Compatibilizing effects of polypropylene-g-itaconic acid on the polypropylene composites

We prepared long carbon fiber (LCF)-reinforced thermoplastic composites using a compatibilizer of itaconic acid grafted polypropylene (PP-g-IA). We confirmed the structure of PP-g-IA and investigated the compatibilizing effects of PPg- IA on LCF/polypropylene composites. The tensile strength, tensile moduli, flexural strength, and flexural moduli of the composites increased with increasing PP-g-IA content in the thermoplastic composites. Using single pull-out analyzing system, we found PP-g-IA improved interfacial strength between the carbon fiber and PP matrix. The thermal properties of the composites were measured by thermogravimetric analysis (TGA). We could observe that LCF enhanced the mechanical properties and thermal decomposition temperature of the polypropylene (PP) composites, compared with neat PP. The fractured surfaces of PP/PP-g-IA/LCF composites showed that PP-g-IA was effective for improving the interfacial adhesion between LCF and PP matrix.     

Influence of wood species and particle size on mechanical and thermal properties of wood polypropylene composites

This study aims to investigate the effects of two types of wood flour; oil palm mesocarp flour (OMF) and rubberwood flour (RWF), and their particle sizes on mechanical, physical, and thermal properties of wood flour reinforced recycled polypropylene (rPP) composites. The composite materials were manufactured into panels by using a twin-screw extruder. The rPP composites based on RWF significantly showed higher flexural, tensile, and compressive properties (both strength and modulus) as well as hardness and thermal stability than those composites based on OMF for the same particle sizes. However, distribution of RWF in the rPP matrix was less homogeneous than that of the rPP/OMF composites. Furthermore, a decrease of the particle sizes of filler for the rPP/OMF or RWF composites increased the flexural, tensile, compressive, and hardness properties. Likewise, the thermal stability of both OMF and RWF composites were insignificantly affected by the particle sizes.     

Jute yarn as reinforcement for polypropylene based commingled eco-composites: Effect of fibre content and chemical modifications on accelerated ageing and tear properties

Bidirectional PP/jute yarn eco-composites were fabricated via environment friendly commingling technique and its long term durability/life time was monitored as an effect of accelerated solar ageing on its mechanical properties (tensile & flexural). Accelerated solar ageing promoted the thermal oxidation of PP thus resulting in deterioration of its properties, however; MAPP and KMnO₄ treated commingled composites showed much better stability towards thermal oxidation brought about by the solar concentrator, compared to untreated sample and neat polypropylene. This increased resistivity of treated composites (especially MAPP and KMnO₄) towards thermal oxidation brought about by the solar concentrator is due to the increased interfacial adhesion between the matrix and jute yarn owing to chemical modifications. The significance of effective stress transfer between the PP matrix and reinforcing jute yarns is evident from the increased tear resistance of PP/jute yarn commingled composites with increasing fibre content and also with different chemical treatments.     

Chitosan-filled polypropylene composites: The effect of filler loading and organosolv lignin on mechanical,morphological and thermal properties

In this work, the effect of organosolv lignin on properties of polypropylene (PP)/chitosan composites was investigated. Mechanical and thermal properties of the composites were analyzed by means of ASTM D 638-91, ASTM D 256, thermogravimetry analysis (TGA) and differential scanning calorimetry (DSC). Tensile strength and elongation at break of the PP composites decreased upon the presence of chitosan filler, but Young’s modulus improved. Impact strength was found to increase with the maximum value at 30 php of filler loading. At a similar loading, treated PP/chitosan composites were found to have higher tensile strength, elongation at break, Young’s modulus as well as impact strength than untreated composites. Furthermore, the presence of organosolv lignin imparted a plasticizing effect. Thermal properties of the treated PP/chitosan composites were better as compared with the untreated PP/chitosan composites; although the chemical treatment did not alter the thermal degradation mechanism. In addition, the obtained results were comparable to results from previous studies. This finding implied that the organosolv lignin could be a potential reagent to replace its synthetic counterpart.     

Core-sheath polyurethane-carbon nanotube nanofibers prepared by electrospinning

The core-sheath nanofibers consisting of polyurethane (PU) core and PU composites sheath with multi-walled carbon nanotubes (MWNTs) were prepared by electrospinning. At low MWNT concentration, MWNTs appeared highly aligned along the fiber axis with some curving in nanotubes, whereas in case of high concentration, some aggregation of MWNTs appeared due to difficulty in full dispersion of nanotubes. In comparison of the single component nanofiber webs, the core-sheath nanofiber webs showed much better mechanical properties of modulus and breaking stress, including an exceptional elongation-at-break. It indicates that the CNT-incorporated core-sheath structure is very effective for enhancing the mechanical properties of nanofiber webs. In addition, the core-sheath nanofibers demonstrated the fast shape recovery, compared with one component fibers of pure shape memory PU and PU/MWNTs, which provides the possibility of fabricating more sensitive intelligent materials.     

Effect of coir fiber content and compatibilizer on the properties of unidirectional coir fiber/polypropylene composites

The main objective of this research was to study the effect of fiber content variation and stearic acid (SA) treatment on the fundamental properties of unidirectional coir fiber (CF) reinforced polypropylene (PP) composites. Several percentages of filler contents were used (10–40 wt %) in order to gain insights into the effect of filler content on the properties of the composites. Coir/PP composites were fabricated by compression molding, and the properties of composites were studied by physico-mechanical and thermal properties. The results from mechanical properties such as tensile strength (TS), tensile modulus (TM) and impact strength (IS) of the CF/PP composites were found to be increased with increasing fiber content, reached an optimum and thereafter decreased with further increase in fiber content. Treatment of the coir with SA as the coupling agent enhanced the mechanical properties, crystallization temperature and crystallinity of virgin PP and water desorption of the resulting composites, resulting from the improved adhesion between the CF and PP matrix. Scanning electron micrographs (SEM) of the tensile fractured samples showed improved adhesion between fiber and matrix upon treatment with SA. Interfacial shear strength (IFSS) of the composites was measured by single fiber fragmentation test (SFFT).     

Effect of mercerization on mechanical, thermal and degradation characteristics of jute fabric-reinforced polypropylene composites

Jute fabric reinforced polypropylene composites were fabricated by compression molding technique. Fiber content in the composites was optimized at 45 % by weight of fiber by evaluating the mechanical parameters such as tensile strength, tensile modulus, bending strength, bending modulus. Surface treatment of jute fabrics was carried out by mercerizing jute fabrics with aqueous solutions of NaOH (5, 10 and 20 %) at different soaking times (30, 60 and 90 mins) and temperatures (0, 30 and 70 °C). The effect of mercerization on weight and dimension of jute fabrics was studied. Mechanical properties of mercerized jute-PP composites were measured and found highest at 20 % NaOH at 0 °C for 60 min soaking time. Thermal analytical data from thermogravimetric and differential thermal analysis showed that mercerized jute-PP composite achieved higher thermal stability compared to PP, jute fabrics and control composite. Degradation characteristics of the composites were studied in soil, water and simulated weathering conditions. Water uptake of the composites was also investigated.     

A novel strategy for the preparation of bamboo fiber reinforced polypropylene composites

In this paper, a novel strategy was used to prepare the bamboo fiber (BF)/polypropylene (PP) composites which greatly improved the distribution of BF. Both the raw and alkali treated BF were utilized for the fabrication of composites and silane coupling agent was used to improve the adhesion of BF and PP. The effects of BF content and the alkali treatment of BF on mechanical, thermal, morphological, dynamic mechanical properties and water absorption were studied. The Fourier transform infrared spectroscopy (FT-IR) analysis indicated that the hydrophilic nature of raw BF was significantly reduced by alkali treatment. In addition, the mechanical properties and the water absorption of the composites were found to increase with the increment of BF loading. Most importantly, the mechanical properties of the alkali treated BF showed much higher values than that of raw BF while the water absorption of alkali treated BF was much lower than that of raw BF. The results indicated the interaction of fiber-matrix was greatly improved by the alkali treatment. Moreover, from the Scanning Electron Microscopy (SEM) images, it further proved that the distribution of BF was improved by the way of papermaking to premix BF and PP fiber. The Dynamic mechanical thermal analysis (DMA) results showed that the storage modulus of the composites was increased with further increase in BF content.     

A study on mechanical,thermal and environmental degradation characteristics of N,N-dimethylaniline treated jute fabric-reinforced polypropylene composites

The mechanical and thermal behavior of compression molded jute/polypropylene (PP) composites were studied by evaluating tensile strength (TS), bending strength (BS), tensile modulus (TM), bending modulus (BM), impact strength (IS), thermogravimetric (TG/DTG) and differential thermal analysis (DTA). A chemical modification was made to jute fabrics using N,N-Dimethylaniline (DMA) in order to improve the interfacial adhesion between the fabrics and matrix. It was found that jute fabrics on treatment with N,N-Dimethylaniline (DMA) significantly improved the mechanical properties of the composites. Thermal analytical data of PP, both treated and untreated jute fabrics as well as composites revealed that DMA treatment increased the thermal stability of the fabrics and composite. DMA treatment also reduced the hydrophilic nature of the composite. DMA treated jute composite was found less degradable than control composite under water, soil and simulated weathering conditions.     

Tensile,Thermal, and Electrical Conductivity Properties of Carbon Fiber Reinforced Composites Using Itaconic Acid Based Dispersants

We prepared itaconic acid based dispersants (IBDs) by the copolymerization of itaconic acid with acrylic acid, acrylamide, or vinyl sulfonic acid, and compared the efficacy of the IBDs on carbon fiber (CF) dispersion in a water-based system, against that of sodium dodecyl sulphate (SDS) which is widely used as a dispersing agent. The procedure to fabricate nonwoven CF (NCF)/PP composites using IBDs includes the following steps: the synthesis of IBDs, the dispersion of CFs in water by the IBDs, the formation of a NCF, and hot pressing of NCF with polypropylene (PP) layer. We determined the tensile, thermal properties, and the electrical conductivity of non-woven CF/PP composites. It was found that using IBDs as a CF dispersing agent led to the CF/PP composites having better tensile, thermal, and electrical properties, as compared to when SDS was used as a dispersing agent.     

Mechanical and thermal degradation behavior of sisal fiber (SF) reinforced recycled polypropylene (RPP) composites

The present investigation focuses on the effect of fiber surface treatment on the mechanical, thermal and morphological properties of sisal fiber (SF) reinforced recycled polypropylene (RPP) composites. The surface of sisal fiber was modified using different chemicals such as silane, glycidyl methacrylate (GMA) and O-hydroxybenzene diazonium chloride (OBDC) to improve the compatibility between fiber surface and polymer matrix. The experimental results revealed an improvement in the tensile strength to 11 %, 20 % and 31.36 % and impact strength to 78.72 %, 77 % and 81 % for silane, GMA and OBDC treated sisal fiber reinforced recycled polypropylene (RPP/SF) composites respectively as compared to RPP. The thermo gravimetric analysis (TGA), Differential scanning calorimeter (DSC) and heat deflection temperature (HDT) results revealed improved thermal stability as compared with RPP. The morphological analysis through scanning electron micrograph (SEM) supports improves surface interaction between fiber surface and polymer matrix.     

Improvement in mechanical properties of aluminum polypropylene composite fiber

Aluminum particles (Al) were added to polypropylene (PP) in the presence of poly ethylene glycol (PEG) and polypropylene-graft-maleic anhydride to produce composites. The composites were then melt-spun into a mono filament and tested for tensile properties, diameter evenness and morphology. Melt rheological properties of Al/PP composites were studied in linear viscoelastic response regions. It was observed that level of dispersion of aluminum particles within a polypropylene composite fiber could be improved by incorporating polyethylene glycol. The improvement of dispersion led to an improvement in the fibers mechanical properties through a reduction of the coefficient of variation of fiber diameter.     

Characterization of oil palm empty fruit bunch and glass fibre reinforced recycled polypropylene hybrid composites

The effects of hybridization of glass fibre on oil palm empty fruit bunch (EFB) and recycled polypropylene-based composites are described in this paper. The compounding process involved extrusion followed by injection moulding technique to prepare the samples for characterizations. Fibre loading were considered as 40 % of the total weight of the blends and EFB:glass fibre ratio was maintained as 30:70, 50:50, 70:30 and 90:10. Two types of coupling agents of maleic anhydride-grafted polypropylene such as polybond-3200 and fusabond P-613 of different molecular weight and maleic anhydride level were used to improve the interfacial adhesion between the fibres and the matrix. Composites were characterized by density, melt flow index, tensile, Izod impact and flexural testing. Morphological images of the fractured surfaces of the composites were examined by field-emission scanning electron microscopy. Samples were also characterized by thermal tests such as thermogravimetric analysis and differential scanning calorimetry to evaluate the thermal and crystalline properties, respectively. Optimization of hybridization of the fibres and effect of coupling agents were evaluated in terms of various properties of the samples. The composite prepared with EFB:glass fibre ratio of 70:30 showed better reinforcing properties than that of others.     

Oil palm fiber (OPF) and its composites: A review

Twenty first century has witnessed remarkable achievements in green technology in material science through the development of biocomposites. Oil palm fiber (OPF) extracted from the empty fruit bunches is proven as a good raw material for biocomposites. The cellulose content of OPF is in the range of 43%–65% and lignin content is in the range of 13%–25%. A compilation of the morphology, chemical constituents and properties of OPF as reported by various researchers are collected and presented in this paper. The suitability of OPF in various polymeric matrices such as natural rubber, polypropylene, polyvinyl chloride, phenol formaldehyde, polyurethane, epoxy, polyester, etc. to form biocomposites as reported by various researchers in the recent past is compiled. The properties of these composites viz., physical, mechanical, water sorption, thermal, degradation, electrical properties, etc. are summerised. Oil palm fiber loading in some polymeric matrices improved the strength of the resulting composites whereas less strength was observed in some cases. The composites became more hydrophilic upon addition of OPF. However treatments on fiber surface improved the composite properties. Alkali treatment on OPF is preferred for improving the fiber–matrix adhesion compared to other treatments. The effect of various treatments on the properties of OPF and that of resulting composites reported by various researchers is compiled in this paper. The thermal stability, dielectric constant, electrical conductivity, etc. of the composites improved upon incorporation of OPF. The strength properties reduced upon weathering/degradation. Sisal fiber was reported as a good combination with OPF in hybrid composites.     

Completely biodegradable soyprotein-jute biocomposites developed using water without any chemicals as plasticizer

Soyprotein-jute fiber composites developed using water without any chemicals as the plasticizer show much better flexural and tensile properties than polypropylene-jute composites. Co-products of soybean processing such as soy oil, soyprotein concentrate and soy protein isolates are inexpensive, abundantly available and are renewable resources that have been extensively studied as potential matrix materials to develop biodegradable composites. However, previous attempts on developing soy-based composites have either chemically modified the co-products or used plasticizers such as glycerol. Chemical modifications make the composites expensive and less environmentally friendly and plasticizers decrease the properties of the composites. In this research, soyprotein composites reinforced with jute fibers have been developed using water without any chemicals as plasticizer. The effects of water on the thermal behavior of soyproteins and composite fabrication conditions on the flexural, tensile and acoustic properties of the composites have been studied. Soyprotein composites developed in this research have excellent flexural strength, tensile strength and tensile modulus, much higher than polypropylene (PP)-jute fiber composites. The soyprotein composites have better properties than the PP composites even at high relative humidity (90%).     

Banana fiber-reinforced polypropylene composites: A study of the physico-mechanical properties

Banana fiber-reinforced polypropylene (PP) matrix composites were prepared by compression molding and their mechanical properties were evaluated. Banana fibers and matrices were irradiated with UV radiation at different intensities. Mechanical properties of irradiated banana fibers and matrices based composites were found to increase significantly compared to untreated counterparts. Optimized banana fibers were treated with 2-hydroxyethyl methacrylate (HEMA) solution and were cured in an oven at different temperatures for different curing times and then composites were fabricated. Monomer concentration, curing temperature and curing time were optimized with the extent of polymer loading and mechanical properties and showed better mechanical properties over untreated composites. Water uptake and simulating weathering test of the composites were also investigated.     

Effects of date palm leaf fiber on the thermal and tensile properties of recycled ternary polyolefin blend composites

This work investigated the effects of date palm leaf fiber (DPLF) content on the thermal and tensile properties; and morphology of compatibilized polyolefin ternary blend. Recycled polyolefin ternary blend consisting of low density polyethylene (RLDPE), high density polyethylene (RHDPE) and polypropylene (RPP) were fabricated at different parts per hundred resin (phr) of DPLF. Maleic anhydride grafted polyethylene (MAPE) was used as compatibilizer to enhance the adhesion between filler and polymer matrix. The composites were prepared using melt extrusion and tests samples were produced via injection molding process. Thermal conductivity results showed that as much as 11 % reduction in thermal conductivity was achieved with the incorporation of 30 phr DPLF. Highest tensile strength was observed with the incorporation of 10 phr DPLF. The elongation at break was reduced with the addition of DPLF due to impediment of chain mobility by the fillers. Initial degradation temperature increased with the addition of DPLF. Hence, it is concluded that DPLF can be used to develop green and thermally insulating composites. It is hoped that the present results will stimulate further studies on the thermally insulative materials based on natural fibers reinforced polymer composites for applications in the building industries.     

Role of potassium permanganate and urea on the improvement of the mechanical properties of jute polypropylene composites

Jute fabrics (hessian cloth) reinforced polypropylene (PP) matrix composites (45 wt% fiber) were fabricated by compression molding. Jute fabrics were treated with 2-hydroxyethyl methacrylate (HEMA) using ultraviolet radiation in order to improve the mechanical properties of the composites. Concentration of HEMA, soaking time and radiation dose were optimized. It was found that 15% HEMA in methanol along with photoinitiator Darocur-1173 (2 %), 10 min soaking time and 20th pass of radiation rendered better performance. Urea of different concentrations (0.5–2 %) was incorporated with 15 % HEMA to monitor its effect on the properties and 1 % urea revealed the best results. For the improvement of the properties, jute fabrics were treated with potassium permanganate (KMnO₄) solution in acetone of different concentrations (0.02, 0.03, 0.05, and 0.5 %) at different soaking times (1, 2, 3, and 5 min) before the composite fabrication. Optimized jute fabrics (jute fabrics treated with 0.03 % KMnO₄) were again treated with HEMA (15 %) solution along with urea (1 %) and promising improvement of mechanical properties of the composites was observed. Scanning electron microscopy, water uptake, soil degradation and thermal aging of the treated and untreated composites were also performed.     

Characterization of plant and animal based natural fibers reinforced polypropylene composites and their comparative study

Natural fibers are largely divided into two categories depending on their origin: plant based and animal based. Plant based natural jute fiber reinforced polypropylene (PP) matrix composites (20 wt% fiber) were fabricated by compression molding. Bending strength (BS), bending modulus (BM), tensile strength (TS), Young’s modulus (YM), and impact strength (IS) of the composites were found 44.2 MPa, 2200 MPa, 41.3 MPa, 750 MPa and 12 kJ/m², respectively. Animal based natural B. mori silk fiber reinforced polypropylene (PP) matrix composites (20 wt% fiber) were fabricated in the same way and the mechanical properties were compared over the silk based composites. TS, YM, BS, BM, IS of silk fiber reinforced polypropylene composites were found 55.6 MPa, 760 MPa, 57.1 MPa, 3320 MPa and 17 kJ/m² respectively. Degradation of composites in soil was measured upto twelve weeks. It was found that plant based jute fiber/PP composite losses its strength more than animal based silk fiber/PP composite for the same period of time. The comparative study makes it clear that mechanical properties of silk/PP composites are greater than those values of jute/PP composites. But jute/PP composites are more degradable than silk/PP composites i.e., silk/PP composites retain their strength for a longer period than jute/PP composites.     

Polyester-based thermoplastic elastomer/MWNT composites: Rheological, thermal, and electrical properties

Polyester-based thermoplastic elastomer (Hytrel®) was melt-compounded with multi-walled nanotubes (MWNTs) using an internal mixer and the changes in the thermal, electrical and rheological properties were investigated using a range of nanotube contents (from 0.1 to 7 wt%). Even at nanotube concentrations as low as 0.1 wt%, the crystallization temperature was remarkably elevated by 15 °C and it increased further up to 22 °C with a 5 wt% loading. On the contrary, the melting temperature increased by 2 °C with 0.1 wt% MWNTs and it was slightly decreased by further additions of MWNTs. Electrical conductivity measured by the four probe method was detected from the 1 wt% MWNTs, indicative of electrical percolation. In addition, MWNTs starting from 4 wt% and above had no significant effect on the electrical conductivity, while it rapidly increased with nanotube contents below 4 wt%. Dynamic rheological properties were measured using a strain controlled rotational rheometer. The complex viscosity increased with MWNT contents giving an abrupt increase between 0.5 and 1 wt% loadings. In addition, the storage and loss modulus increased in a different manner depending on the range of the nanotube concentration. In the Cole-Cole plot, the slope of the nanocomposites decreased from 1.63 to 0.74 with increasing nanotube contents. In the Casson plot, the addition of MWNTs up to 0.5 wt% did not show any yield behavior giving an extremely low value for the yield stress, but further additions of nanotubes increased it notably. The presence of nanotubes in the elastomer increased the relaxation time with nanotube contents and their effect became weak as the frequency increased.