Rare gases in lunar samples: study of distribution and variafions by a microprobe technique

The rare gas distribution in lunar soil, breccias, and rocks was studied with a micro-helium-probe. Gases are concentrated in grain surfaces and originate from solar wind. Helium-4 concentrations of different mineral components vary by more than a factor of 10 apart from individual fluctuations for each type. Also grains with no detectable helium-4 exist. Titanium-rich components have the highest, calcium-rich minerals the lowest concentrations. The solar wind was redistributed by diffusion. Mean gas layer thicknesses are 10, 6, and 5 microm for helium, neon, and argon respectively. Lithic fragments in breccias contain no solar gases. Glass pitted surfaces of crystalline rocks contain about 10(-2) cubic centimeter of helium-4 per square centimeter. Etched dust grains clearly show spallogenic and radiogenic components. The apparent mean exposure age of dust is approximately 500 x 10(6) years, its potassium-argon age is approximately 3.5 x 10(9) yerars. Cavities of crystalline rocks contain helium-4, radiogenic argon, H(2), and N(2).     

Gas-retention and cosmic-ray exposure ages of lunar rock 15555

The last lava flow in the Hadley Rille area of Mare Imbrium, as inferred from an argon-40-argon-39 experiment on a plagioclase separate from the lunar basalt 15555, occurred 3.31+/-0.03x10(9) years ago. An argon-40-argon-39 experiment on a whole rock sample shows significant loss of radiogenic argon-40 and yields a well-defined, high-temperature plateau indicating a lower age of 3.22+/-0.03x10(9) years. A cosmic-ray exposure age of 90+/-10x10(6) years is determined from the ratio of spallogenic argon-38 to calcium.     

Very heavy solar cosmic rays: energy spectrum and implications for lunar erosion

The energy spectrum of solar cosmic-ray particles of the iron group has been determined for the first time over the energy range from 1 to 100 million electron volts per nucleon by the use of glass removed from the Surveyor 3 spacecraft. The difference between the observed (energy)(-3) spectrum and the limiting spectrum derived previously from tracks in lunar rocks gives an erosion rate of 0 to 2 angstroms per year. High-energy fission of lead, induced by galactic cosmicray protons and alpha particles, has also been observed.     

Apollo 11 solar wind composition experiment: first results

The helium-4 solar wind flux during the Apollo 11 lunar surface excursion was (6.3 +/- 1.2) x 10(6) atoms per square centimeter per second. The solar wind direction and energy are essentially not perturbed by the moon. Evidence for a lunar solar wind albedo was found.     

Major and trace elements and cosmic-ray produced radioisotopes in lunar samples

Analytical data for 42 major and trace elements were mostly obtained by a combination of instrumental and radiochemical neutron activation analyses using both thermal and 14-million-electronvolt neutrons. Excesses of nitrogen and chlorine in the fines, compared with the rocks, are attributed to the solar wind. A striking similarity for contents of seven elements in lunar metal and metal from the calcium-rich achondrite Juvinas was noted. Fractional dissolution was used to separate five radionuclides produced by cosmic-ray bombardment in the fines and rock 57-40. Results for argon-39 from the reaction potassium-39 (n,p), and for argon-37, from the reaction calcium-40 (n,a), seem to require a neutron spectrum conitaining more neutrons below 2 million electronvolts than the evaporation spectrum or that given by Arnold, Honda, and Lal (1) or a strong time dependence for the neutron flux.     

Vesicle-Specific Noble Gas Analyses of "Popping Rock": Implications for Primordial Noble Gases in Earth

Gases trapped in individual vesicles in the volatile-rich basaltic glass "popping rock" were found to have the same carbon dioxide, helium-4, and argon-40 composition, but a variable 40Ar/36Ar ratio ( approximately 4000 to >/=40,000). The argon-36 is probably surface-adsorbed atmospheric argon; any mantle argon-36 trapped in the vesicles cannot be distinguished from an atmospheric contaminant. Consequently the 40Ar/36Ar ratios and 3He/36Ar ratios (1.45) determined are minimum estimates of the upper mantle composition. Heavy noble gas relative abundances in the mantle resemble solar noble gas abundance patterns, and a solar origin may be common to all primordial mantle noble gases.     

Gas analysis of the lunar surface

The rare gas analysis of the lunar surface has lead to important conclusions concerning the moon. The large amounts of rare gases found in the lunar soil and breccia indicate that the solar atmosphere is trapped in the lunar soil as no other source of such large amounts of gas is known. The cosmogenic products indicate that the exposure ages of the 17 lunar rocks measured vary from 20 to 400 million years with some grouping of the ages. The most striking feature is the old potassium-argon age which for the 14 rocks analyzed varies from 2.5 to 3.8 billion years. It is concluded that Mare Tranquillitatis crystallized about 4 billion years ago from a molten state produced by a large meteorite impact or volcanic flow.     

Cosmic ray production of rare gas radioactivities and tritium in lunar material

The argon radioactivities (37)Ar and (39)Ar were obtained by vacuum melting from interior and exterior portions of rock 10057 and from a portion of the fines from the bulk sample container. The release of argon and tritium as a function of the temperature was followed for the fine material. A comparison is made of the activities observed in the lunar samples with those expected from the spallation of iron, titanium, and calcium. From these data and the (38)Ar content, the cosmic ray exposure age of rock 10057 is deduced as 110 x 10(6) years.     

Cosmic-ray record in solar system matter

The energetic nuclei in cosmic rays interact with meteoroids, the moon, planets, and other solar system matter. The nuclides and heavy nuclei tracks produced by the cosmic-ray particles in these targets contain a wealth of information about the history of the objects and temporal and spatial variations in the particle fluxes. Most lunar samples and meny meteorites have complex histories of cosmicray exposure from erosion, gardening, fragmentation, orbital changes, and other processes. There appear to be variations in the past fluxes of solar particles, and possibly also galactic cosmic rays, on time scales of 10(4) to 10(7) years.     

Rare gas isotopes in hawaiian ultramafic nodules and volcanic rocks: constraint on genetic relationships

Differences in the rare gas isotopic ratios, especially the ratios of helium-3 to helium-4 and of argon-40 to argon-36, in Hawaiian ultramafic nodules and phenocrysts in volcanic rocks indicate that the nodules and phenocrysts were derived from different sources. The isotopic ratios in ultramafic nodules are similar to those in oceanic tholeiites. The phenocrysts seem to have formed in equilibrium with source materials richer in primordial components than those of the oceanic tholeiites. Mixing between the sources is quite likely.     

Lunar atmosphere as a source of argon-40 and other lunar surface elements

The lunar atmosphere is the likely source of excess argon-40 in lunar surface material; about 8.5 percent of the argon-40 released into the lunar atmosphere will be implanted in the surface material by photoionization and subsequent interaction with fields in the solar wind. The atmosphere is also likely to be the source of other unexpected surface elements or of solar wind elements that impact from non-solar wind directions.     

Composition and structure of the venus atmosphere: results from pioneer venus

Results from the Pioneer Venus sounder probe neutral mass spectrometer indicate that there is no difference in the isotopic ratios of carbon and oxygen between Venus and Earth to within +/- 5 percent. The mixing ratio of nitrogen is 3.5(+3)(-2) percent with an isotopic ratio within 20 percent of that of Earth. The ratio of argon-36 to argon-40 is 85 percent, and the ratio of argon-38 to argon-36 is 20 percent. The mixing ratios of argon-36 and argon-40 are approximately 40 and 50 parts per million, respectively, with an error of about a factor of 2 (mainly toward a lesser amount) resulting from uncertainty in the response of the ion pump to rare gases. Hydrogen chloride cannot account for more than a few percent of the 36 mass peak, and therefore the large excess of primordial argon is a reasonable conclusion. The ratio of neon-20 to argon-36 of 0.5 +/- 0.3 is definitely terrestrial in character rather than solar. These results indicate that there is a large excess of all primordial noble gases on Venus relative to Earth. There appears to be a considerably higher abundance of sulfur compounds below 20 kilometers than in or above the main cloud layer. The 32 and 60 mass peaks show a sharp increase below 22 kilometers, indicating the possible production of sulfur and carbon oxysulfide (COS) at the expense of sulfur dioxide.     

Solid state studies of the radiation history of lunar samples

Particle track densities up to > 3 x 10(9) per square centimeter have been measured in different samples. Rocks 17, 47, 57, and 58 have VH (Z >22) galactic cosmic ray ages of 11, 14, 28, and 13 x 10(6) years, respectively. Rock 57 has a calculated erosion rate of 10(-7) centimeter per year. Near-surface track versus depth data in rock 17 can be fit with solar flare particles that have a differential energy spectrum aE(-3); lunar samples can be used to study the history of solar activity. The uranium in the crystalline rocks occurs principally in small regions <10 to approximately 100 micrometers in size. The (low) thermoluminescence of the fines increases with depth in core 10004. With one possible exception, x-ray studies have not shown pronounced radiation damage effects. The total energy release upon heating is small up to 900 degrees C and occurs in three broad regions.     

Composition of the atmosphere at the surface of Mars: detection of argon-36 and preliminary analysis

The composition of the martian atmosphere was determined by the mass spectrometer in the molecular analysis experiment. The presence of argon and nitrogen was confirmed and a value of 1 to 2750 +/- 500 for the ratio of argon-36 to argon-40 was established. A preliminary interpretation of these results suggests that Mars had a slightly more massive atmosphere in the past, but that much less total outgassing has occurred on Mars than on Earth.     

Oxygen, Silicon, and Aluminum in Lunar Samples by 14 MeV Neutron Activation

Abundances of oxygen, silicon, and altiminutm in 27 lunar rocks and C aliquants of lunar soil have been determined by 14 MeV neutron activation. Mean abundances and standard deviations of individual abundances (in weight percent) within each type are: type A (2 rocks), 38.5 +/- 1.2 oxygen, 18.9 +/- 0.8 silicon, and 4.0 +/- 0.4 aluminum; type B (7 rocks), 39.4 +/- 1.0 oxygen, 18.7 +/- 0.8 silicon, and 5.0 +/- 0.6 aluminum; type C (18 rocks), 41.1 +/- 1.0 oxygen, 19.7 +/- 0.7 silicon, and 6.6 +/- 0.5 aluminum; soil (3 aliquants), 40.8 +/- 1.2 oxygen, 20.2 +/- 0.2 silicon, and 7.2 +/- 0.1 aluminum. Oxygen abundances are lower than those in most common terrestrial rocks and are comparable to those found in certain types of stony meteorites. From these results the lunar soil is most similar to the type C lunar rocks.     

Ages of crystalline rocks from fra mauro

Crystallization ages for six rocks from Fra Mauro have been measured by the argon-40-argon-39 method. All six rocks give an age of 3.77 +/- 0.15 x 10(9) years, which is the same as for fragmental rocks from this site. It is concluded that the Imbrium event and the crystallization of a significant portion of the pre-Imbrian basalts were essentially contemporaneous.     

Cosmic-Ray Exposure Age of the Farmington Meteorite from Radioactive Isotopes

The cosmic-ray exposure age of the Farmington meteorite was found to be greater than 7000 years from the ratio of the carbon-14 and argon-39 present and less than 25,000 years from the ratio of the aluminum-26 and argon-39 present. This exposure age is about an order of magnitude smaller than was estimated previously.     

Primordial radioelements and cosmogenic radionuclides in lunar samples from apollo 15

Two basalts, two breccias, and two soils from Apollo 15 were analyzed by nondestructive gamma-ray spectrometry. The concentrations of potassium, thorium, and uranium in the basalts were similar to those in the Apollo 12 basalts, but the potassium: uranium ratios were somewhat higher. Primordial radioelements were enriched in the soils and breccia, consistent with a two-component mixture of mare basalt and up to 20 percent foreign component (KREEP). The abundance patterns for cosmogenic radionuclides implied surface sampling for all specimens. The galactic cosmic-ray production rate of vanadium-48 was determined as 57 +/- 11 disintegrations per minute per kilogram of iron. Cobalt-56 concentrations were used to estimate the intensity of the solar flare of 25 January 1971.     

Of time and the moon

Considerable information concerning lunar chronology has been obtained by the study of rocks and soil returned by the Apollo 11 and Apollo 12 missions. It has been shown that at the time the moon, earth, and solar system were formed, approximately 4.6 approximately 10(9) years ago, a severe chemical fractionation took place, resulting in depletion of relatively volatile elements such as Rb and Pb from the sources of the lunar rocks studied. It is very likely that much of this material was lost to interplanetary space, although some of the loss may be associated with internal chemical differentiation of the moon. It has also been shown that igneous processes have enriched some regions of the moon in lithophile elements such as Rb, U, and Ba, very early in lunar history, within 100 million years of its formation. Subsequent igneous and metamorphic activity occurred over a long period of time; mare volcanism of the Apollo 11 and Apollo 12 sites occurred at distinctly different times, 3.6 approximately 10(9) and 3.3 approximately 10(9) years ago, respectively. Consequently, lunar magmatism and remanent magnetism cannot be explained in terms of a unique event, such as a close approach to the earth at a time of lunar capture. It is likely that these phenomena will require explanation in terms of internal lunar processes, operative to a considerable depth in the moon, over a long period of time. These data, together with the low present internal temperatures of the moon, inferred from measurements of lunar electrical conductivity, impose severe constraints on acceptable thermal histories of the moon. Progress is being made toward understanding lunar surface properties by use of the effects of particle bombardment of the lunar surface (solar wind, solar flare particles, galactic cosmic rays). It has been shown that the rate of micrometeorite erosion is very low (angstroms per year) and that lunar rocks and soil have been within approximately a meter of the lunar surface for hundreds of millions of years. Future work will require sampling distinctly different regions of the moon in order to provide data concerning other important lunar events, such as the time of formation of the highland regions and of the mare basins, and of the extent to which lunar volcanism has persisted subsequent to the first third of lunar history. This work will require a sufficient number of Apollo landings, and any further cancellation of Apollo missions will jeopardize this unique opportunity to study the development of a planetary body from its beginning. Such a study is fundamental to our understanding of the earth and other planets.     

Particle Track, X-ray, Thermal, and Mass Spectrometric Studies of Lunar Material

Particle tracks in Apollo 11 samples are dominantly of cosmic ray and solar origin: primary galactic and solar flare particles, likely spallation recoil tracks, and possible solar-wind heavy particles. The energy spectrum of irongroup nuclei is inferred from track density gradients in surface layers, and a limit of < 10(-7) centimeter per year is deduced for the surface erosion rate. From cosmic ray tracks in rock and core samples it is clear that the lunar soil is stirred often during each few million years. X-rays reveal augite, anorthite, olivine, ilmenite, troilite, nonmeteoritic iron, and assorted glasses, but no major structural damage. Hydrogen, helium, and other gases in the fines are compatible with expected solar wind ratios.