Chemico-Viscous Remanent Magnetization in the Fe3O4-yFe2O3 System

The chemical remanent magnetization (CRM) acquired when single-domain size magnetite (Fe(3)0(4)) oxidizes to maghemite (gammaFe(2)O(3)) in a 50-microtesla field at a series of 13 temperatures from 1000 to 6560C is of similar intensity to viscous remanent magnetization (VRM) acquired under the same field and temperature conditions by unoxidized magnetite. The remanences of the oxidized and unoxidized phases also have similar resistances to demagnetization. These similarities imply that the remanence of the oxidized material is a chemico-viscous remanent magnetization (CVRM) having some of the characteristics of both classic growth CRM and thermally activated VRM. At low temperatures in partially oxidized grains, VRM of the magnetite core and growth CRM of the maghemite surface layer contribute about equally to CVRM. Near the Curie point, intensity of CVRM increases to a Hopkinson-type peak. High-temperature CVRM is more resistant to demagnetization than the thermoremanent magnetization (TRM) produced from cooling through the Curie point.     

Monodomain theory: experimental verification

The Néel thermal-activation theory of remanence in monodomain grains has been verified quantitatively in experiments on four ferrite micropowders and two natural rocks. Magnetization and demagnetization curves of thermal, isothermal, viscous, and anhysteretic remanences can all be predicted with reasonable accuracy when the Neél theory is generalized to include effects of grain interaction. Results with the natural materials indicate that interacting, single-domain grains or regions are the carriers of the magnetically hard natural remanence of some paleomagnetic rocks.     

The remanent magnetization of lunar soils

The magnetic material in the lunar soils makes them potentially strong carriers of remanence and magnetically viscous. The soils therefore block remanence in the temperature range of the lunar diurnal cycle. This remanence is stable against alternating-field demagnetization. A mechanism whereby such hard natural remanent magnetization may be acquired by material buried in the regolith is proposed.     

Grain size--dependent alteration and the magnetization of oceanic basalts

Unblocking temperatures of natural remanent magnetization were found to extend well above the dominant Curie points in samples of oceanic basalts from the axis of the East Pacific Rise. This phenomenon is attributed to the natural presence in the basalts of three related magnetic phases: an abundant fine-grained and preferentially oxidized titanomagnetite that carries most of the natural remanent magnetism, a few coarser and less oxidized grains of titanomagnetite that account for most of the high-field magnetic properties, and a small contribution to both the natural remanent magnetism and high-field magnetic properties from magnetite that may be due to the disproportionation of the oxidized titanomagnetite under sea-floor conditions. This model is consistent with evidence from the Central Anomaly magnetic high that the original magnetization acquired by oceanic basalts upon cooling is rapidly altered and accounts for the lack of sensitivity of bulk rock magnetic parameters to the degree of alteration of the remanence carrier in oceanic basalts.     

Magnetite: Behavior near the Single-Domain Threshold

Maximum values for the single-domain threshold d(0) and superpara-magnetic threshold d(8) in pure magnetite are found to be 570+/-50 and 350+/-50 angstroms, respectively. Particles larger than do but smaller than about 0.25 micron have size-dependent saturation remanences and coercive forces like those of multidomain particles, but intense and stable thermoremanent magnetization like that of single-domain particles. The presence of magnetite grains in this size range could account for the essentially single-domain character of stable natural remanence in many volcanic and intrusive rocks.     

A mechanism for producing magnetic remanence in meteorites and lunar samples by cosmic-ray exposure

An irradiation of 3 x 1017 neutrons per square centimeter in a reactor core produced an increase in the coercive force of iron and kamacite of 16 to 21 percent. The alternating-current demagnetization spectrum of saturation isothermal remanence was shifted toward higher coercive forces. Similar neutron fluences produced by cosmic-ray exposure may be capable of converting soft isothermal remanence in meteorites and lunar samples to remanence with a higher coercive force.     

Magnetic properties of hydrothermally recrystallized magnetite crystals

The discrepancy between the magnetic hysteresis properties of magnetite crystals that are precipitated from solution (<0.3 micrometer) and of crushed sifted grains (>0.3 micrometer) is not an inherent property of magnetite but is caused by the highly stressed state of crushed material and by adhering finer fragments. The size trends of magnetic properties exhibited by submicrometer-size precipitated grains continue in the size range from 1 micrometer to 1 millimeter in a set of hydrothermally recrystallized magnetite crystals. Coercive forces of these narrowly sized crystals follow a power law over a wide size range (0.1 micrometer to 1 millimeter) as predicted by theory. Dislocation etch pits show similar dislocation densities for hydrothermally grown (3 x 10(10) meter (-2)) and natural (1 x 10(10) meter(-2)) magnetite crystals. Hysteresis parameters of hydrothermally grown crystals are similar to those of natural crystals but are about one-fifth of those for crushed grains.     

Hematite: intrinsic and defect ferromagnetism

Both intrinsic (spin-canted) ferromagnetism and defect ferromagnetism occur in hematite. Because defect ferromagnetism is sensitive to structure, it is altered by stress or heating and could give spurious paleomagnetic information. Annealing experiments now suggest that the defect remanence of fine-grain hematites and red sediments, unlike that of single crystals, is magnetically softer than the spin-canted remanence and can be erased by partial demagnetization.     

Environmental applications of magnetic measurements

A wide range of examples of the application of magnetic measurements to environmental studies illustrate the advantages of magnetic techniques over conventional methods. Magnetic measurements, in both the field and the laboratory, are particularly useful for reconnaissance work because of their spee and flexibility, Quantification as well as simple diagnosis of the transformation and movement of magnetic minerals within and between the atmosphere, lithosphere, and hydrosphere is practical. Techniques of investigating intrinsic and mineral magnetic properties, in addition to paleomagnetic remanence, are described in subjects as diverse as meteorology, hydrology, sedimentology, geophysics, and ecology.     

Viking magnetic properties investigation: preliminary results

Three permanent magnet arrays are aboard the Viking lander. By sol 35, one array, fixed on a photometric reference test chart on top of the lander, has clearly attracted magnetic particles from airborne dust; two other magnet arrays, one strong and one weak, incorporated in the backhoe of the surface sampler, have both extracted considerable magnetic mineral from the surface as a result of nine insertions associated with sample acquisition. The loose martian surface material around the landing site is judged to contain 3 to 7 percent highly magnetic mineral which, pending spectrophotometric study, is thought to be mainly magnetite.     

Origin of magnetization decay in spin-dependent tunnel junctions

Spin-dependent tunnel junctions based on magnetically hard and soft ferromagnetic layers separated by a thin insulating barrier have emerged as prime candidates for information storage. However, the observed instability of the magnetically hard reference layer, leading to magnetization decay during field cycling of the adjacent soft layer, is a serious concern for future device applications. Using Lorentz electron microscopy and micromagnetic simulations, the hard-layer decay was found to result from large fringing fields surrounding magnetic domain walls in the magnetically soft layer. The formation and motion of these walls causes statistical flipping of magnetic moments in randomly oriented grains of the hard layer, with a progressive trend toward disorder and eventual demagnetization.     

Rare gases in lunar samples: study of distribution and variafions by a microprobe technique

The rare gas distribution in lunar soil, breccias, and rocks was studied with a micro-helium-probe. Gases are concentrated in grain surfaces and originate from solar wind. Helium-4 concentrations of different mineral components vary by more than a factor of 10 apart from individual fluctuations for each type. Also grains with no detectable helium-4 exist. Titanium-rich components have the highest, calcium-rich minerals the lowest concentrations. The solar wind was redistributed by diffusion. Mean gas layer thicknesses are 10, 6, and 5 microm for helium, neon, and argon respectively. Lithic fragments in breccias contain no solar gases. Glass pitted surfaces of crystalline rocks contain about 10(-2) cubic centimeter of helium-4 per square centimeter. Etched dust grains clearly show spallogenic and radiogenic components. The apparent mean exposure age of dust is approximately 500 x 10(6) years, its potassium-argon age is approximately 3.5 x 10(9) yerars. Cavities of crystalline rocks contain helium-4, radiogenic argon, H(2), and N(2).     

Cryptic grain-scale heterogeneity of oxygen isotope ratios in metamorphic magnetite

Oxygen isotope ratios measured by ion microprobe in magnetite from granulite-facies marble of the Adirondack Mountains, New York, range from +2 to +11 per mil (standard mean ocean water) across a single grain that measures 3 millimeters by 5 millimeters. Low values are concentrated in irregular domains near the grain boundary but also occur in the grain's interior. In contrast, grains 1 millimeter in diameter that are from a second nearby sample show no significant heterogeneity, except within 10 micrometers of the grain boundary. These data, including large gradients of up to 9 per mil per 10 micrometers, provide important new constraints on the nature and origins of intragrain isotopic heterogeneity and on oxygen isotope thermometry. The differences between these magnetite grains result from contrasting mechanisms of isotope exchange with fluids after the peak of regional metamorphism. Volume diffusion of oxygen through the crystal structure of magnetite contributed to isotope exchange in the rims of small grains, but larger grains are crosscut by healed cracks that are not readily detected and that short-circuited diffusion.     

Topographic and magnetic-sensitive scanning tunneling microscope study of magnetite

The topographic and magnetic surface structure of a natural single crystal of magnetite (Fe(3)0(4)), a common mineral, has been studied from the submicrometer scale down to the atomic scale with a scanning tunneling microscope having nonmagnetic tungsten as well as ferromagnetic iron probe tips. Several different (001) crystal planes were imaged to atomic resolution with both kinds of tips. A selective imaging of the octahedrally coordinated Fe B-sites in the Fe-O planes, and even a selective imaging of the different magnetic ions Fe(2+) and Fe(3+), has been achieved, demonstrating for the first time that magnetic imaging can be realized at the atomic level.     

Formation of magnetic single-domain magnetite in ocean ridge basalts with implications for sea-floor magnetism

Although magnetic data are the primary evidence for ocean floor spreading, the processes by which magnetic phases in ocean floor basalts are formed remain poorly constrained. Scanning transmission electron microscopic observations show that magnetic single-domain magnetite in sheeted dike basalts of Deep Sea Drilling Project hole 504B formed through oxidation-exsolution of ilmenite, exsolution of ulv?spinel lamellae, and recrystallization of end-member magnetite by interaction with convecting fluids. The data suggest that the sheeted dike basalts, with single-domain magnetite as an efficient and stable magnetic carrier, contribute significantly to sea-floor magnetism.     

油气管道带磁原因及退磁方法

在油气长输管道维修更换作业中,为了缩短更换作业周期及减少剩磁对管道焊接质量的影响,需要对管道进行退磁作业。分析了导致油气管道带磁的原因:管道检测;外部存在磁场、电场;管道焊接与摩擦等。探讨了管道带磁对管道焊接、其他检测方法与管道寿命的影响。基于油气管道的退磁原理,提出3种管道退磁方法:直流退磁法、交流退磁法及永磁铁退磁法,以此提高油气管道在线焊接质量。研究结果对于工程实践中油气管道退磁方法的选择有一定的指导作用。     

Magnetic properties of lunar samples

The magnetic properties of samples of rock, fines, and magnetic separate from the fines from Apollo 11 have been measured. Native iron, or possibly nickel-iron, of submicroscopic particle size is the most important constituent, with minor contributions from ilmenite, paramagnetic iron minerals, and other iron-titanium oxides. The remanent magnetization of a sample of the micro-breccia rapidly acquires a viscous magnetization and does not appear to have a significant stable remanence. The crystalline sample has a weak natural remanence showing some stability.     

Lepidocrocite, an apatite mineral, and magnetic in teeth of chitons (Polyplacophora)

X-ray diffraction patterns show that the mature denticles of three extant chiton species are composed of the mineral lepidocrocite and an apatite mineral, probably francolite, in addition to magnetite. Each of the three minerals forms a discrete microarchitectural unit of the chiton denticles. This is the first indication that lepidocrocite is precipitated by marine organisms and an apatite mineral by chitons.     

基于仿人智能控制的长输管道新型退磁仪的智能化实现

对于年金的时间价值的研究,往往假定利率在整个期间内是固定不变的.但事实上,由于受到多种因素的影响,利率通常具有不确定性.因此,本文采用可逆MA(1)模型对随机利息力进行建模,在此基础上,研究了期末付虹式年金和期末付平顶虹式年金的时间价值问题,给出了上述两种形式年金现值的期望和方差的递推公式.通过数值仿真分析了相关参数对期末付虹式年金现值的期望值的影响,其结论对投资者的投资决策提供了参考依据.     

Magnetic properties of lunar dust and rock samples

Determinations on 20-to 80-milligram portions of the rock samples and the -150 mesh fraction of the lunar dust show pronounced Curie points between 680 degrees and 780 degrees C. Remanent intensities of five rock fragments vary from 8.4 x 10(-5) to 0.30 X J0(-5) emu/gram. Upon demagnetization, two of the samples had only viscous magnetization and two other samples had stable magnetizations with remanent coercivities in excess of 50 oersteds. Partial thermal demagnetization suggests that these apparently stable moments may have been acquired in a magnetic field in excess of 1500 gammas. xsxs.