in soil metal content was apparently caused by the deposition of metallic aerosols via long-range transport. Total long-term inputs are estimated for average values of Cd (0.6 kg ha^?1), Cr (5 kg ha^?1), Cu (12 kg ha^?1), Ni (7 kg ha^?1), Pb (25 kg ha^?1) and Zn (6 kg ha^?1) for the 1 m depth. Several Atlantic areas of Europe are probably affected by a similar metal input.     

Effects of time and temperature on the bioavailability of Cd and Pb from sludge-amended soils

A pot experiment was conducted to compare the behaviour and bioavailability of Cd and Pb from two soils mixed with sewage sludge at three rates (0, 50 and 150 t ha^?1) and maintained at two contrasting ambient temperatures (15°C and 25°C) over a period of one year following the treatments. Ryegrass (Lolium perenne) accumulated Cd and Pb in the sewage sludge treated soils, although accumulation was significantly lower in the soils treated at the high rate (150 t ha^?1) compared to the low rate (50 t ha^?1). Ryegrass grown in the warm environment (25°C) accumulated significantly higher levels of Cd and Pb than that grown in cooler conditions (15°C). Samples of the soils spiked with nitrate salts of Cd and Pb at equivalent rates of metal loading resulted in the ryegrass accumulating much higher levels of both the metals than on the sludge treated soils. Metal uptake by the ryegrass from the sludge treatments increased over successive harvests while that from metal salt treatments decreased. The observed trend of increasing plant metal uptake over time coincided with a trend of decreasing pH in the sludge treatments. However, the concentrations of Cd and Pb extracted by DTPA failed to predict the changes in plant metal uptake. The importance of sewage sludge as both a source and a sink of pollutant metals and the trend of increasing bioavailability over time shown by this experiment are discussed.     

Effect of sewage sludge–coir pith pellets on dry matter yield and trace metal concentration in various plant parts of forage maize

Sewage sludge (SS), a highly heterogeneous semisolid fraction of sewage water (about 1% of the sewage water), contains various amounts of nitrogen (N) and phosphorus (P) as well as trace elements such as cadmium (Cd), lead (Pb), copper (Cu), nickel (Ni) and zinc (Zn) with extremely variable physical and chemical compositions. Application of SS improves soil properties, increases yield and simultaneously increases trace metal content in soil and plants. The difficulty in handling, transporting and applying SS and its adverse effect, especially trace metal content in soil and plant, can be overcome by SS–coir pith pelletization (SSCP) or mixing with sewage sledge–coir pith mixture (SSCM). A study was undertaken to evaluate the prepared SSCM and SSCP (1:1 ratio of SS and coir pith) along with SS on dry matter yield, trace metal content in soil and plant parts. The results showed that increased rates of application of SS or SSCM or SSCP increased the green and dry fodder yield of forage maize. Application of SS as either SSCM or SSCP at 1.2 and 2.4 g pot^?1 significantly reduced the trace metal content diethylene triamine pentaacetic acid (DTPA extractable) in soil and plant parts (leaves steam and root) compared to SS application. Therefore, in order to reduce the bioavailability of trace metal in soil and its uptake by plant, application of SSCM or SSCP at 1.2 or 2.4 g pot^?1 proved to be a better option than SS application.     

Copper and zinc adsorption by sewage sludge‐treated soil in southern Spain

Abstract

Heavy metal accumulation in soil due to the application of sewage sludge may induce changes in its ionic retention capacity. In this work, sludge application effects on copper (Cu) and zinc (Zn) adsorption by the surface horizon of a calcareous soil in Southern Spain have been studied. Sludge from the urban waste water treatment plant in Cordoba was applied at rates of 0,40, and 80 Mg sludge ha^‐1 for two consecutive years. Despite the low metal content of this sludge and the high amount of organic matter added, a decrease in the soil adsorption levels for both Cu and Zn was detected in the sludged samples. Differences were observed, though, in the behavior of each metal, relative to the main adsorption mechanism involved. Copper adsorption was related to carbonate surfaces in soil. Values up to 400 mmol adsorbed Cu kg^‐1 soil were obtained for the three treatments, in equilibrium with 13.6, 16.7, and 17.4 mmol Cu m^‐3 in solution for 0, 40, and 80 Mg sludge ha^‐1, respectively, the first year, and 13.9, 21.2, and 52.2 mmol Cu m^‐3 in solution the second year. However, an increase of soil Cu availability is not likely to arise during or after continuous application of these sludge doses, due to the high calcium carbonate content of this soil. In the case of Zn, adsorption took place in CEC sites, with values up to 40 mmol adsorbed Zn kg^‐1 soil in the 0 and 80 Mg sludge ha^‐1 samples, in equilibrium with 158.3 and 164.5 mmol Zn m³ in solution, respectively the first year, and 196.1 and 505.8 mmol Zn m³ in solution the second year, whereas in the 40 Mg sludge ha^‐1 samples adsorption was below 25 mmol Zn kg^‐1 soil, in equilibrium with 171.1 mmol Zn m³ in solution the first year, and 231.0 mmol Zn m^‐3 the second year. As soil CEC values and its organic matter content are positively related, Zn availability in this soil could be expected to increase after the cessation of sludge applications, due to the mineralization of the organic matter added.     

Comparative availability to wheat of metals from sewage sludge and inorganic salts

A greenhouse experiment was conducted to evaluate the availability of metals from sewage sludge and inorganic salts, and the effect of pH and soil type on yield and metal (Zn, Cu, Cd and Ni) uptake by wheat (Triticum aestivum L. var. ‘holly’). Soils used in this study were Hartsells sandy loam (fine-loamy, siliceous Thermic Typic Hapludult) and Decatur silty clay loam (Clayey, kaolinitic, Thermic Rhodic Paleudult). Two treatments of sewage sludge containing metals were applied at the rate of 20 and 100 mt ha^?1. Inorganic Salts of Zn, Cu, Cd, and Ni were applied (as sulfate salts) at concentrations equivalent to those found in the 20 and 100 mt ha^?1 sludge. One treatment consisted of inorganic metals plus sewage at the 20 Mg ha^?1 rate. Two soil pH levels, one at field pH (below 6.0) and another pH adjusted between 6.5 and 7.0 were used. Wheat plants were harvested four weeks after germination. Two more subsequent harvests were made at four week intervals. For each harvest, dry matter yield increased as the rate of sludge application increased for both soil types. The soil pH also influenced the dry matter yield. High yield was observed when the pH was adjusted between 6.5 to 7.0 for both soils. An increase in yield was also observed at each subsequent harvest for most of the treatments. Inorganic salt treatments produced lower dry matter yields when compared with the sludge. Both sludge application and metal salts increased plant tissue concentration of Zn, Cu, Cd, and Ni at field pH for both soils. However, increasing the pH of the soil for both sludge and inorganic salt treatments generally decreased the tissue concentration of the above metals.     

Nitrogen Availability for Maize from a Rolling Pampa Soil After Addition of Biosolids

Abstract

The objective of this paper was to evaluate the influence of different rates of biosolids on the soil nitrogen (N) availability for maize and its residuality. A field experiment was developed in a typic Argiudol located in the NE of the Buenos Aires Province. Maize was sown for two consecutive years 1997–1999. Biosolids from a sewage treatment plant of Buenos Aires outskirts were superficially applied to the soil and incorporated by plowing. There were eight treatments: Check; 8, 16, and 24 Mg of dry biosolid ha^?1; 8 and 16 Mg of dry biosolid ha^?1 applied one year before, 100 and 150 kg N ha^?1 of calcium ammonium nitrate (CAN). The sampling and determinations were done during the second maize cycle. At presowing (PS), sowing (S), 6 expanded leaves (V6), 12 expanded leaves (V12), and Flowering (Fl) composite soil samples from 0–40 cm depth were obtained to determine ammonium and nitrate contents. At Fl maize plants were sampled in order to determine total biomass and N content. The N‐nitrate content in the soil was significantly increased by the biosolids application (p < 0.05), and varied for each increment depending on the biosolids rates and the phenological stage. After 30 days from the incorporation the increases of 1.19, 1.34, and 2.05% were observed for N‐nitrates for 8, 16, and 24 Mg ha^?1, respectively. The contribution of mineral N from the biosolids was 2.48, 6.46, and 5.01 kg N Mg^?1 when the rates were incremented from 0–8, 8–16, and 16–24 Mg ha^?1, respectively. The nitrogen mineralization followed a release pattern with a maximum value of 296 kg N‐nitrate ha^?1 at sowing for 24 Mg ha^?1. Since then, the release of mineral nitrogen decreased significantly till Fl. The N‐nitrates values variation with the temperature adjusted to polinomic functions. The mineral N released from the biosolids increased as a response to the increment of soil temperature and then decreased due to the maize nitrogen absorption and the potentially mineralized nitrogen exhaustion. The application of 150 kg N ha^?1 as CAN incremented significantly the soil N‐nitrate content and equalized 16 and 24 Mg of dry biosolids ha^?1 at V6. But, no synchronism between the high nitrate releasing from biosolids and the increment in the nitrogen absorption by maize was observed. This fact generates a surplus of nitrate that incremented the potential of nitrogen loss by lixiviation. We observed a residual effect from the biosolids that were applied the previous year. This contribution represented the 35% of the maize requirements and was similar to the nitrate content observed in Bio 16. The biosolids might be a valuable source of nitrogen for maize crop if the synchronism between the soil supply and maize demand is observed in order to avoid nitrates surplus.     

Effects of lime and sewage sludge on soil,pasture production,and tree growth in a six‐year‐old Populus canadensis Moench silvopastoral system

In many regions worldwide, silvopastoral systems are implemented to enable sustainable land use allowing short, medium, and long‐term economic returns. However, the short‐term production in silvopastoral systems is often limited due to nonappropriate soil‐fertility management. This study evaluated the effects of two doses of lime (0 and 2.5 t CaCO₃ ha^–1) and three sewage‐sludge treatments (0, 200, and 400 kg total N ha^–1 y^–1 applied in 2 consecutive years) on soil characteristics (soil pH, soil organic matter [SOM], soil nitrogen, cation‐exchange capacity [CEC]), pasture production, and tree growth in a silvopastoral system of Populus × canadensis Moench in Galicia, northern Spain during 6 years after establishment. Soil pH increased during the experimental period for all treatments, although this effect was more pronounced after lime application. Changes in SOM and soil nitrogen content were not consistent over time, but sewage‐sludge application seemed to result in higher values. Higher CEC was found for treatments with lime and sewage‐sludge application. Following incorporation of lime and sewage sludge, pasture production was significantly enhanced (cumulative pasture production 51.9 t DM ha^–1 for Lime/N400 compared to 39.0 t DM ha^–1 for No lime/N0). This higher pasture production also affected tree growth due to more severe competition between pasture and tree resulting in slower tree growth. Liming and application of sewage sludge are relevant measures to improve soil fertility and thereby optimizing the overall production of silvopastoral systems. However, it is important not to overintensify pasture production to ensure adequate tree growth.