Beryllium Chemistry in the Lysina Catchment,Czech Republic

The environmental chemistry of beryllium (Be) was investigated at the Lysina catchment in western Bohemia, Czech Republic, a forest ecosystem with high loadings of acidic atmospheric deposition. The catchment supports Norway spruce plantations; it is underlain by leucogranite and the soils are Spodosols. Average concentrations of Be were high in groundwater (3.3 µg L-1) and in stream water (1.5 µg L-1), in comparison to the drinking water standard of the Czech Republic (0.2 µg L-1). Chemical equilibrium calculations suggest that aquoberyllium Be2+ was the prevailing inorganic species in drainage waters at the site. Atmospheric deposition of Be (45 µg m-2 yr-1) was small in comparison to drainage outflow (586 µg m-2 yr-1) at Lysina. Elevated Be concentrations in drainage water appear to be the result of the mobilization of Be from soils and weathered bedrock due to acidic atmospheric deposition. Increased mobility of Be due to acidification may have serious ecological consequences in acid-sensitive areas with terrestrial pools of available Be.     

Reservoirs' siltation measurments and sediment transport assessment in the Czech Republic,the Vrchlice catchment study

Sediment transport from agricultural land into rivers and reservoirs is a problem within the Czech Republic. This problem was highly accelerated almost 50 years ago during the communist period. At that time strong collectivization was undertaken leading to destruction of traditional landscape patterns, surface outflow, erosion processes intensification and surface water quality deterioration. Thirteen years after political changes erosion problems remain.At the Department of Irrigation, Drainage and Landscape Engineering at the CTU Prague there has been continuous research undertaken in the field of erosion and sediment transport assessment. There are several modelling tools available for this purpose. One of them—USLE (Universal Soil Loss Equation) is commonly used in the Czech Republic for many years at a plot-scale but modern GIS (geographical information systems) tools in computer science allow using it at larger scales. Very important is the validation of this model for two-dimensional topography and GIS routines. Moreover USLE produces only local erosion amount values and has to be completed by another tool to get sediment amounts. For this purpose SDR (sediment delivery ratio) is usually used, applying a lumped approach—total erosion of every watershed is reduced by SDR and by pond’s trapping efficiency. Another available approach is using the Watem/SEDEM model that puts together RUSLE (Revised USLE) and a distributive approach to sediment transport modelling. This has already been used for estimating sediment amount in several catchments of the Czech Republic, but has to be validated as well.At the Dept. of Drainage, Irrigation and Landscape Engineering there are datasets of sediment amount from different reservoirs available and other reservoirs are to be measured soon. As the dataset of various watersheds is expanded, a methodology for sediment amount measurements is needed. The main objective of this paper is to propose a simple methodology to measure the sediment amount within reservoirs as well as to present a review of available methods. The application of the methodology at Vrchlice Catchments (97 km²) case study is presented. Total sediment amounts between 125 000∼140 000 m³ were measured in Vrchlice reservoir and values of 110 976 m³ (using USLE), resp. 105833 m³ (using Watem/SEDEM) were predicted by the erosion models. For catchments of this scale it is a sufficient validation.     

Reservoirs' siltation measurments and sediment transport assessment in the Czech Republic, the Vrchlice catchment study

Sediment transport from agricultural land into rivers and reservoirs is a problem within the Czech Republic. This problem was highly accelerated almost 50 years ago during the communist period. At that time strong collectivization was undertaken leading to destruction of traditional landscape patterns, surface outflow, erosion processes intensification and surface water quality deterioration. Thirteen years after political changes erosion problems remain.At the Department of Irrigation, Drainage and Landscape Engineering at the CTU Prague there has been continuous research undertaken in the field of erosion and sediment transport assessment. There are several modelling tools available for this purpose. One of them—USLE (Universal Soil Loss Equation) is commonly used in the Czech Republic for many years at a plot-scale but modern GIS (geographical information systems) tools in computer science allow using it at larger scales. Very important is the validation of this model for two-dimensional topography and GIS routines. Moreover USLE produces only local erosion amount values and has to be completed by another tool to get sediment amounts. For this purpose SDR (sediment delivery ratio) is usually used, applying a lumped approach—total erosion of every watershed is reduced by SDR and by pond’s trapping efficiency. Another available approach is using the Watem/SEDEM model that puts together RUSLE (Revised USLE) and a distributive approach to sediment transport modelling. This has already been used for estimating sediment amount in several catchments of the Czech Republic, but has to be validated as well.At the Dept. of Drainage, Irrigation and Landscape Engineering there are datasets of sediment amount from different reservoirs available and other reservoirs are to be measured soon. As the dataset of various watersheds is expanded, a methodology for sediment amount measurements is needed. The main objective of this paper is to propose a simple methodology to measure the sediment amount within reservoirs as well as to present a review of available methods. The application of the methodology at Vrchlice Catchments (97 km²) case study is presented. Total sediment amounts between 125 000140 000 m³ were measured in Vrchlice reservoir and values of 110 976 m³ (using USLE), resp. 105833 m³ (using Watem/SEDEM) were predicted by the erosion models. For catchments of this scale it is a sufficient validation.     

Biogeochemistry of aluminum in a forest catchment in the Czech Republic impacted by atmospheric inputs of strong acids

The Lysina catchment in the Czech Republic was studied to investigate the biogeochemical response of Al to high loadings of acidic deposition. The catchment supports Norway spruce plantations and is underlain by granite and podzolic soil. Atmospheric deposition to the site was characterized by high H⁺ and SO₄ ^2– fluxes in throughfall. The volume-weighted average concentration of total Al (Al_t) was 28 mol L^–1 in the O horizon soil solution. About 50% of Al_t in the O horizon was in the form of potentially-toxic inorganic monomeric Al (Al_i). In the E horizon, Al_t increased to 71 mol L^–1, and Al_i comprised 80% of Al_t. The concentration of Al_t (120 mol L^–1) and the fraction of Al_i (85%) increased in the lower mineral soil due to increases in Al_i and decreases in organic monomeric Al (Al_o). Shallow ground water was less acidic and had lower Al_t concentration (29 mol L^–1). The volume-weighted average concentration of Al_t was extremely high in stream water (60 mol L^–1) with Al_i accounting for about 60% of Al_t. The major species of Al_i in stream water were fluorocomplexes (Al-F) and aquo Al³⁺. Soil solutions in the root zone were undersaturated with respect to all Al-bearing mineral phases. However, stream water exhibited Al_i concentrations close to solubility with jurbanite. Acidic waters and elevated Al concentrations reflected the limited supply of basic cations on the soil exchange complex and slow weathering, which was unable to neutralize atmospheric inputs of strong acids.     

Spatial variation and interaction of runoff generation and erosion within a semi-arid, complex terrain catchment: a hierarchical approach

Purpose

Closed erosion plots have been used extensively to investigate soil loss and its spatial variation within a watershed. However, erosion rates measured on closed plots at various locations within a watershed may not reflect the “real world” conditions due to plot boundary problems. The purpose of this study was to identify runoff and sediment sources in a semi-arid, complex terrain catchment by using the data collected from open plots, nested catchments, and tunnel systems.

Materials and methods

The study catchment, in the Loess Plateau of China, was partitioned into various-level geomorphic units. Runoff and sediment discharges were measured from 55 storm events between 1963 and 1968 on open plots and nested catchments. Storm flows were also monitored in 14 rainfall events from the tunnel systems between 1989 and 1990. This study combined the data collected from the two periods to investigate runoff and sediment sources from the different geomorphic units of the catchment.

Results and discussion

On the four open plots (S1, S2, S3, and S4) of the hill slope, total runoff depths of 128.5 mm (S1), 84.3 mm (S2), 101.92 mm (S3), and 141.73 mm (S4) were recorded from all the events over the first period, which correspondingly produced total sediment yields of 3.056 kg m^?2 (S1), 9.058 kg m^?2 (S1), 42.848 kg m^?2 (S3), and 97.256 kg m^?2 (S4). The number of runoff events also varied due to a non-uniformity in runoff generation among the different geomorphic units of the catchment. Tunnel flows generally had higher mean sediment concentrations than catchment outflows. Three nested catchments located from the headwaters (C1) to the mouth of the catchment (C3) generated total runoff depths of 120.02 mm (C1), 143.92 mm (C2), and 149.43 mm (C3), and correspondingly produced sediments yields of 62.01 kg m^?2 (C1), 144.02 kg m^?2 (C2), and 123.92 kg m^?2 (C3) for the first period.

Conclusions

Significant variations in runoff and erosion existed within the catchment. The spatial variation of runoff generation on the hill slopes resulted from the variation of soil infiltration. Sediment produced from the lower hill slope zone was disproportionally higher than that from the upper hill slope zone. Nevertheless, a significant portion of the sediment eroded on the lower slope zone was caused by runoff generated from the upper slope zone. Tunnel erosion also played a significant role in sediment production.     

A multi-scale approach of runoff generation in a Sahelian gully catchment: a case study in Niger

Runoff production conditions in a small gully catchment are studied at four different scales: the point scale (0.001 m²), the local scale (1 m²), the field scale (of the order of 100 m²) and the catchment scale (0.2 km²). At the point scale, infiltration measurements were conducted using a tension infiltrometer. At the local and the field scale, runoff plots were setup on typical soil surface conditions of the catchment (plateau bare soil, hillslope bare soil and fallow grassland). At the catchment scale, stream discharges were measured at two gauging stations.The overland flow yield is significantly nonuniform in space, due to the high spatial variability of infiltration capacities and the depressional storage of the soil surface. The runoff and the infiltration data collected confirmed the major role played by soil crusting on runoff generation in that part of Sahel. At the point scale, hydraulic conductivity measurements have shown that infiltration and runoff were driven by the hydraulic properties of the crust. At the field scale, microtopography and heterogeneity in the soil surface crusting decreased discharge volumes. The influence of vegetation growth on runoff yield was evident in the case of the fallow sites. Analysis of discharge data at the catchment scale highlights that infiltration through the bottom of the gully between two gauging stations leads to considerable runoff water transmission losses.     

Relationships among rainfall, runoff, and suspended sediment in a small catchment with badlands

The Araguás Catchment of the Central Spanish Pyrenees has been monitored since 2004 to study weathering, erosion, and the hydrological and sediment response to rainfall events in order to understand the hydromorphological dynamics of a badland area in a relatively humid environment. This small catchment (0.45 km²) shows highly active processes of physical and chemical weathering related to seasonal variations in temperature and moisture. Erosion and sediment transport are widely studied in badlands within Mediterranean environments because they represent the dominant sediment source. To obtain information about suspended sediment and discharge, a gauging station was installed within the Araguás Catchment during the summer of 2005. The aim of this work is to determine the relationships among rainfall, runoff, and suspended sediment in this badland area. Towards this goal, we analyze the relationships between suspended sediment concentration and discharge during rainfall events.From a hydrological viewpoint, the Araguás Catchment reacts to all rainfall events with torrential flow being the most characteristic hydrological response. The results obtained between October 2005 and April 2007 reveal extremely high concentrations of suspended sediment, with values frequently exceeding 100 g l^{<modINS>−<!--[/INS]"> 1} and reaching a maximum of 1200 g l^{<modINS>−<!--[/INS]"> 1}. Three different types of hysteretic loops were observed: clockwise (22 events, 28%), counter-clockwise (27 events, 34%), and figure-eight (12 events, 15%). Moreover, 23% of events were classified as complex hysteretic loops and removed from the analysis due to their complexity. Clockwise hysteretic floods are characterized by their long duration and the highest hydrological and sedimentological responses; counter-clockwise hysteretic floods are characterized by their short duration and moderate hydrological and sediment responses; finally, figure-eight hysteretic floods are related to multiple peaks in suspended sediment, coinciding with oscillations in discharge associated with the highest rainfall intensities within each event and moderate hydrological and sediment responses.     

Recovery of acidified catchments in the extremely polluted Krusne hory Mountains,Czech Republic

Runoff and atmospheric chemistry in the Krusne hory Mts. have changed significantly from 1978 to 1994. Forest die-back related deforestation resulted in decreased dry deposition of SO₂ and changes in streamwater chemical composition. Atmospheric sulphur (S) deposition decreased from extremely high values of 66.6 kg S ha^?1 year^?1, in the early 1980s to 35.5 kg S ha^?1 year^?1 in 1994. Decreasing S input is reflected in decrease of streamwater sulphate (SO₄ ^2?) concentrations, which decreased from 1560 μeq l^?1 to 1164 μeq l^?1. Runoff export of S was 53 kg S ha^?1 year^?1 in 1993, S is not retained in the catchments. Nitrogen (N) budget indicates accumulation in the catchment, which is attributed to forest regrowth.     

土壤结皮对降雨入渗和产流产沙的影响

 依据250场次人工降雨和相应的径流、泥沙资料,采用对比法,分析结皮与无结皮土壤对降雨入渗和产流产沙的影响。结果表明,非结皮土壤的平均入渗率是结皮土壤的1.25倍,平均产沙总量为1.28倍,而结皮土壤的平均产流总量是非结皮土壤的1.15倍。因此,土壤结皮具有减缓降雨入渗、增大地表径流和抑制产沙的作用,且雨强愈小影响作用愈大,雨强愈大,影响作用愈小。     

Runoff generation in an intensively disturbed,abandoned farmland catchment,Central Spanish Pyrenees

This paper studies the hydrological response to rainstorm events of a small experimental catchment in the Central Spanish Pyrenees. The Arnás catchment was cultivated until 40 years ago, and then abandoned and affected by plant recolonisation, especially shrubs. A rainfall of a few millimeters is enough to produce a sudden increase in discharge, due most probably to the steep gradients and the small size of the catchment and the extensive areas with low vegetation density and thin soils. The intensity of the response shows a very high variability, depending on the intensity of precipitation and soil humidity conditions before the flood. This paper identifies two types of floods according to the relationships between precipitation and discharge, and confirms that antecedent soil moisture explains much of the response. The shape of the hydrograph, very similar to the hyetograph, suggests that the Arnás catchment is dominated by overland flow processes. However, more intense rainstorms do not generate higher peak flows, thus demonstrating the existence of different runoff-generating areas.     

Influx and concentration of triazine pesticides in the Amaterska cave system,Moravian Karst,Czech Republic

Purpose

The aim of this study was to detect three triazine pesticides and their metabolites in the drip water and the sediment of the Amaterska cave system. Diversity of the bacterial community in the sediment was also assessed, and the potential role of bacteria in degradation of these pesticides was evaluated.

Materials and methods

Triazines and their metabolites were analyzed in the soil, drip water, and sediment of the Amaterska cave system area in seven sampling sites (S1–S7) based on the above ground cover that included forest, permanent grassland, and agriculture cropland. The bacterial community in the cave sediments (S1–S6) was also analyzed using the Illumina sequencing of the V3 and V4 regions of 16S rDNA.

Results and discussion

Triazines were present in the soil and drip water in all sites below grassland and agricultural land but not under the forest area. Only atrazine metabolites were detected in the surface soil. In contrast, atrazine was detected in all cave sediments regardless of above ground cover, and this is likely due to the occasional alluvial influx. The overall prevalence of bacteria potentially capable of atrazine degradation in the cave sediment ranged from 13.4 to 64.0% of the entire bacterial community. The concentrations of atrazine in the cave sediment were 16 to 70 times higher than in those in drip water.

Conclusions

High concentrations of atrazine in the cave sediment indicate a slow degradation rate of triazines in the cave likely due to low temperatures and absence of photolysis. The main source of atrazine in the Amaterska cave system is likely not drip water but the alluvial influx. Bacteria potentially capable of triazine degradation in the cave sediment were detected; however, their role in this process remains to be investigated.

     

Historical Changes in Levels of Organic Pollutants in Sediment Cores from Brno Reservoir, Czech Republic

Results of a comprehensive study are presented on the spatial and depth-related distribution of persistent organic pollutants (POPs) in sediments of the Brno reservoir, Czech Republic. Based on sedimentological observations, three major historic phases were identified related to the evolution of the depositional environment, flow rate, and material input. Data on organic carbon, polycyclic aromatic hydrocarbons, polychlorinated biphenyls, and organochlorine pesticides showed specific distribution patterns in a 3-m-deep core. The analysis of the depth trends of the geochemical data combined with sedimentology made it possible to distinguish between remote sources of the pollutants, early weathering alterations of POPs, transport by river associated with organic matter as sorbent on one hand, and local sources weakly related to lithology on the other hand. The integrated sedimentological and environmental geochemical archive provided an improved dynamic view of the pollution in historical terms.     

Reducing runoff by managing crop location at the catchment level,considering agronomic constraints at farm level

Runoff and erosion cause frequent damage through muddy floods in the loess belt of Northern Europe. One possibility for reducing damage is to lower runoff on agricultural land by spatially alternating different crops at the catchment level. But crop location results from decisions taken at the farm level. This study aimed to assess the existing leeway to modify crop location in the farms of a catchment, in order to reduce runoff at the catchment's outlet. The case study was the Bourville catchment (1086 ha), cultivated by 28 farmers and located in Pays de Caux, France. First, crop location rules in the 14 main farms of the catchment were analysed on the basis of surveys carried out with farmers, distinguishing spatial constraints from temporal ones. These rules made it possible to simulate crop location on each farm territory for the 2001–2002 crop year. Each field of the catchment was classified depending on whether one or several crops could be sown, taking into account both field history and farmer decision rules. Then two extreme scenarios of crop location in the Bourville catchment were built. Runoff simulation at the outlet with the STREAM model showed that runoff could be reduced while sticking to current farmer decision rules in terms of crop location. Depending on rainfall event characteristics, runoff reduction varied between 13·5 per cent and 4·5 per cent. Copyright © 2006 John Wiley & Sons, Ltd.     

Effect of drought on yield variability of key crops in Czech Republic

The relationship between seasonal agricultural drought and detrended yields (within a period from 1961 to 2000) of selected crops was assessed in the conditions of the Czech Republic, which are to some extent representative of a wider area of Central Europe. Impact of water stress was analyzed using time series of yields for 8 crops (spring barley, winter wheat, grain maize, potato, winter rape, oats, winter rye and hay from permanent meadows) for 77 districts in the Czech Republic (average district area is 1025 km²). Relative version of Palmer’s Z-index (rZ-index or rZ-i) was used as a tool for quantification of agricultural drought. The monthly values of the rZ-index for each individual district were calculated as the spatial average (only for the grids of arable land). The study showed that severe droughts (e.g., in 1981 and 2000) are linked with significant reduction in yields of the main cereals and majority of other crops through the most drought prone regions. We found a statistically significant correlation (p ≤ 0.05) between the sum of the rZ-index for the main growing period of each crop and the yield departures of spring barley within 81% (winter wheat in 57%, maize in 48%, potato in 89%, oats in 79%, winter rye in 52%, rape in 39%, hay in 79%) of the analyzed districts. This study also defined the crop-specific thresholds under which a soil moisture deficit (expressed in terms of rZ-index) leads to severe impact at the district level. This can be expressed as the sum of the monthly rZ-index during the period of high crop sensitivity to drought; for spring barley it is ?5, winter wheat ?5, maize ?9, rape ?12, winter rye ?10, oat ?4, potato ?6 and for hay ?3. The length of the sensitive period is also crop-specific and includes the months that are important for the yield formation. The results show that yields of spring barley (and spring crops in general) are significantly more affected by seasonal water stress than yields of winter crops and hay from permanent meadows. The study proved that a severe drought spell during the sensitive period of vegetative season does have a quantifiable negative effect, even within more humid regions. These results demonstrate that, at least in some areas of the CR (and probably most of Central Europe), drought is one of the key causes of interannual yield variability.     

Decomposition and Coleoptera succession on exposed carrion of small mammal in Opava,the Czech Republic

In 1997 and 1998, field studies on exposed rat carcasses were conducted in Opava, the Czech Republic, to describe the decomposition process and Coleoptera succession patterns. Coleoptera assemblages were monitored during three 40-d succession series conducted in spring, summer and autumn in two different habitats: meadow and deciduous forest. The rate of decomposition was studied in carcasses open to insects and isolated from them. The stages of decomposition recognised in this study follow Reed's classification: fresh, bloated, decay and dry stage. Carcass in summer decayed much faster than in spring and autumn and the decomposition of insect-free carcasses was less rapid than that of carcasses exposed to insects. A total of 145 Coleoptera species belonging to 22 families was recorded on the carcasses. The number of species in the succession series increased from the fresh stage, reached a maximum in the decay stage and gradually declined in the dry stage. The greatest diversity of Coleoptera was found in spring, followed by summer and autumn. More species were collected in forest site than in meadow. Four ecological groups, each characterised by a specific type of carrion association and varying in food specialisation and species biology, have been distinguished.     

Gårdsjön Project: lake acidification,chemistry in catchment runoff,lake liming and microcatchment manipulations

The Gårdsjön Project is an ecosystem approach in studying acid deposition and its effects on terrestrial parts and lakes within a catchment. The study is an attempt to quantify the processes causing the acidification as well as an analyses of the chemical and biological conditions before liming of the lake and manipulations in microcatchments. This paper gives a brief overview of some studies already performed and recently started experiments within the project, such as lake liming, lime application on land, forest fertilization, clearcutting and applications of acid and neutral sulphate on land.     

Quantifying the impacts of human activities on runoff and sediment load changes in a Loess Plateau catchment,China

Journal of Soils and Sediments - Significant changes in the runoff and sediment load have been detected in many catchments of the Loess Plateau. These changes are expected to be influenced by the...     

The Behavior of Nitrogen Isotopes in Acidified Forest Soils in the Czech Republic

The effects of atmospheric deposition on N cycling in acidified soils were studied at three spruce and one beech forested sites in the Czech Republic. Nitrogen content and δ¹⁵N were monitored in bulk and throughfall precipitation, needles, leaves, soils and soil solutions. Changes in soil NO₃ ^- production, effect of admixing of atmospheric N in spruce forest and N consumption in deciduous forest are described using changes in ¹⁵N fractionation of mineralized N in soil. Admixing of atmospheric NH4+ can be identified at low concentrations of exchangeable NH₄ ⁺. The δ¹⁵N ratio of atmospheric NO₃ ^- input is on average by 2‰ less negative than the δ5N ratio in soil water; admixing changes the δ¹⁵N of soil NO₃ ^- detected in lysimeters.