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1.
The kinetics of color changes in keyaki (Zelkova serrata Makino) and sugi (Cryptomeria japonica D. Don) wood during heat treatment were examined. The color of wood specimens treated at 90, 120, 150, and 180 °C was measured by an imaging spectrophotometer and expressed using CIELAB color parameters. At any treatment temperature, values for L* and $ \Updelta E_{ab}^{*} $ decreased and increased in both wood species, respectively, with increased treatment time. Changes in a* and b* varied depending on wood species and treatment temperature. The color changes were successfully analyzed using the kinetic approach applying time–temperature superposition method. This approach elucidated and accurately predicted color changes during heat treatment.  相似文献   

2.
Dielectric spectroscopy of Scots pine   总被引:1,自引:0,他引:1  
Dielectric properties of Scots pine (42 trees) were compared with density, moisture content (MC), and resin acid content (RAC) (of heartwood). The samples were measured in frozen, green, conditioned and non-conditioned dry moisture states to evaluate the potential of dielectric spectroscopy in determining the wood characteristics at different stages of wood processing. Heartwood and sapwood parts of each sample were measured separately, and through-transmission measurement was conducted in longitudinal and tangential direction at frequencies from 1 MHz to 1 GHz. The MC and density correlated significantly with the dielectric parameters in both measurement directions but especially in longitudinal direction. The RAC of the heartwood correlated significantly with tanδ and ε″/(ε′ ? 1) of the green samples measured in the tangential direction at frequencies above 200 MHz. The correlation at 1 GHz was ?0.56 for green samples, ?0.66 for conditioned samples and ?0.61 for non-conditioned samples (P < 0.001, for all). The study suggests that the extractives also affect radio-frequency dielectric responses, which might be used for extractive analyses of pine heartwood.  相似文献   

3.
Performances of Pinus taxa were studied to 10 years of age in two trials in each of Misiones and Entre Ríos provinces across the Mesopotamia region of Argentina. Taxa comprised 22 populations from sources in Argentina, Australia, Brazil and Zimbabwe including Pinus elliottii var. elliottii (Pee), Pinus caribaea var. hondurensis (Pch), their four, inter-specific hybrids (F1, F2 and backcrosses from F1 to Pch and to Pee—all as broadly based bulks); other Pee and Pinus taeda (Pt) comprised narrower or unspecified bulks. Variable numbers of taxa were missing at each site. Mean survival across sites at age 10 years ranged 53.2–91.3% averaging 74.2%. Analysis of variance of plot means indicated population effect was statistically significant (p < 0.05) for all or most growth and quality traits at all sites. However, significant differences from the nominated check seedlot at the Entre Ríos sites (Pee, Australia) were extremely rare, while quite common at the northern, Misiones sites (check seedlot a Pt population). In the Misiones trials, F1, F2 and both backcross hybrids showed better stem straightness than Pee and Pt from Argentina, generally with statistically significant differences (p < 0.05). Pt showed lowest forking scores (desirable). Taxon × environment interaction was statistically significant (p < 0.01) for growth traits only (p > 0.05). However, this interaction contributed an average of only 34.1% of the taxon variance suggesting a lack of practical importance. Taxa most suitable for deployment in the Mesopotamia region, Argentina are suggested.  相似文献   

4.
The properties of oak heat treated at temperatures of 160–220 °C, oxygen concentrations of 2–10 %, steam pressures of 0.1–0.4 MPa and treatment time of 2–4 h were investigated. Although modulus of elasticity (MOE), modulus of rupture (MOR) and equilibrium moisture content (EMC) of the heat-treated wood (HTW) were reduced, the value of $ \Updelta E^{*} $ was increased, and the dimensional stability [anti-swelling efficiency in radial (ASE-R), anti-humidity efficiency (AHE)] was improved considerably. Six regression equations (temperature, oxygen concentration, steam pressure and time as functions of MOE, MOR, ASE-R, AHE, EMC and $ \Updelta E^{*} $ ) were developed for the estimation and a nonlinear programming model was derived with operation research theory to obtain the most desirable HTW properties under some production constraints.  相似文献   

5.
The aim of this study was to evaluate the potential of visible and near infrared spectroscopy (Vis/NIRS) in predicting the chemical, physical and mechanical behavior of single-piece natural corks stoppers used for sealing wine bottles. Two training sets of 90 and 150 cork stoppers were used to obtain four spectra per sample in different positions: two of the stopper bases (transversal section) and two of the stopper sides (tangential section and radial section). The samples were scanned in the range of 400–2,500 nm using a Foss-NIRSystems 6500 SY II spectrophotometer equipped with a remote reflectance fiber-optic probe. On each training set, two-thirds of the samples were used to develop modified partial least square (MPLS) calibration equations, and the remaining one-third of the sample for the external validation of these MPLS equations. The best equations were obtained for the transversal section, which is the recommended one when applying Vis/NIRS technology to cork. The best results for the chemical composition were obtained for waxes and total polyphenols, showing coefficient of determination of the cross validation (r cv 2 ) values of 0.64 and 0.56 and coefficient of determination of the external validation (r EV 2 ) values of 0.53 and 0.55, respectively. The best equation for the physical and mechanical parameters was obtained for moisture content (r cv 2  = 0.86 and r EV 2  = 0.85), with somewhat lower results for density, compression force and extraction force (r cv 2  = 0.66, 0.72, 0.52 and r EV 2  = 0.52, 0.49, 0.51, respectively). The SECV (standard error of cross validation) and SEP (standard error of external validation) were similar for all the physical and mechanical parameters, thus confirming the robustness of the equations. MPLS model for moisture content fulfills the requirements for screening (RPD >2.5), but MPLS models obtained for waxes, total polyphenols, density, compression force and extraction force are not good enough for routine analysis or quality control. The results obtained from the MPLS models based on Vis/NIRS technology would permit the continuous quality control of humidity in the production line as well as obtaining information about certain chemical components (extractives contents) and some physical and mechanical parameters (density, extraction force and compression force).  相似文献   

6.
Tomography is a wave-based technique used to depicture tree cross-sections; specifically, impulse tomography uses data given by the passage of impulse waves, which were primarily influenced by density, modulus of elasticity, and moisture content of wood. The influence of wood characteristics on various kinds of waves has been extensively studied, allowing the establishment of statistical correlations between wave behavior and wood properties. In this context, the relationship between impulse speed from cross-section tomography and conditioned density that was obtained on diametrical sample by X-ray densitometry was analyzed using logs of three tree species with different densities that were air dried to 12 % moisture content. For each species, means from 5 mm length intervals of conditioned density profile graph (ρ 12%) and impulse speed distribution graph (S 12%) on the same diametrical sample are used to fit models. Joining data from all species, the exponential model \( \ln \rho_{12\% } = - 4.32822 + 1.67894 *\ln S_{12\% } \) was obtained with correlation coefficient of 0.85 and highly significant parameters. The results indicate that conditioned density could be explained by impulse speed on the cross-section, but research is necessary to make a useful tool out of it.  相似文献   

7.

Context

Wood quality traits are important to balance the negative decline of wood quality associated with selection for growth attributes in gymnosperm breeding programs. Obtaining wood quality estimates quickly is crucial for successful incorporation in breeding programs.

Aims

The aims of this paper are to: (1) Estimate genetic and phenotypic correlations between growth and wood quality attributes, (2) Estimate heritability of the studied traits, and (3) Assess the accuracy of in situ non-destructive tools as a representative of actual wood density.

Methods

Wood density (X-ray densitometry), tree height, diameter, volume, resistance drilling, acoustic velocity, and dynamic modulus of elasticity were estimated, along with their genetic parameters, for 1,200, 20-year-old trees from 25 open-pollinated families.

Results

Individual tree level heritabilities for non-destructive evaluation attributes were moderate ( $ {\widehat{h}}_i^2=0.37-0.42 $ ), wood density and growth traits were lower ( $ {\widehat{h}}_i^2=0.23-0.35 $ ). Favorable genetic and phenotypic correlations between growth traits, wood density, and non-destructive evaluation traits were observed. A perfect genetic correlation was found between resistance drilling and wood density (r G ?=?1.00?±?0.07), while acoustic velocity and dynamic modulus of elasticity showed weaker genetic correlations with wood density (r G ?=?0.25?±?0.24;?0.46?±?0.21, respectively).

Conclusion

This study confirmed that resistance drilling is a reliable predictor of wood density in western larch, while the weak genetic correlations displayed by acoustic velocity and dynamic modulus of elasticity suggest limited dependability for their use as fast in situ wood density assessment methods in this species.  相似文献   

8.
The wave attenuation function of a Japanese black pine forest was evaluated based on its growth at different initial planting densities (P ini) using the spatially explicit, individual-based, dynamic global vegetation model. The forest dynamics were simulated for 150 years utilizing datasets for tree density and stem diameter at different stand ages obtained in the field. To elucidate the ability of the forest to reduce the wave height $ \eta_{t} $ (m), a long linear wave that propagates on dry ground was assumed. The attenuation of $ \eta_{t} $ (m) was expressed as follows: $ \eta_{t} = \eta_{t0} \exp ( - k_{\text{i}} x) $ , where $ \eta_{t0} $ , x, and k i are the initial wave height (m), the distance (m), and the wave attenuation coefficient (m?1), respectively. The tree destruction caused by the waves was considered in order to estimate k i. The model suggested that there was a peak age that maximized k i and was dependent on $ \eta_{t} $ , and that the maximum k i attained decreased with increasing $ \eta_{t} $ . When P ini was varied widely from 0.5 to 4 m?2, the maximum k i for a relatively low wave height (≤3 m) changed dramatically. For example, when $ \eta_{t} = 2{\text{ m}},$ the maximum k i ranged from 0.008 to 0.031 m?1, depending on P ini. Thus, utilizing a relatively low P ini would be an efficient way of quickly creating a forest capable of sufficient wave attenuation in areas where a relatively high wave height (≥4 m) is expected. It was concluded that regular harvesting and planting would be required to realize the full potential of the coastal forests to attenuate waves, and that tailoring P ini is one of the management options that could be used to establish a wave prevention forest.  相似文献   

9.
Effect of severe thermal treatment on spruce and beech wood lignins   总被引:1,自引:0,他引:1  
  • ? The structure, proportion and mode of assembly of lignin, celluloses and hemicelluloses have marked effects on the reaction mechanisms during thermal treatment and therefore have a strong influence on the quality of the final product. The effect of treatment conditions, including severe conditions (up to 553 K) and treatment duration (up to 8 h) on the structure of native spruce and beech lignins was studied.
  • ? Lignin content was determined by the Klason method and lignin structure was evaluated by thioacidolysis.
  • ? The results highlighted the strong reactivity of the native spruce and beech lignins towards severe heat treatments. The distinct susceptibility of syringyl (S) and guaiacyl (G) units towards thermal treatment is confirmed by comparing the data for beech and spruce samples. The most severe treatment of spruce wood (280 °C) induced a dramatic enrichment in lignin content together with the almost complete disappearance of G lignin units, whereas a more moderate treatment substantially changed lignin structure by degradation reactions that affect the p-hydroxyphenyl (H) and G lignin units similarly.
  • ? Thioacidolysis revealed that the thermal treatment induces the appearance of vinyl ether structures in spruce lignins. The decreased yield of the G and S thioacidolysis monomers reflects the progressive disappearance of G and S lignin units only involved in β-O-4 bonds and the formation of condensed linkages in proportions related to treatment severity. In severe conditions, β-O-4 linked S units are more degraded than their G homologues.
  •   相似文献   

    10.
    Thermal modification of wood is an environment-friendly alternative method for improving several properties of wood without the use of chemicals. This paper deals with the examination of color and chemical changes in spruce (Picea abies L.) and oak wood (Quercus robur F.) that occur due to thermal treatment. The thermal modification was performed at 160, 180, and 210 °C according to thermowood process. The color changes were measured by the spectrophotometer and described in the L*a*b* color system. Chemical changes were examined by wet chemistry methods, infrared spectroscopy and liquid chromatography. During the experiment, oak samples showed smaller color changes than spruce samples at all temperature values. During thermal modification, the content of cellulose, lignin, and extractives increases; however, the hemicellulose content drops by 58.85% (oak) and by 37.40% (spruce). In addition to deacetylation, new carbonyl and carboxyl groups are formed as a result of oxidation. Bonds in lignin (mainly β-O-4) and methoxyl groups are cleaved, and lignin is condensed at higher temperatures.  相似文献   

    11.
    Coffee, Coffea arabica L., which is native to Ethiopia, is the world’s most widely traded tropical agricultural commodity. While much is known about the productivity and management of coffee for coffee beans little attention has been given to the plants overall biomass production and carbon sequestration. The objective of this study was to develop and evaluate allometric equations for estimating the aboveground biomass of C. arabica plants growing in indigenous agroforestry system in the Rift Valley escarpment of south-eastern Ethiopia. Coffee plays an important role in providing income and in sustaining these productive systems. Biomass harvesting of 31 plants with 54 stems was carried out in a 40 km2 area varying in elevation from 1,500 to 1,900 m. The stem accounted for most (56 %) of plant biomass, followed by branches (39 %) and twigs plus foliage (5 %). Plant mean biomass was 22.9 ± 15.8 kg. Power equations using stem diameter measured at either 40 cm (d 40) or at breast height (d, 1.3 m) with and without stem height (h) were evaluated. The square power equation, $ Y \; = \; b_{ 1} d_{ 40}^{ 2} $ , was found to be the best (highest ranked using goodness-of-fit statistics) for predicting total and component biomass. The reliability of the prediction decreased in the order: stem > branches > twigs plus foliage. A cross-validation procedure showed that equation parameterization was stable and coefficients reliable. Our parameterized square power equation for total aboveground biomass was also found to be better than the equations parameterized by Hairiah et al. (Carbon stocks of tropical land use systems as part of the global C balance: effects of forest conversion and options for clean development activities, International Centre for Research in Agroforestry, Bogor, 2001) and Segura et al. (Agroforest Syst 68:143–150, 2006) for C. arabica grown in agroforestry systems, confirming the importance of parameterization of allometric equations with site specific data when possible.  相似文献   

    12.
    To determine the independent decomposition rates of lignin and cellulose of decayed woody debris, a technique for the rapid analysis of lignin and cellulose is required. We applied a near-infrared spectroscopy (NIRS) technique to measure the lignin and holocellulose content in decayed wood. We succeeded in creating partial least-squares (PLS) models to estimate the lignin and holocellulose content in the decayed wood of five species using NIR spectra. Although the accuracy was acceptable for the estimation of a five-species mixed model (R 2 = 0.970 for lignin and R 2 = 0.962 for holocellulose), it was further improved when the model was applied to each species independently. This combination of NIRS and a PLS model is a valuable tool for the determination of the lignin and holocellulose content in decayed wood. The technique is time efficient (3 min per sample) and non-hazardous (no acid treatment is required).  相似文献   

    13.
    Although the heterogeneity of wood could preclude assessment of the performances of adhesion, the within-tree variations in its thermodynamic properties still remain unexplored. This study analyzed the surface free energy of wood (γ W ) calculated by the geometric mean approach along the radius and at different sampling heights in black spruce and balsam fir with a statistical model, employing apparent contact angles of three testing liquids. Sampling height and species affected the apparent contact angles, and consequently the polar ( $ \gamma_{W}^{P} $ ) and dispersed ( $ \gamma_{W}^{D} $ ) components of γ W , but no significant difference was observed along the radius. On average, γ W was 43.77?mJ?m?2 at the stem base and gradually decreased, attaining 27.19?mJ?m?2 at 14?m of height. $ \gamma_{W}^{P} $ was markedly higher than $ \gamma_{W}^{D} $ with an opposite pattern along the tree height. These findings demonstrated the huge variability in γ W along the stem, which could be related to the structural or chemical features of wood.  相似文献   

    14.
    Pulverized samples of wood, cedar and eucalyptus were treated with 5 N NaOH solutions at 25–150 °C. Hemicellulose and lignin content in the samples decreased with increasing treatment temperatures, while the recovery of glucose was maintained at nearly 90 %. X-ray diffraction analysis showed that the content of the original cellulose I structure in the samples decreased with increasing temperature, and most of the cellulose in the sample treated at 150 °C was converted to cellulose II by mercerization. Enzymatic hydrolysis of the alkaline-treated samples was carried out at 37 °C using solutions comprising a mixture of cellulase and β-glucosidase. The samples treated at higher temperatures showed better enzymatic degradability. Treatment with an alkaline solution of lower concentration (1 N NaOH) at 150 °C was also used. Despite significant quantities of hemicellulose and lignin being removed, mercerization was not induced. The enzymatic degradability was much lower than that of the sample treated with a 5 N NaOH solution at 150 °C. Thus, treatment with concentrated alkaline solution at high temperature led to not only the removal of hemicellulose and lignin, but also to modification of the cellulose structure, which resulted in high efficiency of enzymatic saccharification of the wood samples.  相似文献   

    15.
  • ? The effect of brown-rot (Coniophora puteana) decay on the water adsorption capacity and concentration of extractives of Scots pine (Pinus sylvestris L.) heartwood were studied by comparing corresponding properties of decayed and undecayed wood samples.
  • ? The samples derived from 39 felled trees having a large between-tree variation in the extractive concentrations, and subsequently in the mass loss in the decay test. The water adsorption capacity, expressed as equilibrium moisture content (EMC), was measured at a high relative humidity (RH ~100%, 21 °C).
  • ? In contrast to the widely held belief, the water adsorption capacity of brow-rotted heartwood appeared to be significantly higher than that of undecayed heartwood.
  • ? The chemical composition of heartwood was changed radically by the fungus: the concentration of stilbenes, resin acids and free fatty acids decreased, while the concentration of soluble sugars increased as a result of decay. In addition, fungal sugars were found in the decayed samples. The concentration of total phenolics increased, which obviously reflected chemical changes in cell wall constituents other than extractives.
  • ? As a conclusion, the information concerning the hygroscopicity of brown-rotted wood might be valuable e.g. when carrying out repairs on buildings damaged by advanced decay.
  •   相似文献   

    16.

    Context

    Since the 2003 drought and heat wave, Douglas-fir dieback has been reported in France in trees older than 30 years. Consequently, it is questioned whether selected Douglas-fir provenances are suited to the frequent and severe drought events which are forecast due to climate change.

    Aims

    Our objective was to contribute to the screening of variability in productivity and growth response to soil-water deficit of mature trees from provenances not currently used for plantation in France.

    Methods

    We sampled 22 provenances, including coastal and interior Douglas-fir, covering a wide part of its natural distribution, from Oregon to California for coastal provenances and from British Columbia to New Mexico for interior provenances. These provenances were planted at the mid 1970s in two provenance trials located in the south-west area of France. Variability of productivity, of wood density, and of radial growth in response to drought episodes among provenances was quantified and related to soil-water deficit computed by daily water balance calculations.

    Results

    Whatever the provenance, annual radial growth is highly dependent on local soil-water deficit (Felines R 2 = 0.57, Le Treps R2 = 0.49). Radial growth and wood properties exhibit large differences between provenances at 30 years old. Variability between provenances for all wood characteristics studied is mainly structured geographically. Coastal provenances perform best for productivity at 30 years old (619 cm2?±?59), and exhibit a small growth reduction in 2004, the second successive year of drought (?10.7 %?±?3.8). Surprisingly, the southern interior provenances from the driest environments in the natural range show a large growth reduction in 2004 (?30.5 %?±?5.2).

    Conclusions

    The provenances tested exhibited significant differences in growth performance and growth reduction induced by the soil-water deficit. The approach coupling retrospective analysis of radial growth on mature trees and water balance modelling is relevant for evaluating provenance adaptation to more frequent or severe drought episodes.  相似文献   

    17.

    ? Introduction

    There has been an increasing interest in very early selection of radiata pine to reduce the breeding cycle for solid wood products. For such selection, new approaches are required to assess wood quality in wood from very young stems.

    ? Methods

    Nursery seedlings of clones of radiata pine were grown in leant condition using two leaning strategies for 18–20 months. Opposite wood and compression wood were isolated from the leaning stems and tested for dynamic modulus of elasticity, density, longitudinal shrinkage, volumetric shrinkage and compression wood area using new methods evolved for testing small size samples quickly and reliably. The methods were tested for their efficiency in differentiating clones by their wood properties.

    ? Results

    Leaning of stems provided distinct opposite and compression wood for testing. Automated image analysis method used for compression wood area assessment was found to be a quick and effective method for processing large number of samples from young stems. Compression wood was characterised by high basic density, high longitudinal shrinkage and low volumetric shrinkage than that of opposite wood. Acoustic velocity in opposite wood had a strong negative association with longitudinal shrinkage. The study signifies the importance of preventing mixing of opposite wood with compression wood while assessing wood quality in young stems thus making leaning a critical strategy. The comparison of wood properties of opposite wood revealed significant differences between clones. Opposite wood of the clone with the lowest dynamic modulus of elasticity exhibited the highest longitudinal shrinkage.

    ? Conclusion

    Significant differences in measurable wood properties between clones suggest the prospects of early selection for solid wood products.  相似文献   

    18.
    The future of South Africa’s most important pine species, Pinus patula, is threatened by the pitch canker fungus, Fusarium circinatum. Pinus maximinoi and P. tecunumanii represent two subtropical species that provide an alternative to planting P. patula on the warmer sites of South Africa. Extending the planting range of P. tecunumanii and P. maximinoi to include higher and colder altitude sites will reduce the area planted to P. patula and the risk of F. circinatum. During 2007 progeny trials of P. tecunumanii and P. maximinoi were planted on a sub-tropical and sub-temperate site. Shortly after the establishment of these trials, unusually cold weather conditions were experienced across South Africa (?3°C at the sub-temperate site) resulting in severe mortality. This provided the opportunity to assess the variation in survival as a measure of frost tolerance within these two species to determine whether it could be improved upon through selection. Results indicated that the variation in survival was under genetic control in P. tecunumanii (h (0,1) 2  = 0.16, h L 2  = 0.27) and P. maximinoi (h (0,1) 2  = 0.11, h L 2  = 0.23) at the sub-temperate site. Correlations in provenance ranking for survival across sites were high for both species. Moderate correlations in family survival for P. tecunumanii (r = 0.52) were found at the two sites. Improvements in cold tolerance can thus be made in both species extending their planting range to include greater areas planted to P. patula thereby limiting the risk of F. circinatum.  相似文献   

    19.
    A digital image correlation (DIC) method was utilized to measure strain distributed within approximately 0.5 mm of the cutting edge during slow-speed orthogonal cutting of air-dried hinoki (Chamaecyparis obtusa), to clarify the relationships of the strain distribution and cutting conditions, including cutting angle (\(\theta\)) and depth of cut (\(d\)). The strain was measured in 0.04 mm steps, and the measurable minimum strain was approximately 0.08%. Tensile strain of 3% or larger normal to the cutting direction, \({\varepsilon _y}\), tended to extend 0.2 mm or further ahead of the tool when \(\theta \leq 60^\circ\) and \(d \geq 0.1{\text{ mm}}\). This tensile \({\varepsilon _y}\) corresponded to the occurrence of the fore-split in Chip Type I. The tensile \({\varepsilon _y}\) detected along the path of the cutting edge decreased as \(\theta\) and/or \(d\) decreased. Positive shear strain, \({\gamma _{xy}}\), tended to be detected ahead of the tool in Type I. Negative \({\gamma _{xy}}\) tended to be detected ahead of the tool in Type II and III \(\left( {\theta \geq 70^\circ ,\,\,d \geq 0.05{\text{ mm}}} \right)\). These \({\gamma _{xy}}\) values were considered to be related to the elongation and shrinkage of the chip. The study confirmed the usability of the DIC method for the evaluation of cutting conditions and also to classify chip formation into chip types.  相似文献   

    20.
  • ? Eperua grandiflora, which is widely distributed in the French Guiana forest region, shows high variability in decay resistance. Further information concerning this wood quality parameter is necessary, but standard testing methods are complex and time-consuming. We assessed the use of colorimetry to determine durability in heartwood samples from a range of trees.
  • ? Eperua grandiflora colour parameters were measured using a CIELAB system, revealing that the tree effect was greater than the radial position and height effects.
  • ? The wood samples were exposed to Coriolus versicolor and Antrodia sp. according to two European standards (En 350-1 and XP CEN TS 15083-1). Eperua grandiflora is more susceptible to brown rot. These two standards did not give the same durability classes. The high variation in natural durability was due to the tree effect.
  • ? These two properties were found to be correlated and the assessment also distinguished the extreme durability classes but they are not sufficient to classify the class of durability of this species.
  •   相似文献   

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