Long-term dynamics of anthropogenic solonetzicity in soils of the Eastern okrug of Moscow under the impact of deicing salts

The long-term dynamics of the anthropogenic soil solonetzicity under the impact of applied deicing salts were studied in the Eastern administrative okrug (EAO) of Moscow. The composition and amount of the applied agents and distribution patterns of sodium in snowmelt water and in soils of different land-use zones were analyzed. The maps of soil solonetzization in the EAO in 1989, 2005, and 2010 were compiled, and the degree of degradation of the soil cover was evaluated. It was shown that the contrast of the technogenic anomalies in the content of exchangeable sodium and the size of these anomalies in soils of the okrug increase with time. In 21 years, the mean content of exchangeable sodium in the surface soil layer increased from 0.38 to 0.80 cmol(equiv.)/kg, and the degree of solonetzicity (as judged from the exchangeable sodium percentage) increased from 3.1 to 7.2%. In 2005–2010, the rates of sodium accumulation in the soil adsorption complex were twice as high as those in 1989–2005.     

Multiyear dynamics and factors of accumulation of benzo(a)pyrene in urban soils (on the example of the Eastern Administrative Okrug,Moscow)

Multiyear data obtained from a survey of benzo(a)pyrene (BP) in the soils of the Eastern Administrative Okrug (prefecture) of Moscow have shown that, over the period from 1990 to 2006, its concentration increased from 492 to 645 ng/g, exceeding the background value by 145 to 190 times. Two stable and strongly contrasting anomalies of BP have been identified as a result of mapping its distribution across topsoil horizons. The multiyear BP dynamics is reflected on the map of its annual increase in concentration. The intensity of soil contamination by this compound is caused by type of land use and by their salinity level. The average BP concentration in the okrug’s soils amounted to 32.2 maximum permissible concentration (MPC). Soils with levels of contamination deemed extremely dangerous or dangerous are predominant, and their area in 2006 reached 96% of the total territory covered by the survey.     

Polycyclic aromatic hydrocarbons in urban soils (Moscow,Eastern District)

The content and distribution of 17 individual structures of polycyclic aromatic hydrocarbons (PAH) were determined in the surface soil layers of the Eastern Administrative District of Moscow and in the background soils of the Meshchera Lowland. The maximum contribution to the PAH spectrum in the background soil belonged to the structures with a small number of nuclei mainly of natural genesis. In the urban soils, the mean total PAH was 5385 ng/g; it was 40 times higher than in the background objects. The unsubstituted multinuclear hydrocarbons as compared to homologues accumulated two times more intensely. The total PAH concentration in the soils of different functional zones varied from 4288 (old residential area) to 8655 ng/g (new blocks). The soils of each zone were characterized by a constant composition of polyarenes, which reflected a specific combination of pollution sources. Using the maps of the benz(a)pyrene contents in the soils in different years, two of its contrasting technogenic anomalies were revealed in the northern and central parts of the district. In 2006, in these areas, the benz(a)pyrene concentration exceeded its MPC by 150 times. The ecological hazard of PAH pollution was assessed. The estimate obtained took into account the carcinogenic potential of 13 individual polyarenes by their equivalents with respect to benz(a)pyrene.     

Long-term salinization dynamics in irrigated soils of the Golodnaya Steppe and methods of their assessment on the basis of remote sensing data

A set of salinization maps (1983–2000) for the former Yusupov State Farm in the irrigated area of the Golodnaya Steppe (Uzbekistan) were developed with the use of aerial and satellite images taken in the early autumn season. A unified approach based on the analysis of the mottled patterns of the cotton fields was used. The soil cover of the farm consists of irrigated hydromorphic moderately saline soils with the participation of nonsaline and strongly saline soils. The long-ter m dynamics of the soil salinity were studied via superposing two or more maps for different years. It was shown that the long-term salinization dynamics could not be determined on the basis of the comparison of only two maps for different years. Maps of the trends of the salinization for the entire period of the observations, a map of the salinization dynamics showing the degree of changes in the soil salinity for the particular areas, a map of the areas with stable salinization through the entire period, and some other maps were developed. A considerable part of the investigated area was characterized by highly unstable soil salinity and active salinization-desalinization processes. The degree of the soil salinity varied from slight to strong and vice versa. For the entire period, the soils were mainly medium saline in the upper meter with a weakly expressed tendency for further salinization and a drop in the area of nonsaline and slightly saline soils.     

Dynamics of contamination of urban soils with lead in the eastern district of Moscow

Spatial-temporal trends were revealed in the contamination of Moscow soils with lead as a priority pollutant emitted with automobile exhaust. From the data of 1989 and 2005, maps of technogenic lead aureoles in soils of the eastern district were compiled, the average annual rate of increase in the element content was estimated, and its doubling time was predicted. Ecological-indication properties controlling the accumulation of lead in soils were determined.     

Isotopic composition of lead in soils and street dust in the Southeastern administrative district of Moscow

The content and isotope ratios of lead were studied in soils, street dust, and snow sampled in the Southeastern administrative district of Moscow. The relationships between the lead isotope ratios and the content of different lead compounds in soils were revealed. It was shown that isotope ratios for the total lead have low information values upon low levels of lead contamination. The contribution of technogenic lead compounds to the isotopic composition of lead increases in the following sequence: total lead < acid-soluble lead < mobile lead. The effect of emissions from thermal power stations and vehicles’ exhaust on the isotopic composition of lead in the street dust and soils was estimated.     

Content and distribution pattern of dichlorodiphenyltrichloroethane (DDT) in soils of Moscow

The content and distribution pattern of dichlorodiphenyltrichloroethane (DDT) and its metabolites (DDE and DDD) in the surface layers of soils in Moscow are studied. The residual content of these substances in the soils varies within 2.22–1440 µg/kg (at a mean value of 158.9 ± 314.1 µg/kg and median 42.53 µg/kg). The correlation between the contents of DDT and its metabolites and DDD and organic matter is revealed. The highest contents of the pollutants are seen in the residential–transport and industrial zones of Moscow, while their lowest contents are revealed in the soils of the yards of preschool facilities and schools. With respect to the residual contents of the pesticide, most of the soils of Moscow can be considered uncontaminated (80.0%) and acceptably contaminated (7.5%).     

Anthropogenic transformation of soils in the Pokrovskoe-Streshnevo Park (Moscow) and adjacent residential areas

The diversity of soils within the specially protected natural territory of Pokrovskoe-Streshnevo in Moscow is discussed. The soils of this large park are not affected by the modern construction activities that delete the features inherited from the early stages of the anthropogenic transformation of soils in Moscow. They are characterized by the book-like type of soil memory, which makes it possible to trace several sequences of the anthropogenic soil transformation. The background natural soils-rzhavozems (Chromic Cambisols)—have been transformed into agrogenic soils (agrosols) and postagrogenic soils (postagrosols) under abandoned plowlands, into urbo-soils and urbanozems in the areas of former or modern settlements, and into techno-soils in the areas of active excavation works and engineering reclamation. The change in the character of the land use without the accumulation of osediments on the surface leads to the development of polygenetic soil horizons.     

Transformation and form of dichlorodiphenyltrichloroethane (DDT) applied to Moscow soils

The transformation rate and direction of dichlorodiphenyltrichloroethane (DDT) and its forms entering the surface layers of Moscow soils have been analyzed. The DDT transformation rate into metabolites—dichlorodiphenyldichloroethylene (DDE) and dichlor diphenyl dichloroethane (DDD)—is small. In 75% of soils, less than half the initial pesticide is transformed. In 67.5% of soils, formation of DDD predominates in the DDE formation. In soils of the entire area of Moscow, 16% of DDT was transformed into DDE and 23% into DDD. The о,n′-DDT to n,n′-DDT ratio is <0.3 for 95% of soils, and the mean ratio is 0.1, which is typical for application of DDT as a technical product.     

A procedure for evaluating and mapping the erosion resistance of soils (by the example of irrigated soils of Tajikistan)

A procedure was developed on the basis of the experimental-theoretical equation for calculating the parameters of soil erosion resistance (the bottom eroding velocity of flow), the principles of the erosion resistance theory, the experimentally obtained relationships between the main erosion parameters of Tajikistan soils (the size of water-stable aggregates and their cohesion), and other properties (the initial water content, the lumpiness, the contents of physical clay and humus, the porosity ratio, and the lower plasticity limit). For practical purposes, a simpler procedure is recommended to evaluate and map the erosion resistance of irrigated lands in the areas of typical serozems and mountain cinnamonic soils of Tajikistan from minimum initial information (the texture, lumpiness, and density of the soils and the content of plant roots).     

Specific features of the ecological functioning of urban soils in Moscow and Moscow oblast

Urban soils (constructozems) were studied in Moscow and several cities (Dubna, Pushchino, and Serebryanye Prudy) of Moscow oblast. The soil sampling from the upper 10-cm-thick layer was performed in the industrial, residential, and recreational functional zones of these cities. The biological (the carbon of the microbial biomass carbon, C_mic and the microbial (basal) respiration, BR) and chemical (pH_water and the contents of C_org, heavy metals, and NPK) indices were determined in the samples. The ratios of BR to C_mic (the microbial respiration quotient, qCO₂) and of C_mic to C_org were calculated. The C_mic varied from 120 to 738 μg C/g soil; the BR, from 0.39 to 1.94 μg CO₂-C/g soil per hour; the C_org, from 2.52 to 5.67%; the qCO₂, from 1.24 to 5.28 μg CO₂-C/mg C_mic/g soil per h; and the C_mic/C_org, from 0.40 to 1.55%. Reliable positive correlations were found between the C_mic and BR, the C_mic and C_mic/C_org, and the C_mic and C_org values (r = 0.75, 0.95, and 0.61, respectively), as well as between the BR and C_mic/C_org values (r = 0.68). The correlation between the C_mic/C_org and qCO₂ values was negative (r = −0.70). The values of C_mic, BR, C_org, and C_mic/C_org were found to correlate with the ammonium nitrogen content. No correlative relationships were revealed between the determined indices and the climatic characteristics. The principal component analysis described 86% of the variances for all the experimental data and clearly subdivided the locations of the studied soil objects. The ANOVA showed that the variances of C_mic, C_org, and BR are controlled by the site location factor by 66, 63, and 35%, respectively. The specificity of the functioning of the anthropogenic soils as compared with their natural analogues was clearly demonstrated. As shown in this study, measurable biological indices might be applied to characterize the ecological, environmental-regulating, and productive functions of soils, including urban soils.     

Ecological status of soils in Moscow Zoo

The quantitative assessment of the status of soils in Moscow Zoo was performed using traditional and original methods based on the differentiated system of indices. The studies were conducted in animal open-air cages and on plots available for visitors. The dynamics of the temperature and water-air regimes in the root-inhabited layer, the density, the acidity, and the salinity of the soils were studied. The level of the biological activity was assessed according to the intensity of the organic matter decomposition and the substrate-induced respiration. In the background of the rather satisfactory status of the soils, negative factors were found: a periodic excess or deficit of moisture and, for the most part, low biological activity (low respiration and decomposition of the lignin-cellulose test material). Recommendations for the improvement of the status of the soil cover in Moscow Zoo are proposed.     

Fractional composition of lead compounds in soils of Moscow and Moscow region

Sequential fractionation of lead compounds from the urban and suburban soils of Moscow and eastern Moscow region was performed using the Tessier method. It was found that strongly bound lead compounds retained by Fe and Mn hydroxides were predominant in the background (reference) soils of the Meshchera Lowland in Moscow oblast. The content of almost all the lead fractions, except for the hydroxide fraction, increased in the contaminated soils. The quantitative proportions of the particulate fractions varied depending on the distance from the city, the physicochemical properties of the soils, and the land use. The profile distribution of the lead was of accumulative character; the metal was fixed on the biogeochemical barrier, where the lead compounds of the fourth fraction bound to organic matter are mainly accumulated.     

Polycyclic aromatic hydrocarbons in soils of Moscow

The contents of polycyclic aromatic hydrocarbons (PAHs) in the upper horizons of Moscow soils range up to 1400 mg/kg for individual compounds and up to 10000 mg/kg for their sum. The concentration coefficients of PAHs in the soil vary from 0.7 to 200 depending on individual polyarene properties and land use. The heavy polynuclear structures of technogenic origin have the highest concentration coefficients. The highest accumulation of PAHs is observed for the soils of dumping sites, residential-transport areas, and industrial zones. According to the state sanitary norms set in the Russian Federation for the content of benzo[a]pyrene in soils, more than one-third of the urban soils studied are classified as pure, and about half soils are classified as acceptable.     

The biological activities of post-agrogenic soils (Based on an Example from the Moscow Region)

Based on the example of soils from the Moscow Region a number of biological activity indicators of arable, virgin, and post-agrogenic soils were studied. The lowest indicators of biological activity (potential breathing activity, biomass of microorganisms and the relationship between carbon and microorganisms to soil carbon) were shown by arable soils. Among post-agrogenic soils, the soils of neglected fields, which formed after the termination of plowing, are more biogenic than soils of perennial dry meadows; this is due to the combination of a high level of fertilizer elements and the annual receipt of a soft vegetative substrate. The carbon dioxide emissions of a soil as a multifactor and strongly varying indicator cannot be the only criterion of the biological activity of a soil.     

Mobile aluminum compounds in soils of the southern taiga (soils of the central forest reserve as an example)

The profile distributions of aluminum extracted by the Tamm and Bascomb reagents and of the exchangeable aluminum were studied in soils of automorphic, transitive, and accumulative positions in the landscapes of the southern taiga. In the mineral horizons of the gleyic peaty-podzolic soils developed on poorly drained flat surfaces and in the floodplain soils, the distribution of oxalate- and pyrophosphate-soluble aluminum has a strongly pronounced accumulative character. In the podzolic soils of the automorphic positions and slopes, an eluvial-illuvial distribution was characteristic with the maximal aluminum content in the podzolic horizons. The strong differentiation of the upper part of the profile in the automorphic podzolic soils in terms of the Al content in the Tamm and Bascomb extracts is mainly related to an increase of the pedogenic chlorite content upon the transition from the AE to the E horizon. In the podzolic horizons of these soils, aluminum can accumulate in the form of proto-imogolite structures. The exchangeable aluminum displays an accumulative type of distribution. On the basis of calculating the reserves of the different aluminum compounds, two main accumulative zones for the mobile compounds of this element were recorded in the soils of the landscapes studied: the E horizon in the automorphic podzolic soils, where Al accumulates as soil chlorite or, probably, as proto-imogolite, and the A1 horizon of the floodplain soils, where Al accumulates in aluminoorganic complexes.     

Study of Pedo Genesis of soils of Bundi district (Rajasthan)

The soils of Rajasthan vary from desert sand to heavy clay with all intermediate stages like sandy loam, loam and clay loam. The last two textural groups are more prevalant on the eastern, northeastern and southeastern part of the Aravallies which run almost in the middle of the State from southeast to northeast. The latter groups of soils have more potential from the point of agricultural development in the State. These soils are widely termed as alluvial soils which is a general term to indicate the nontaxonomic group of soils that have parent material of alluvial origin, Riecken ¹⁷, Kelloog ⁸ has referred to the soils developed from the alluvium as classified under variety of world soil groups. In our country many of the alluvial soils have not yet been studied from the soil genesis point of view as a measure to classify the soils under taxonomic groups. Ray Chawdhary and Mukerji ¹⁵, concluded that the alluvial soil groups of our country are ill defined and the classification of these soils need more study. Basu ³ was able to distinguish the genetic characteristics of the soils of Deccan. Agrawal and Mukherji ¹⁾ established that distinct genetic soil types have come into expression under Gangetic alluvium. Agarwal ² has concluded about the three types of soils in the toposequence with precipitated calcium throughout, zone of calcium accumulation in the bottom of the profile and soils free of calcium, and suggests that the soils of Gangetic plain be called as derived from alluvium. A process of reclassifying the alluvial soil series into taxonomic groups is a common trend in the United States since the last two decades.     

The effect of the microrelief on salinization of semidesert soils

The microrelief affects the distribution of soluble salts in the upper horizons of salt-affected soils. This has been shown for semidesert soils—meadow solonchak, solonchakous meadow, and meadow soils—within the Sulak Lowland in the Republic of Dagestan. The total content of salts and the concentrations of sodium, magnesium, chlorine, and sulfate ions are higher in the soils of microelevations. However, no significant effect of the microrelief on the distribution of calcium in the soil water extracts has been found. The properties of the solid soil phase (the humus content and the content of adsorbed bases, including calcium, magnesium, and sodium) and the soil pH are not reliably differentiated by the elements of the local microtopography.     

Amelioration and reforestation of sulfurous mine soils in Lusatia (Eastern Germany)

In Germany nearly 1.550 km² have been claimed by brown coal mining until now. Mine soils formed of carboniferous and sulfurous overburden are classified as “sulfurous mine soils”. They remain vegetation-free for decades and may be cultivated only after soil amelioration. The objective of amelioration is a sustained improvement of soil reaction. Lime requirement for the achievement of a certain pH-value is calculated from acid-base-balance (SBB). Lime fertilizers and base-rich brown coal ashes are used for amelioration. As ashes have serveral advantages,their application is recommended. The ameliorative application of lime fertilizer or brown coal ash should be incorporated intensively into the soil to a depth of 60 cm, better 100 cm. Amelioration includes a mineral fertilization with N, P and K. Afforestations with Pinus sylvestris, Pinus nigra, Larix decidua, Larix eurolepis, Tilia cordata, Quercus rubra and Quercus petraea on ameliorated mine soils show surprising good results. Multi-species stands have very positive effects on soil formation. Raw humus is formed under pine and larch, and under deciduous trees moder and mull with higher bioactivity and better development of water and nutrient balance in the topsoil are found.