Impact of water percolation on nutrient leaching from an irrigated paddy field in Japan

Abstract. We examined the effect on soil nutrient status and sustainability of water percolation through an irrigated paddy field in Japan, to the depth of drainage (40 cm). The difference between amounts of nutrients leached by percolation and those supplied by irrigation indicated that 25–130 kg ha⁻¹ Ca, 8–24 kg ha⁻¹ Mg, from −1 to 9 kg ha⁻¹ K, and 8–17 kg ha⁻¹ Fe, respectively, were lost each year from the 0–40 cm soil layer during rice cultivation, when the supply from fertilization and rainfall and the loss in grain harvest were not accounted for. When the supply of K from rainfall and the loss in grain harvest were taken into account, a total K loss of about 10 kg ha⁻¹ was estimated. The electrical neutrality of inorganic ions in the percolating water was always maintained. From these results we estimate that the amounts of exchangeable Ca and Mg in the soil to a depth of 40 cm would decrease by 50% within 50–260 and 30–100 years, respectively, if similar management were continued without fertilization. The total amount of carbon dioxide (ΣCO₂) leached in percolating water during the period of rice cultivation was 120–325 kg C ha⁻¹, which corresponded to 0.47–0.94% of the soil organic carbon to 40 cm depth.     

Effects of ridging on crop performance and symbiotic N2 fixation of fababean (Vicia faba L.)

Abstract. The success of organic cropping systems depends on symbiotic N₂ fixation by leguminous crops, and it is important to explore new management systems to improve the nitrogen input through N₂ fixation. During two growing seasons the possible advantage of growing fababean ( Vicia faba L.) in ridges was studied in comparison to the traditional method on flat soil. Differences in soil physical parameters resulted in a significantly greater microbial activity and a deeper root system at the flowering stage when grown in the ridge than on the flat. Consequently, the amount of fixed N at flowering was significantly greater in ridges than in flat soil. However, during the period from flowering until harvest, when the major part of the N uptake and N₂ fixation took place, the differences between the treatments disappeared. Average values for the growing season of fluorescein diacetate hydrolysis, arylamidase activity and arylsulphatase activity were significantly greater in the ridge than on the flat, and the microbial biomass-C, derived from substrate induced respiration (SIR), was on average 232 and 223 μg C g⁻¹ soil in the ridge and on the flat, respectively. Measured total-N uptake, including root N (0–30 cm depth), ranged from 206 to 247 kg N ha⁻¹, of which 182–201 kg N ha⁻¹ was fixed N. From 154 to 173 kg N ha⁻¹ was removed in grain resulting in a soil-N balance of +28 kg N ha⁻¹ in both years. However, by including estimates of total root N and rhizodeposition-N the soil-N balance ranged from +52 to +62 kg N ha⁻¹.     

Errors in the estimation of soil water properties and their propagation through a hydrological model

Abstract. The Agricultural Catchments Research Unit model (ACRU) includes a decision support system (DSS) for estimating the water content of soil at field capacity (θ _fc ) and wilting point (θ _wp ) when these characteristics are not directly measurable. Three methods of estimation are proposed: (a) based on silt and clay content and bulk density, (b) based on clay content only, and (c) based on soil series. These three pedotransfer functions are compared with respect to both the estimation of θ _fc and θ _wp and the propagation of errors when the actual evapotranspiration of a wheat crop (E) is predicted over the growing season by the ACRU model.
The standard error of estimation was between 0.066 and 0.082 m³/m³ for θ _fc , between 0.056 and 0.069 m³/m³ for θ _wp and between 29.9 and 34.8 mm of water for E. The method based on silt and clay contents and bulk density predicted θ _fc and θ _wp for non-swelling soils most precisely. The method based on soil series was better than other methods for swelling soils. It also performed better for estimating available water capacity and consequently for predicting E from a conceptual soil water model. The propagated error of estimating θ _fc and θ _wp using the DSS reached 15–18% of the simulated E. The error in the prediction of E can reach 26–30% when spatial variation in soil properties is also estimated.     

The use of tension infiltrometers to assess routes and rates of infiltration in a clay soil

This paper describes the design and operation of a simple tension infiltrometer which imposes pressure potentials at the soil surface (h_b) of –0.5, – 2 and –9 cm water, corresponding to equivalent diameters ( e _d) of the largest conducting pore of 6, 1.5 and 0.3 mm respectively. Infiltration measurements obtained in Evesham series clay soil were fitted to Philip's (1957) two-term infiltration equation. Results were interpreted using information on the number, type and size of conducting macropores obtained in a dye tracing experiment. Significantly larger values of effective hydraulic conductivity at h _b=–0.5 cm were attributed to the flow of water in large shrinkage cracks which constituted nearly 90% of the total conducting macroporosity. Measured fluxes at h _b=–9 cm were related to sorption and swelling in the clay matrix, since within the range of infiltration times considered ( t <0.5 h), the gravity or steady state component of infiltration was negligible. Rainfall intensity/duration data for a large number of storms at Silsoe were used to demonstrate that in dry soil nearly 70% of rainfall infiltrates in the clay matrix, and that the infiltration capacity of macropores of e _d≤1.5 mm is only rarely exceeded.     

Potassium balances for arable soils in southern England 1986–1999

Abstract. The behaviour of potassium (K) in a range of arable soils was examined by plotting the change in exchangeable K of the topsoil (Δ K_ex) at the end of a 3–5 year period against the K balance over the same period (fertilizer K applied minus offtake in crops, estimated from farmers' records of yield and straw removal). Based on the assumption that values for offtake per tonne of crop yield used for UK arable crops MAFF 2000) are valid averages, 10–50% of Δ K_ex was explained by the balance, relationships being stronger on shallow/stony soils. Excess fertilizer tended to increase K_ex and reduced fertilization decreased it, requiring between 1.2 and 5.4 kg K ha⁻¹ for each mg L⁻¹Δ K_ex. However, merely to prevent K_ex falling required an extra 20 kg K ha⁻¹ yr⁻¹ fertilizer on Chalk soils and soils formed in the overlying Tertiary and Quaternary deposits, despite clay contents >18%. Whereas, on older geological materials, medium soils needed no extra K and clays gained 17 kg K ha⁻¹ yr⁻¹. It is unlikely that the apparent losses on some soil types are anomalies due to greater crop K contents. Theory and the literature suggest leaching from the topsoil as a major factor; accumulation in the subsoil was not measured. Recommendations for K fertilization of UK soils might be improved by including loss or gain corrections for certain soil types.     

Effects of saline and alkaline stresses on the germination, growth, photosynthesis, ionic balance and anti-oxidant system in an alkali-tolerant leguminous forage Lathyrus quinquenervius

We compared the effects of saline stress (9:1 molar ratio of NaCl : Na₂SO₄, pH 6.44–6.65) and alkaline stress (9:1 molar ratio of NaHCO₃ : Na₂CO₃, pH 8.71–8.89) on the germination, growth, photosynthesis, ionic balance and activity of anti-oxidant enzymes of Lathyrus quinquenervius to elucidate the physiological adaptive mechanism of plants to alkaline stress (high pH). The results showed that, at a low stress intensity, the effects of saline stress and alkaline stress on L. quinquenervius were similar. Compared with saline stress, high alkaline stress intensity clearly inhibited germination, growth, photosynthesis and root system activity, and led to a sharp increase in Na⁺ and an ion imbalance in the shoots, as well as enhanced H₂O₂ and malondialdehyde content, resulting in severe intracellular oxidative stress. The results indicated that the accumulation of organic acid was a central adaptive mechanism by which L. quinquenervius maintained intracellular ionic balance under alkaline stress. Lathyrus quinquenervius may enhance organic acid synthesis to remedy the shortage of negative charge resulting from the massive influx of Na⁺ and decreased inorganic anions. In addition, saline stress and low alkaline stress slightly enhanced the activities of superoxide dismutase (SOD) and ascorbate peroxidase (APX), but did not affect catalase (CAT) activity. However, strong alkaline stress significantly enhanced the activities of SOD and APX, and reduced CAT activity. We propose that enhancing the activities of SOD and APX may be a vital mechanism by which L. quinquenervius resists oxidative stress caused by alkaline stress.     

Kinetic Parameters of Gross N Mineralization of Peat Soils as Related to the Composition of Soil Organic Matter

Peat land has been considered as an alternative type of land for agricultural development especially in the tropics. In the present study, the N-supplying capacity, one of the most important soil properties in terms of crop production, of peat soils was examined. Ten peat soil samples were collected from Indonesia, Malaysia, and Japan. Gross N mineralization in the soil samples was estimated using a zero-order model, and kinetic parameters of mineralization were determined using a simple type model. Soil organic matter composition was investigated using ¹³C CPMAS NMR. Mineralization potential ( N ₀), apparent activation energy ( E _a), and mineralization rate constant ( k ) ranged between 571–2,445 mg kg⁻¹, 281–8,181 J mol⁻¹, and 0.009–0.020 d⁻¹, respectively. Although none of the parameters showed a significant correlation with the soil C/N ratio, a negative correlation was observed between the k value and the ratio of the proportion of alkyl C in total C to that of O -alkyl C estimated by ¹³C CPMAS NMR. The latter suggested that the k values were higher in the peat soils relatively rich in readily decomposable organic matter including carbohydrates.     

Ammonia volatilization from Vertisols

Farmers want to minimize losses of nitrogen (N) by volatilization of ammonia when adding fertilizers and improve fertilizer recovery of N by plants. We aimed to quantify the losses of N through NH₃ volatilization as affected by soil moisture content, type of fertilizer, and placement method in Vertisols in Kenya, and conducted three experiments for the purpose under controlled conditions in the laboratory. We found that NH₃-N losses were greatest at 80% water holding capacity, which we ascribed to the ready availability of water to dissolve the fertilizer at that water content. The soil's cation exchange capacity (CEC) did not influence volatilization, whereas the soil's pH indicated the potential of the soil to volatilize ammonia. Ammonia losses from the fertilizers were in the order urea > ammonium sulphate > ammonium nitrate applied. Incorporating fertilizer within the 0–5 cm soil layer more than halved NH₃ volatilization but did not prevent it completely. These results indicate that soil pH, rather than CEC, is the main inherent characteristic influencing ammonia volatilization from Vertisols. Ammonium-based fertilizers should be incorporated within the 0–5 cm soil layer, or preferably somewhat deeper, to avoid losses via NH₃ volatilization, particularly in alkaline soils. Nitrate fertilizers are preferable to urea where the risks of NH₃ volatilization are large, provided due consideration is given to denitrification risks.     

The nature and kinetics of organic matter release from soil by salt solutions

Laboratory experiments in soil columns were performed to study the influence of dissolved salts on the amount and composition of organic matter (OM) released from soil. Samples of two surface soils from former wastewater infiltration sites were leached with solutions containing dissolved salts (NaH₂PO₄, NaNO₃, CaCl₂) and by deionized water. The NaH₂PO₄ solution induced strongest release with 0.6% of soil organic carbon (C_org) with 700 ml for 100 g of soil, while CaCl₂ released the least, summing to 0.1–0.2% of C_org. The OM released was characterized by UV absorbance (aromaticity), ultrafiltration (molecular size distribution) and solid-phase extraction (polarity). The results suggest that CaCl₂ preferentially released readily soluble OM. For the other solutions we assume solubilization by enhanced electrostatic repulsion (water), sodium exchange (NaNO₃), and sodium exchange and calcium decomplexation and displacement of sorbed organic anions (NaH₂PO₄) to be the major mechanisms of release. In all experiments a phase of spontaneous desorption was observed, followed by a phase of steady-state desorption. Activation energies for steady-state release were estimated from kinetic investigations and suggest that the release is controlled by diffusion towards the phase boundary. These investigations emphasize the influence of dissolved salts on the nature and quantity of organic matter released from soil. The method presented seems able to characterize soil organic matter with respect to its availability and its mode of association with the soil matrix.     

Using time domain reflectometry to characterize cattle and pig slurry infiltration into soil

Abstract. The rate and extent to which cattle or pig slurry infiltrates into soil after application is one of the important factors determining the rate and extent of subsequent ammonia (NH₃) volatilization. Better characterization of the infiltration process is required to improve predictive models of NH₃ losses after land spreading. This paper describes a laboratory system using time domain reflectometry to measure slurry infiltration into soil columns. This system enabled semi-continuous, non-destructive infiltration measurements to be made, assessing the influence of slurry type, dry matter (DM) content, soil type and soil water tension. Differences were noted in the infiltration behaviour of cattle and pig slurries. For cattle slurry, DM content (range 1.7–7.1%) was the main influencing factor. Infiltration rate rapidly decreased with increasing DM content and there was no influence of soil type or water tension. For pig slurry, all of the slurry infiltrated into a sandy clay loam soil within the first hour, regardless of DM content (range 1.5–4.7%), whereas only 60% infiltrated into a clay loam soil over the same time period (slurry DM content 2.1%).     

Amelioration of saline–sodic soil with mildly saline water in the Songnen Plain, northeast China

Abstract. The saline–sodic soils of the dryland Songnen Plain in northeast China are only slowly permeable to fresh water because of their large content of montmorillinite clay and sodium bicarbonate. Use of slightly saline groundwater containing adequate dissolved calcium and magnesium for leaching and reclamation can potentially prevent dispersion of the clay soil particles during treatment. Amelioration was evaluated using shallow, mildly saline groundwater to irrigate sorghum–corn rotations in a two-year field experiment. After two growing seasons during which a total of 400 mm of leaching water was applied, in addition to some supplemental irrigation water, the average electrical conductivity (EC_e) of the top 1.2 m of the soil profile decreased from 14.5±3.5 to 2.7±0.2 dS m⁻¹, and the sodium absorption ratio (SAR_e) decreased from 35.3±4.1 to 10.1±2.5 (meq L⁻¹)^0.5. The soil physical properties were improved: infiltration rate with mildly saline groundwater increased from 12.1 to 42 mm h⁻¹. Salinity changes in the top 1.2 m of soil layers after 700 mm of leaching produced no further improvement. Crop yields produced on plots undergoing amelioration increased by 64–562% compared with the rainfed control. The improved soil conditions after leaching resulted in 59–548% greater crop yields.     

Denitrification in drained and undrained arable clay soil

Emissions of nitrous oxide (N₂O) and nitrogen gas (N₂) from denitrification were measured using the acetylene inhibition method on drained and undrained clay soil during November 1980-June 1981. Drainage limited denitrification to about 65% of losses from undrained soil. Emissions from the undrained soil were in the range 1 to 12 g N ha^–1 h^–1 while those from the drained soil ranged from 0.5 to 6 g N ha^–1 h^–1 giving estimated total losses (N₂O + N₂) of 14 and 9 kgN ha^–1.
Drainage also changed the fraction of nitrous oxide in the total denitrification product. During December, emissions from the drained soil (1.8±0.6 gN ha^–1 h^–1) were composed entirely of nitrous oxide, but losses from the undrained soil (2.7 ± 1.1 g N ha^–1 h^–1) were almost entirely in the form of nitrogen gas (the fraction of N₂O in the total loss was 0.02). In February denitrification declined in colder conditions and the emission of nitrous oxide from drained soil declined relative to nitrogen gas so that the fraction of N₂O was 0.03 on both drainage treatments. The delayed onset of N₂O reduction in the drained soil was related to oxygen and nitrate concentrations. Fertilizer applications in the spring gave rise to maximum rates of emission (5–12g N ha^–1 h^–1) with the balance shifting towards nitrous oxide production, so that the fraction of N₂O was 0.2–0.8 in April and May.     

IMAGE: a physically-based one dimensional irrigation management model for soil salinity control

Abstract. This paper describes a study of 37 farms in the Batinah region of Oman where fodder crops and date palms are grown using saline irrigation water. Soil water salinities (ε_s) range from 2 to 50 dS m^–1. Soil water salinity depends on irrigation water quality and management factors such as the amount and frequency of irrigation and the area of the irrigation basin relative to the vegetation canopy. An irrigation management model for soil salinity control IMAGE has been developed, based on the salt balance of the profile assuming that the ε_s is in equilibrium with the irrigation water. The input parameters required to run the model include the annual water application, irrigation interval, soil textural class, potential evaporation, the ratio of crop canopy to irrigation basin area and the salinity of irrigation water. Verification of the model using rather uncertain data from a survey of the farms showed that this simple approach predicted ε_s to within 2.5 dS m^–1 in 82% of cases. The model showed that ε_s was highly sensitive to the size of irrigation basin and the amount and scheduling of irrigation, and so provides a tool for optimizing salinity management.     

Myths of slash and burn on physical degradation of savannah soils: impacts on Vertisols in north Cameroon

Abstract. A study was conducted to assess the impact of agricultural land use history on macro-aggregate (4.0–4.8 mm) stability in the 0–5 cm layers of Chromic and 'Hydromorphic' Vertisols in north Cameroon. Macroaggregate stability to water drop impact was determined and the ASI₅₀ index calculated. Macroaggregates from fallow and zero-tilled cropped soils disaggregated in a stepwise manner. Macroaggregates from ploughed cropped soils collapsed in one step into semi-liquefied microaggregates and primary particles. On both soil types, the ASI₅₀ index of samples from ploughed land was 10.0 mJ, compared to 16.4– 21.9 mJ from zero-tilled slash and burn land use. The stepwise disintegration of macroaggregates indicated the existence of a hierarchy of aggregation within the size range 2–5 mm. Slash and burn land use on zero-tilled Vertisols significantly increased sand-sized organic carbon content and the stability of macroaggregates to water impact.     

Long-term effects of lantana residue additions on water retention and transmission properties of a medium-textured soil under rice–wheat cropping in northwest India

Abstract. Hydraulic properties of soils after rice cropping are generally unfavourable for wheat cultivation. Poor drainage, delayed planting and oxygen stress in the root zone may adversely affect the wheat crop after lowland rice cultivation. We studied long-term effects of lantana ( Lantana spp. L.) residue additions at 10, 20 and 30 t ha⁻¹ yr⁻¹ (fresh biomass) on physical properties of a silty clay loam soil under rice–wheat cropping in northwest India. At the end of ten cropping cycles, soil water retention, infiltration rate, saturated hydraulic conductivity and drying rate of soil increased significantly with lantana additions. The available water capacity (AWC), on volume basis, declined at rice harvest (from 22.0 to 18.8–20.9%), but increased at wheat harvest (from 12.9 to 13.4–15.0%) after lantana treatment. The volumes of water transmission (>50 μm) and storage pores (0.5–50 μm) were greater, while the volume of residual pores (<0.5 μm) was smaller in lantana-treated plots than in controls at both rice and wheat harvest. Infiltration rate in the lantana-treated soil was 1.6–7.9 times that of the control (61 mm d⁻¹) at rice harvest, and 2–4.1 times that of the control (1879 mm d⁻¹) at wheat harvest. Thus lantana addition improved soil hydraulic properties to the benefit of the wheat crop in a rice–wheat cropping sequence.     

Carbon mineralization in soil size fractions after various amounts of aggregate disruption

Aggregates (1–2mm) were subjected to shaking, increasing intensities of ultrasonification, or a peroxide treatment and then physically fractionated into sand-, silt- and clay-size fractions. CO₂ evolution was measured during a 20-day incubation of the sand-, silt- and clay-size fractions and was used to assess the decomposability of the organic matter within aggregates and associated with these size fractions.
All of the size fractions showed a large increase in the amount of readily decomposable C when the ultrasonic energy input increased from 300 to 500 J ml⁻¹ and disruption of microaggregates occurred. The data suggest that some readily decomposable organic matter is sequestered within microaggregates and protected from microbial attack.
Following complete dispersion, the C mineralized (mg C g⁻'C) upon incubation was greatest in the sand particles and least in the clay. The levels of potentially mineralizable C ( C ₀) in the sand-size fraction increased with increased dispersion energy whereas the mineralization rate (k) remained about the same. The levels of C₀ in the clay-size fraction decreased and the estimates of k increased abruptly upon the disruption of micro-aggregates.     

Soils as carbon sinks: the global context

Abstract. Soil carbon sequestration could meet at most about one-third of the current yearly increase in atmospheric CO₂-carbon, but the duration of the effect would be limited, with significant impacts lasting only 20–50 years. Coupled with this limited duration, increases in population and per-capita energy demand mean that soil carbon sequestration could play only a minor role in closing the difference between predicted and target carbon emissions by 2100. However, if atmospheric CO₂ concentrations are to be stabilized at reasonable levels (450–650 ppm), drastic reductions in carbon emissions will be required over the next 20–30 years. Given this, carbon sequestration should form a central role in any portfolio of measures to reduce atmospheric CO₂ concentrations over this crucial period, while new energy technologies are developed and implemented. International agreements, such as the Kyoto Protocol, encourage soil carbon sequestration and could be used to formulate soil carbon sequestration polices. Such policies need to take account of other environmental impacts as well as political, economic and societal needs, so that they form part of a raft of measures encouraging sustainable development. Of the carbon sequestration options available, those of a 'win–win' nature, that is, those that increase carbon stocks at the same time as improving other aspects of the environment, and those that protect or enhance existing stocks ('no regrets' implementation) show the greatest promise in meeting these goals.     

Three-dimensional mapping of salt stores in the southeast Murray–Darling Basin, Australia

Abstract. An airborne electromagnetic survey yields a three-dimensional map of ground electrical conductivity. The remotely sensed data are translated into salt load by field and laboratory calibration: drilling, measurement of borehole conductivity, electrical conductivity of 1:5 soil–water extracts (EC_1:5) and chemical analysis of pore fluids. Using these field measurements, the conductivity map is calibrated by constraining model parameters within limits defined by the measured values. Once the airborne data is calibrated, we can derive a regional constant ( K _salt) by comparing total ground conductivity with the mass of salt measured in bore samples. Pore fluid chemistry provides a definitive measure of salt, but EC_1:5 values may be used, provided that the procedure ensures complete dispersal of clay aggregates to release all the salt. Maps of salt load can be generated from the conductance (total conductivity) maps using a geographical information system. Without calibration, airborne electromagnetic surveying is misleading. Properly calibrated, it provides a detailed, semi-quantitative, three-dimensional map of the distribution of salt in the landscape: a prerequisite for the effective management of salinity. Salt appearing at the surface and in streams is the result of processes operating throughout entire catenas and groundwater flow systems. Across the southeastern catchments of the Murray–Darling Basin, we found that salt is stored predominantly in thick clay horizons within the regolith (encompassing the soil cover, weathered parent material and unlithified sediments down to unweathered basement). Coarse materials, for example in prior stream channels, may serve as conduits for salt transport to rivers and the land surface.     

Estimates of carbon stock changes in Belgian cropland

Abstract. Article 3.4 of the Kyoto Protocol allows carbon emissions to be offset by demonstrable removal of carbon from the atmosphere by improved management of agricultural soils. To make use of this possibility, a good estimate of soil organic carbon (SOC) stocks and baseline emissions (in 1990) are crucial factors. Over 210 000 topsoil (0–24 cm) measurements have been made in Belgian cropland in the period 1989–1999, which are available for seven different agro-pedological regions and for three periods (1989–91, 1992–95, 1996–99). We used this extensive SOC data set to estimate SOC stocks and fluxes in Belgian cropland. The measurements of SOC were extrapolated to 1 m depth using an exponential SOC depth distribution model, based on another large data set of over 5184 fully described soil profiles on Belgian cropland made during the National Soil Survey. The SOC data were combined with cropland area figures to calculate SOC stocks to 1 m depth. The 1990 baseline SOC flux of Belgian cropland was then obtained using two different calculation methods, which each yielded similar results and showed that SOC stocks were decreasing in the 1990s at a mean rate of 608 kton OC yr⁻¹. Consequently, a large part of the Belgian cropland acted as a net source of CO₂ emissions during the period 1989–1999.     

Heat pipe phenomenon in soil under reduced air pressure

We measured the heat flux, temperature distribution and water content of an unsaturated Ando soil under a constant temperature gradient and reduced air pressure to investigate the mechanism of latent heat transfer in the soil and its relationship to the distribution and circulation of soil water. As the air pressure decreased, the heat flux increased for the soil samples with an initial volumetric water content ( θ _ini) greater than 0.30 m³ m⁻³, but did not change for θ _ini less than 0.20. While the temperature gradient of the sample did not change for θ _ini greater than 0.30 m³ m⁻³, it did increase on the hotter side of the sample and decreased on the colder side for θ _ini less than 0.20. The water content did not change, and a homogeneous distribution of water content was observed for θ _ini greater than 0.30 m³ m⁻³. For θ _ini less than 0.20, the water content decreased on the hotter side and increased on the colder side, forming a large water content gradient. The large transfer of latent heat was caused by the circulation of water vapour and liquid water, which resulted in the homogeneous water distribution. We concluded that the soil functions as a heat pipe through a series of micro-heat pipes centred on the soil pores. Our experimental results will help to explain the transfer mechanism of latent heat in soil as a heat pipe phenomenon.