Argon-40: excess in submarine pillow basalts from kilauea volcano, hawaii

Submarine pillow basalts from Kilauea Volcano contain excess radiogenic argon-40 and give anomalously high potassium-argon ages. Glassy rims of pillows show a systematic increase in radiogenic argon-40 with depth, and a pillow from a depth of 2590 meters shows a decrease in radiogenic argon40 inward from the pillow rim. The data indicate that the amount of excess radiogenic argon-40 is a direct function of both hydrostatic pressure and rate of cooling, and that many submarine basalts are not suitable for potassium-argon dating.     

Gas-retention and cosmic-ray exposure ages of lunar rock 15555

The last lava flow in the Hadley Rille area of Mare Imbrium, as inferred from an argon-40-argon-39 experiment on a plagioclase separate from the lunar basalt 15555, occurred 3.31+/-0.03x10(9) years ago. An argon-40-argon-39 experiment on a whole rock sample shows significant loss of radiogenic argon-40 and yields a well-defined, high-temperature plateau indicating a lower age of 3.22+/-0.03x10(9) years. A cosmic-ray exposure age of 90+/-10x10(6) years is determined from the ratio of spallogenic argon-38 to calcium.     

Venus lower atmospheric composition: preliminary results from pioneer venus

Initial examination of data from the neutral mass spectrometer on the Pioneer Venus sounder probe indicates that the abundances of argon-36, argon-38, and neon-20 in the Venus atmosphere are much higher than those of the corresponding gases in Earth's atmosphere, although the abundance of radiogenic argon-40 is apparently similar for both planets. The lower atmosphere of Venus includes significant concentrations of various gaseous sulfur compounds. The inlet leak to the mass spectrometer was temporarily blocked by an apparently liquid component of the Venus clouds during passage through the dense cloud layer. Analysis of gases released during the evaporation of the droplets shows the presence of water vapor to some compound or compounds of sulfur.     

40Ar-39Ar Dating of the Manson Impact Structure: A Cretaceous-Tertiary Boundary Crater Candidate

The mineralogy of shocked mineral and lithic grains in the Cretaceous-Tertiary (K-T) boundary claystone worldwide is most consistent with a bolide impact on a continent. Both the concentrations and sizes of these shocked grains are greatest in the western interior of North America. These data suggest that the Manson impact structure in north-central Iowa is a viable candidate for the K-T boundary impact event. Argon-40-argon-39 age spectrum dating of shocked microcline from the crystalline central uplift of the Manson impact structure indicates that there was severe argon-40 loss at 65.7 +/- 1.0 million years ago, an age that is indistinguishable from that of the K-T boundary, within the limits of analytical precision.     

Lunar atmosphere as a source of argon-40 and other lunar surface elements

The lunar atmosphere is the likely source of excess argon-40 in lunar surface material; about 8.5 percent of the argon-40 released into the lunar atmosphere will be implanted in the surface material by photoionization and subsequent interaction with fields in the solar wind. The atmosphere is also likely to be the source of other unexpected surface elements or of solar wind elements that impact from non-solar wind directions.     

Mechanisms of Argon Retention in Clays Revealed by Laser 40Ar-39Ar Dating

A method for dating clays is important for studies of weathering, diagenesis, hydrocarbon migration, and the formation of major metalliferous deposits. However, many attempts have produced imprecise or inaccurate results. Data from shales show that, contrary to expectations, the (40)Ar-(39)Ar dating technique can be successfully used to determine the diagenetic age of ancient sediments because (39)Ar losses during irradiation are controlled by release from low retentivity sites in illite equivalent to those that have lost radiogenic (40)Ar in nature, rather than by direct recoil as is generally assumed.     

Age and Duration of Weathering by 40K-40Ar and 40Ar/39Ar Analysis of Potassium-Manganese Oxides

Supergene cryptomelane [K(1-2)(Mn(3+)Mn(4+))(8)O(16). chiH(2)O] samples from deeply weathered pegmatites in southeastern Brazil subjected to (40)K-(40)Ar and (40)Ar/(39)Ar analysis yielded (40)K-(40)Ar dates ranging from 10.1 +/- 0.5 to 5.6 +/- 0.2 Ma (million years ago). Laser-probe (40)Ar/(39)Ar step-heating of the two most disparate samples yielded plateau dates of 9.94 +/- 0.05 and 5.59 +/- 0.10 Ma, corresponding, within 2 sigma, to the (40)K-(40)Ar dates. The results imply that deep weathering profiles along the eastern Brazilian margin do not reflect present climatic conditions but are the result of a long-term process that was already advanced by the late Miocene. Weathering ages predate pulses of continental sedimentation along the eastern Brazilian margin and suggest that there was a time lag between weathering and erosion processes and sedimentation processes.     

Major and trace elements and cosmic-ray produced radioisotopes in lunar samples

Analytical data for 42 major and trace elements were mostly obtained by a combination of instrumental and radiochemical neutron activation analyses using both thermal and 14-million-electronvolt neutrons. Excesses of nitrogen and chlorine in the fines, compared with the rocks, are attributed to the solar wind. A striking similarity for contents of seven elements in lunar metal and metal from the calcium-rich achondrite Juvinas was noted. Fractional dissolution was used to separate five radionuclides produced by cosmic-ray bombardment in the fines and rock 57-40. Results for argon-39 from the reaction potassium-39 (n,p), and for argon-37, from the reaction calcium-40 (n,a), seem to require a neutron spectrum conitaining more neutrons below 2 million electronvolts than the evaporation spectrum or that given by Arnold, Honda, and Lal (1) or a strong time dependence for the neutron flux.     

Composition and structure of the venus atmosphere: results from pioneer venus

Results from the Pioneer Venus sounder probe neutral mass spectrometer indicate that there is no difference in the isotopic ratios of carbon and oxygen between Venus and Earth to within +/- 5 percent. The mixing ratio of nitrogen is 3.5(+3)(-2) percent with an isotopic ratio within 20 percent of that of Earth. The ratio of argon-36 to argon-40 is 85 percent, and the ratio of argon-38 to argon-36 is 20 percent. The mixing ratios of argon-36 and argon-40 are approximately 40 and 50 parts per million, respectively, with an error of about a factor of 2 (mainly toward a lesser amount) resulting from uncertainty in the response of the ion pump to rare gases. Hydrogen chloride cannot account for more than a few percent of the 36 mass peak, and therefore the large excess of primordial argon is a reasonable conclusion. The ratio of neon-20 to argon-36 of 0.5 +/- 0.3 is definitely terrestrial in character rather than solar. These results indicate that there is a large excess of all primordial noble gases on Venus relative to Earth. There appears to be a considerably higher abundance of sulfur compounds below 20 kilometers than in or above the main cloud layer. The 32 and 60 mass peaks show a sharp increase below 22 kilometers, indicating the possible production of sulfur and carbon oxysulfide (COS) at the expense of sulfur dioxide.     

40Ar/39Ar Dating of the Brunhes-Matuyama Geomagnetic Field Reversal

Magnetostratigraphic studies are widely used in conjunction with the geomagnetic polarity time scale (GPTS) to date events in the range 0 to 5 million years ago. A critical tie point on the GPTS is the potassium-argon age of the most recent (Brunhes-Matuyama) geomagnetic field reversal. Astronomical values for the forcing frequencies observed in the oxygen isotope record in Ocean Drilling Project site 677 suggest that the age of this last reversal is 780 ka (thousand years ago), whereas the potassium-argon-based estimate is 730 ka. Results from 4039; Ar incremental heating studies on a series of lavas from Maui that straddle the Brunhes-Matuyama reversal give an age of 783 + 11 ka, in agreement with the astronomically derived value. The astronomically based technique appears to be a viable tool for dating young sedimentary sequences.     

Vesicle-Specific Noble Gas Analyses of "Popping Rock": Implications for Primordial Noble Gases in Earth

Gases trapped in individual vesicles in the volatile-rich basaltic glass "popping rock" were found to have the same carbon dioxide, helium-4, and argon-40 composition, but a variable 40Ar/36Ar ratio ( approximately 4000 to >/=40,000). The argon-36 is probably surface-adsorbed atmospheric argon; any mantle argon-36 trapped in the vesicles cannot be distinguished from an atmospheric contaminant. Consequently the 40Ar/36Ar ratios and 3He/36Ar ratios (1.45) determined are minimum estimates of the upper mantle composition. Heavy noble gas relative abundances in the mantle resemble solar noble gas abundance patterns, and a solar origin may be common to all primordial mantle noble gases.     

Composition of the atmosphere at the surface of Mars: detection of argon-36 and preliminary analysis

The composition of the martian atmosphere was determined by the mass spectrometer in the molecular analysis experiment. The presence of argon and nitrogen was confirmed and a value of 1 to 2750 +/- 500 for the ratio of argon-36 to argon-40 was established. A preliminary interpretation of these results suggests that Mars had a slightly more massive atmosphere in the past, but that much less total outgassing has occurred on Mars than on Earth.     

Early miocene subglacial basalts, the East antarctic ice sheet, and uplift of the transantarctic mountains

Subglacially erupted volcanic rocks from Mount Early and Sheridan Bluff, Antarctica, yield whole-rock potassium-argon dates and argon-40/argon-39 release spectra of Early Miocene age. Field associations suggest the existence of the East Antarctic ice sheet and significant uplift of the Transantarctic Mountains by that time.     

40Ar/39Ar Age of Cretaceous-Tertiary Boundary Tektites from Haiti

(40)Ar/(39)Ar dating of tektites discovered recently in Cretaceous-Tertiary (K-T) boundary marine sedimentary rocks on Haiti indicates that the K-T boundary and impact event are coeval at 64.5 +/- 0.1 million years ago. Sanidine from a bentonite that lies directly above the K-T boundary in continental, coal-bearing, sedimentary rocks of Montana was also dated and has a (40)Ar/(39)Ar age of 64.6 +/- 0.2 million years ago, which is indistinguishable statistically from the age of the tektites.     

Rare gas isotopes in hawaiian ultramafic nodules and volcanic rocks: constraint on genetic relationships

Differences in the rare gas isotopic ratios, especially the ratios of helium-3 to helium-4 and of argon-40 to argon-36, in Hawaiian ultramafic nodules and phenocrysts in volcanic rocks indicate that the nodules and phenocrysts were derived from different sources. The isotopic ratios in ultramafic nodules are similar to those in oceanic tholeiites. The phenocrysts seem to have formed in equilibrium with source materials richer in primordial components than those of the oceanic tholeiites. Mixing between the sources is quite likely.     

Iron meteorites with low cosmic ray exposure ages

Analysis of argon-38 and argon-39 produced by cosmic rays in four iron meteorites gives normal amounts of the radioactive product argon-39 and abnormally low amounts of stable argon-38. This indicates that these meteorites were exposed to cosmic rays for unusually short periods of time. These exposure times are one or two orders of magnitude shorter than those for the average iron meteorite, and they overlap the periods found for chondrites. It is suggested that perhaps 20 percent of the iron meteorites have similarly short exposure periods.     

Martian gases in an antarctic meteorite?

Significant abundances of trapped argon, krypton, and xenon have been measured in shock-altered phases of the achondritic meteorite Elephant Moraine 79001 from Antarctica. The relative elemental abundances, the high ratios of argon-40 to argon-36 (>/= 2000), and the high ratios of xenon-129 to xenon-132 (>/= 2.0) of the trapped gas more closely resemble Viking data for the martian atmosphere than data for noble gas components typically found in meteorites. These findings support earlier suggestions, made on the basis of geochemical evidence, that shergottites and related rare meteorites may have originated from the planet Mars.     

Ages of crystalline rocks from fra mauro

Crystallization ages for six rocks from Fra Mauro have been measured by the argon-40-argon-39 method. All six rocks give an age of 3.77 +/- 0.15 x 10(9) years, which is the same as for fragmental rocks from this site. It is concluded that the Imbrium event and the crystallization of a significant portion of the pre-Imbrian basalts were essentially contemporaneous.     

Venus Thermosphere: In situ Composition Measurements, the Temperature Profile, and the Homopause Altitude

The neutral mass spectrometer on board the Pioneer Venus multiprobe bus measured composition and structral parameters of the dayside Venus upper atmosphere on 9 December 1978. Carbon dioxide and helium number densities were 6 x 10(6) and 5 x 10(6) per cubic centimeter, respectively, at an altitude of 150 kilometers. The mixing ratios of both argon-36 and argon-40 were approximately 80 parts per million at an altitude of 135 kilometers. The exospheric temperature from 160 to 170 kilometers was 285 +/- 10 K. The helium homopause was found at an altitude of about 137 kilometers.     

Age and origin of carlsbad cavern and related caves from 40Ar/39Ar of alunite

40Ar/39Ar dating of fine-grained alunite that formed during cave genesis provides ages of formation for the Big Room level of Carlsbad Cavern [4.0 to 3.9 million years ago (Ma)], the upper level of Lechuguilla Cave (6.0 to 5.7 Ma), and three other hypogene caves (11.3 to 6.0 Ma) in the Guadalupe Mountains of New Mexico. Alunite ages increase and are strongly correlative with cave elevations, which indicates an 1100-meter decline in the water table, apparently related to tectonic uplift and tilting, from 11.3 Ma to the present. 40Ar/39Ar dating studies of the hypogene caves have the potential to help resolve late Cenozoic climatic, speleologic, and tectonic questions.