化肥和饲料添加剂生产磷流动特征研究

磷是作物和畜禽生长必需的营养元素,同时也是不可再生资源。为了提高农牧业生产力,80%左右的磷矿石用于生产磷肥与磷饲料添加剂,因此提高磷肥和磷饲料添加剂生产效率至关重要。然而关于磷肥和磷饲料添加剂"采矿—选矿—磷酸—磷肥/磷饲料添加剂"整个链条的磷流动特征和各个环节效率的定量研究却很少。本研究通过企业实地调研,建立企业流动数据库,利用物质流分析的方法扩展了NUFER(NUtrient flows in Food chains,Environment and Resources use)模型的磷肥和饲料磷添加剂生产模块。以我国某大型磷化工企业为例,定量揭示磷化工企业"采矿—选矿—磷酸—磷肥/磷饲料添加剂"整个链条磷流动特征、损失和利用效率;分析各种磷肥和饲料添加剂产品生产磷流动、利用效率和磷足迹;并利用情景分析提出提高磷利用效率的策略和优化潜力。结果表明:2015年该企业利用含3.902?106 t P2O5的自然矿石,生产了2.426?106 t(折纯P2O5,下同)磷复肥和磷饲料添加剂,其中磷酸二铵和磷酸一铵是最主要的产品,分别为156万t和54万t。磷酸二铵、磷酸一铵、重过磷酸钙、磷酸一二钙、普通过磷酸钙、复合肥、硫肥和磷酸二氢钾产品的生产效率分别为98%、98%、93%、95%、91%、99%、98%和91%,整个生产链条的生产效率为80%。大多数的磷资源在矿石加工部门损失掉,占磷损失量的51%;其次是矿石开采部门(25%)和磷酸生产部门(14%)。通过提高生产效率和废弃物利用率,磷资源损失预计可以减少42%。研究企业的磷利用效率在国内已达先进水平,但仍有提升潜力。     

Response of interspecific and sativa upland rices to Mali phosphate rock and soluble phosphate fertilizer

In West Africa, two-thirds of upland rice is grown on acidic phosphorus (P)-deficient soils. Phosphorus is one of the most limiting-nutrients affecting crop productivity. A three-year field experiment was conducted on a Ferralsol in Côte d'Ivoire to study the response of four interspecific rice cultivars and a sativa (control cultivar) to Tilemsi phosphate rock (PR) and soluble triple superphosphate (TSP) fertilizer. PR was applied at 0, 150, 300, and 450 kg ha^?1 P once in the first year and residual effects were measured in the following years. TSP (0, 50, 100 and 150 kg ha^?1 P) was applied yearly. More significant yield increasing (38%) was observed in the second year. Annual application of 50 kg P ha^?1 as TSP or a one-time application of 150 kg P ha^?1 as PR was the optimum rate for the production of all cultivars. Higher rates of P from TSP (100 and 150 kg P ha^?1) gave 2–3 times greater residual P in soil than the optimum rate, inducing no further response of rice. Two interspecific cultivars were identified as the most acid- and low P-tolerant cultivars for improving rice production in West Africa humid forest zone.     

Ameliorative Effects of Potassium Phosphate on Salt‐Stressed Pepper and Cucumber

Abstract

Bell pepper (Capsicum annuum cv. Urfa Isoto) and cucumber (Cucumis sativus cv. Beith Alpha F1) were grown in pots containing field soil to investigate the effects of supplementary potassium phosphate applied to the root zone of salt‐stressed plants. Treatments were (1) control: soil alone (C); (2) salt treatment: C plus 3.5 g NaCl kg^?1 soil (C + S); and (3) supplementary potassium phosphate: C + S plus supplementary 136 or 272 mg KH₂PO₄ kg^?1 soil (C + S + KP). Plants grown in saline treatment produced less dry matter, fruit yield, and chlorophyll than those in the control. Supplementary 136 or 272 mg KH₂PO₄ kg^?1 soil resulted in increases in dry matter, fruit yield, and chlorophyll concentrations compared to salt‐stressed (C + S) treatment. Membrane permeability in leaf cells (as assessed by electrolyte leakage from leaves) was impaired by NaCl application. Supplementary KH₂PO₄ reduced electrolyte leakage especially at the higher rate. Sodium (Na) concentration in plant tissues increased in leaves and roots in the NaCl treatment. Concentrations of potassium (K) and Phosphorus (P) in leaves were lowered in salt treatment and almost fully restored by supplementary KH₂PO₄ at 272 mg kg^?1 soil. These results clearly show that supplementary KH₂PO₄ can partly mitigate the adverse effects of high salinity on both fruit yield and whole plant biomass in pepper and cucumber plants.     

Agronomic effectiveness of partially acidulated phosphate rock fertilizers in an allophanic soil at near‐neutral pH

Abstract

The agronomic effectiveness of five partially acidulated phosphate rocks (PAPRs) and an unground phosphate rock (PR) were compared against single superphosphate (SSP) in a glasshouse experiment using a high phosphorus (P) retention soil at a near‐neutral pH (pH 6.5), and corn (Zea mays L.) as the test crop. The PAPRs were prepared by acidulating unground North Carolina PR with either phosphoric or sulphuric acid (expressed as Phos‐PAPR and SA‐PAPR, respectively) and at three levels of acidulation (20, 33, and 50%). The relative agronomic effectiveness (RAE) and substitution value (SV) of the test fertilizers, calculated with respect to SSP using the standard “vertical”; and “horizontal”; comparisons, showed that 50% phosphoric acidulated PAPR performed as effectively as SSP whereas the other fertilizers were less effective. The PR treatment showed a small yield response. The dry matter yield and P uptake were linearly related to water‐soluble P of the fertilizers up to 66% of total P and there was no advantage in acidulating fertilizers above this level of water‐soluble P using reactive PR. Whereas very little of the directly‐applied PR dissolved (3.4% of PR applied), PR applied as a component of PAPRs dissolved up to 22%. The dissolved proportion of added PR component increased with increasing water‐soluble P content of the fertilizer. The results suggest a greater efficiency of PAPR than SSP as a P supplier to plants.     

Not All Phosphate Fertilizers Immobilize Lead in Soils

The effects of six phosphate (P) fertilizers in mobilizing and immobilizing water-soluble lead (Pb) were determined in a contaminated soil (Alfisol from Shaoxing) from China and four Australian soils (an Oxisol from Twonsville Queensland and three South Australian soils from Cooke Plains (Typic Palexeralf)), Inman Valley (Vertisol), and Two Wells (Natric Palexeralf). The fertilizers tested were single superphosphate (SSP), triple superphosphate (TSP), monoammonium phosphate (MAP), diammonium phosphate (DAP), monocalcium phosphate (MCP), and dicalcium phosphate (DCP) to produce an initial P concentration of 1,000 mg/L. The Chinese soil contained 16,397 mg/kg total Pb, but the Australian soils were uncontaminated. The four Australian soils were each spiked with 1,000 mg Pb/kg soil (as Pb(NO₃)₂) and incubated for a month. Single superphosphate treatments decreased total soluble Pb in soil solution to 2–14 % of those of the nil-P (0P) treatment in the four Pb-spiked soils and to 48 % in the Chinese Pb-contaminated soil. The DAP treatment followed by the MAP treatment greatly increased the total soluble Pb in soil solution up to 135–500 % of the 0P treatment, except in the Two Wells soil. MCP could decrease the total soluble Pb in Cooke Plains, Inman Valley, Shaoxing, and Two Wells soils while increase it in the Queensland soil; DCP decreased the total soluble Pb in Cooke Plains and Queensland soils while increased it in the Shaoxing and Inman Valley soils. There were close relationships between the total soluble Pb, total soluble Al, and total soluble Fe in the water extracts of each. Soluble Al and Fe ions in soil solution increased soluble Pb concentrations. We conclude that not all phosphate fertilizers immobilize Pb in soils equally well. SSP and TSP are excellent Pb-immobilizing fertilizers, while MAP and DAP are strong Pb-mobilizing fertilizers. MCP and DCP are either Pb-immobilizing fertilizers or Pb-mobilizing fertilizers depending on their reactions with individual soils.     

Simultaneous Dynamics and Kinetics of Soil Phosphorus Under Different Fertilizer Systems During Two-Growth Seasons of Maize

This study investigated phosphorus (P) dynamics and kinetics in calcareous soil under inorganic, organic, and integrated (inorganic+organic) fertilizer systems during two growing seasons of maize in two soil depths (0–0.15 and 0.15–0.30 m). A field experiment was conducted with 150, 300, and 400 kg ha^?1 triple superphosphate (TSP), 7.5 and 15.0 ton ha^?1 (on dry matter basis) farmyard manure (FYM), and integrated systems. In order to analyze Olsen P, soil samples were collected in 30-day-intervals after planting. The results showed that at the end of the two growing seasons of maize, the lowest magnitudes of Olsen P_0–0.15 m were 6.0, 6.8, 7.4, and 7.6 mg kg^?1 for the control, 7.5 FYM, 15 FYM, and 150 TSP, respectively. The highest magnitudes of Olsen P_0–0.15 m were 12.4, 11.5, 11.4, and 11.1 mg kg^?1 for 300 TSP+15 FYM, 400 TSP+7.5 FYM, 400 TSP+15 FYM, and 300 TSP+7.5 FYM, respectively. The same trends were observed for Olsen P_{0.15–0.30 m}. Heterogeneous diffusion model demonstrated that Elovich equation could best describe the experimental data (mean; R² = 0.98, SE = 0.29). The highest P supply rates (PSR) were 4.73, 3.91, and 3.86 mg kg^?1day^?1 (days after application) for 400 TSP, 400 TSP+15 FYM, and 300 TSP, respectively. The models of P supply capacity of soil could estimate P supply of soil under different fertilizer systems (R² = 0.84–0.95). The present study improved the understanding of the capacity and rate of P supply by considering P uptake by grain maize. Fertilizer recommendations depend on the accessibility of fertilizer types suggested to help choose the best fertilizer systems.     

Rock phosphate-P enhances biomass and nitrogen accumulation by legumes in upland crop production systems in humid West Africa

Experiments were conducted during 1996–1998 in screen house and in the field in the humid forest zone of Côte d’Ivoire, to evaluate the effects of phosphorus (P) from phosphate rock (PR) on the performance of the root nodulating legume Crotalaria micans grown for 8 weeks. The experimental soils were acid Ultisols with <4 mg/kg extractable Bray-1 P. Tilemsi PR from Mali and triple superphosphate (TSP) were applied at 60 kg P ha^?1 (screen house) and 90 kg P ha^?1 (field) to the legume. Legume N-fixed (BNF) was estimated by the ¹⁵N-isotope dilution and δ ¹⁵N natural abundance methods, using Cassia obtusifolia L. as a non-fixing legume reference plant. Without P supply, and under the field conditions, C. micans produced less than 1 tonne of biomass and accumulated 29 kg N/ha. The application of PR-P enhanced legume N by about fourfold over the unfertilised control. There was no significant difference between the effects of TSP and PR. Phosphorus application mainly affected the total amount of N accumulated rather than the percentage derived from the atmosphere (%N dfa) per se. Furthermore, the cumulative effects of PR-P on the performance of C. micans greatly improved with time in the screen house. This study confirms that Tilemsi PR is an agronomically effective source of P for short-duration legume green manure (GM) even in the first year of its application to acid P-deficient soils in the West African humid zone.     

Biological P cycling is influenced by the form of P fertilizer in an Oxisol

Phosphate rock (PR) is an alternative fertilizer to increase the P content of P-deficient weathered soils. We evaluated the effects of fertilizer form on indicators of biological cycling of P using an on-farm trial on a Rhodic Kandiudox in western Kenya. Treatment plots were sampled after 13 cropping seasons of P applications as Minjingu phosphate rock (PR) or as triple super phosphate (?TSP) (50 kg P ha^?1 season^?1), as well as a P-unfertilized control (0 kg P ha^?1 season^?1). Soils (0–15 and 15–30 cm) were analyzed for microbial biomass P (P_mic), activities of acid phosphomonoesterase, alkaline phosphomonoesterase, and phosphodiesterase, and sequentially extractable P fractions. P additions as Minjingu PR yielded 299% greater P_mic than TSP at 0–15-cm depth despite similar labile P concentrations in the two P fertilization treatments and stimulated activities of acid phosphomonoesterase (+39%). When added in the soluble form of TSP, a greater percentage of total soil P was present in mineral-bound forms (+33% Fe- and Al-associated P). Higher soil pH under Minjingu PR (pH 5.35) versus TSP (pH 5.02) and the P-unfertilized treatment (pH 4.69) at 0–15-cm depth reflected a liming effect of Minjingu PR. The form of P fertilizer can influence biological P cycling in weathered soils, potentially improving P availability under Minjingu PR relative to TSP via enhanced microbial biomass P and enzymatic drivers of P cycling.     

Agronomic Efficiency of Two Types of Lime and Phosphate Fertilizer Sources in Brazilian Cerrado Soils Cultivated with Soybean

With the increase in phosphate fertilizer prices, there is a need to find lower-cost alternatives that are as efficient as soluble sources such as single (SSP) and triple superphosphate (TSP). In Brazil’s northern and northeastern regions, there are reserves of igneous rocks with low solubility containing high concentrations of total phosphorus (P) that can be used to produce fertilizers, such as thermalphosphates. To assess the efficiency of sources of P and two types of lime on soybean yield, a field experiment was carried out in an area with dystrophic Red Latosol (Oxisol) in a Cerrado region in the southern part of Maranhão State. The experimental design was randomized blocks in a 2 × 3 × 4 factorial scheme, with four replicates. The treatments were two types of lime [calcitic (CL) (<5 dag kg^?1 of MgO) and dolomitic (DL) (>13 dag kg^?1 of MgO)], three phosphate fertilizer sources [triple superphosphate (TSP), “Yoorin” thermalphosphate (YT), and experimental thermalphosphate (ET)], and four rates of phosphorus pentoxide (P₂O₅; 0, 100, 200, and 300 kg ha^?1). After 2 years of cultivation, the application of DL resulted in greater soybean yields than the application of CL. The two lime types influenced the pH, carbon (C), calcium (Ca), and magnesium (Mg) concentrations as well as the Ca/Mg, Ca/K, and Mg/K ratios in the soil. With respect to sources of P, the YT applied in the soil with DL produced an agronomic efficiency index (AEI) similar to that of TSP, whereas in the soil with CL, the TSP, YT, and ET were similar, with maximum technical efficiency (MTE) under both conditions starting at 230 kg ha^?1 of P₂O₅. The critical concentration of available phosphorus (P) in the soil (Mehlich-1 extractant) for cultivation of soybean under the climate and soil conditions studied was between 5.0 and 6.0 mg kg^?1.     

Phosphorus Sources and Rates Associated with Nitrogen Fertilization in Mombasa Grass Yield

Nitrogen (N) and phosphorus (P) deficiency is one of the important causes of degradation of cultivated pasture under tropical conditions. The aim of this study was to evaluate phosphate rates and sources, and N rates on the concentration and uptake of N and P, and shoot dry mass (SDM) yield of Megathyrsus maximum grass cv Mombasa in an Ultisol. The trial was carried out in a greenhouse in pots with 4.0 dm^?3 of soil. The experiment was arranged in a completely randomized design with four replicates. The 3 × 3 × 3 factorial treatments consisted of phosphorus sources [reactive rock phosphate from Morocco (RPM), reactive rock phosphate from Algeria (RPA) and triple superphosphate (TSP)], three phosphorus rates (0, 150, and 300 mg kg^?1), and three N rates (0, 250, and 500 mg kg^?1). The SDM and tillering of Mombasa grass were significantly influenced with the TSP, RPM, and RPA application associated with N fertilization. The RPM, RPA, and TSP met the nutritional demands of Mombasa grass. The three P sources showed the same effect on the total N uptake by Mombasa grass. The P use efficiency (PUE) when fertilizer-P sources were added alone by Mombasa grass was <12% of the added P, and PUE decreased as follows: TSP > RPA > RPM. When P and N-fertilizer were added together, the fertilizer-N use efficiency (NUE) was 62%. The reactive phosphate (RPM and RPA) is an efficient P sources for Mombasa grass, but requiring higher rate of application compared to TSP source.     

Comparison of phosphate rock and triple superphosphate on a phosphorus‐deficient Kenyan soil

Abstract

Soil phosphorus (P) deficiency is a constraint to crop production in many regions of sub‐Saharan Africa, which could be overcome through use of either soluble P fertilizer or sufficiently reactive phosphate rock (PR). A field study was conducted with corn (Zea mays L.) for three growing seasons (18 months) on a P‐deficient, acid soil in Kenya to compare a soluble P source (triple superphosphate, TSP) and relatively reactive Minjingu PR from Tanzania. In the 18 months following application of 250 kg P ha^‐1, bicarbonate extractable inorganic soil P (P_i) was higher for application of TSP than PR, but Pi extracted with a mixed anion‐cation resin was comparable for TSP and PR. Inorganic P extracted by 0.1M NaOH, without prior extraction of resin and bicarbonate P_i, decreased during the 18 months following TSP application, but increased following PR application. After 18 months, about 7% of the added PR‐P remained as Ca‐bound P that was extracted with 1M HCl. The 1M HCl extractable P., however, underestimated residual PR‐P that gradually dissolved and supplied plant‐available P, as indicated by recovery of <40% of PR‐P added to soil in laboratory incubations even though PR solubility in HCl was >90%. Minjingu PR was an effective source of P for corn. Corn yields were comparable for TSP and PR, and the relative agronomic effectiveness of PR averaged 107% in Season 1 and 79% in Season 3. Anion resin and mixed anion‐cation resin appeared to be superior to bicarbonate and NaOH as a soil P test for use with both TSP‐ and PR‐treated soils.     

Agronomic Evaluation of Phosphorus Sources in Lowland Rice Production

Phosphorus (P) deficiency is one of the most yield-limiting factors in lowland rice production on Brazilian Inceptisol. The objective of this study was to evaluate eight P sources for lowland rice production. The P sources were simple superphosphate (SSP), polymer-coated simple superphosphate (PSSP), ammoniated simple superphosphate (ASSP), polymer-coated ammoniated simple superphosphate (PASSP), triple superphosphate (TSP), polymer-coated triple superphosphate (PTSP), monoammonium phosphate (MAP), and polymer-coated monoammonium phosphate (PMAP). These P sources were applied in four rates (i.e., 50, 100 200, and 400 mg P kg^?1) + one control treatment (0 mg P kg^?1). Plant height, straw yield, grain yield, panicle number, and root dry weight were significantly increased in a quadratic fashion with increasing P levels from 0 to 400 mg kg^?1 of all the P sources evaluated. However, overall maximum root length and P-use efficiency were significantly less at greater P levels. Based on regression equation, maximum plant height was obtained with 262 mg P kg, maximum straw yield was obtained with 263 mg P kg^?1, maximum grain yield was obtained with 273 mg P kg^?1, and maximum panicle density was obtained with 273 mg P kg^?1. Plant growth and yield components had significant positive association with grain yield, except maximum root length. Based on grain yield and average P rate of maximum grain yield, which is 273 mg kg^?1, P sources were classified for P-use efficiency in the order of PSSP = TSP > PTSP > PASSP > SSP > MAP > ASSP. Soil chemical properties [pH; P; potassium (K); calcium (Ca); magnesium (Mg); hydrogen (H) + aluminum (Al); cation exchange capacity (CEC); base saturation; Ca, Mg, and K saturation; acidity saturation; Ca/Mg, Ca/K, and Mg/K ratios] changed significantly with the addition of different P treatments.     

Unacidulated and partially acidulated Phosphate Rock as P sources in an acid Ultisol in the forest zone of southeastern Nigeria

The relative agronomic effectiveness (RAE) of phosphate rock (PR) and its 50% partially acidulatet form (PAPR) (less soluble P sources) relative to single superphosphate (SSP) and diammonium phosphate (DAP) (soluble sources) was studied in a two year field trial with maize in an acid Ultisol in the forest zone of southeastern Nigeria. All the P sources increased top growth, grain, and stover yields over the control. The RAE of PR relative to SSP was lower in the first year (25 and 38% for dry matter (DM) and grain yield (GY) respectively) compared to the second (64 and 58% for DM and GY respectively). Partial acidulation increased the yields by 17 and 7% for DM and GY, respectively, in the first year but not in the second. The RAE of PR and PAPR relative to DAP followed the same trend. The response curves of DM, and GY to rates of applied P showed that lower grain yields were produced in the first compared to the second year. The soluble and less soluble sources built up the Bray 1 extractable P to levels adequate for maize production in the agroecological zone.     

Comparative Effects of Rock Phosphates on Arbuscular Mycorrhizal Colonization of Trifolium pratense L.

Abstract

The effect of five rock phosphates with different solubility (from Algeria, North Florida, North Carolina, Senegal, and Morocco) and that of single superphosphate (SSP) alone or with lime was investigated on the root colonization of red clover with indigenous arbuscular mycorrhizal fungi (AMF). In a pot experiment, the phosphorus (P) sources were applied at four rates (0, 100, 400, and 1600 mg total P₂O₅ kg^?1 dry soil) to an acidic sandy soil (Nyírlugos) and to an acidic clay loam soil (Ragály). The arbuscule content of the roots was more sensitive to various rock phosphates than the infection frequency. No mycorrhizal colonization of roots was observed in the Nyírlugos soil at the 1600 mg P₂O₅ kg^?1 level of SSP or in either soil at the 1600 mg P₂O₅ kg^?1 level of SSP+lime, indicating that the mycorrhizal dependency of the host was eliminated by the highest soluble P concentrations in the soil.     

Response of wheat to foliar phosphorus treatments under field and high temperature regimes

Potassium phosphate (KH₂PO₄) is applied commonly in dilute foliar sprays to wheat (Triticum aestivum L.) in China. Yield responses to foliar P sources have also been reported for several crop species in other countries. Experiments were conducted to determine efficacy of four P sources and four rates of KH₂PO₄ as foliar treatments on wheat under field conditions and KH₂PO₄ under two controlled temperature regimes. Grain yields were increased most by KH₂PO₄ followed by β‐glycerophosphate and tripolyphosphate; only phytic acid was ineffective. All rates of 1 to 4 kg ha^‐1 KH₂PO₄ increased grain yields. Foliar KH₂PO₄ applications increased grain weight early under low controlled temperatures, but did not affect final grain weight under either temperature regime. Beneficial effects of foliar P treatments were associated with increased plant P content, which may have increased cell sugar content and protected membranes. Although preliminary results are favorable, additional research is needed to determine optimum methods and conditions for treating wheat with foliar P sources.     

Agronomic Effectiveness of Partially Acidulated Phosphate Rock

Laboratorial incubation and field experiments were conducted on soils ranging in texture from sandy loam to clay and in pH from 3.6 to 9.0 to determine the agronomic effectiveness of single superphosphate (SSP).fused magnesium phosphate(FMP) and partially acidulated phosphate rock(PAPR) on 8 field crops.The results showed that the pattern of available P released from SSP was fixing-releasing-fixing-steady state,while that of PAPR was shortly fixing-slowly releasing-fixing steady state.And the PAPR,SSP and FMP were equally effective as judged by yield Puptake by phants and extractable P in soils after crop harvesting,The PAPR used as basal fertilizer was more effective than that as top dressing,and its residual effect was also obvious.     

Sorption of Phosphorus from Swine,Dairy, and Poultry Manures

In most phosphorus (P) sorption studies, P is added as an inorganic salt to a predefined background solution such as calcium chloride (CaCl₂) or potassium chloride (KCl); however, in many regions, the application of P to agricultural fields is in the form of animal manure. The purpose of this study, therefore, was to compare the sorption behavior of dissolved reactive P (DRP) in monopotassium phosphate (KH₂PO₄)–amended CaCl₂ and KCl solutions with sorption behavior of DRP in three different animal manure extracts. Phosphorus single‐point isotherms (PSI) were conducted on eight soils with the following solutions: KH₂PO₄‐amended 0.01 M CaCl₂ solution, KH₂PO₄‐amended 0.03 M KCl solution, water‐extracted dairy manure, water‐extracted poultry litter, and swine lagoon effluent. The PSI values for the dairy manure extract were significantly lower than the CaCl₂ solution for all eight soils and lower than the KCl solution for six soils. The PSI values were significantly higher, on the other hand, for poultry litter extract and swine effluent than the inorganic solutions in four and five of the soils, respectively. Our observations that the sorption of DRP in manure solutions differs significantly from that of KH₂PO₄‐amended CaCl₂ and KCl solutions indicates that manure application rates based on sorption data collected from inorganic P salt experiments may be inaccurate.     

Phosphate fertilizer enhancing soil erosion: effects and mechanisms in a variably charged soil

Purpose

The extensive application of phosphate fertilizers could produce a series of environmental problems by adsorbing on the surface of soil particle and migrating into water during soil erosion. Therefore, this study is to explore the effects of phosphate on soil aggregate stability and soil erosion and to analyze the mechanisms of phosphate enhancing soil erosion from the scope of soil charge density, electric field, and particle interaction.

Materials and methods

A variable charged soil (0–20 cm) was pre-treated firstly by KCl, K₂HPO₄, and KH₂PO₄, respectively. Under the conditions of KCl, K₂HPO₄, and KH₂PO₄ solutions with concentrations of 0.0001, 0.001, 0.01, 0.1, and 1 mol L^?1, (1) the amounts of soil particle transport and erosion intensities were measured using rainfall simulation with electrolyte solutions instead of rainwater; (2) the aggregate stabilities were measured by weighing the particles and micro-aggregates of <2, 5, and 10 μm after soil aggregate breakdown in electrolyte solutions; and (3) the zeta potentials of soil particles were measured in electrolyte solutions.

Results and discussion

The application of K₂HPO₄ and KH₂PO₄ in soil strongly enhanced soil aggregate breakdown and soil erosion, while in KCl application, soil aggregates were stable and erosion did not occur. Moreover, the intensities of soil aggregate breakdown and soil erosion for K₂HPO₄ application were much stronger than that for KH₂PO₄ application. Phosphate, especially K₂HPO₄, strongly increased surface negative charge density of soil particles and thus increased the electrostatic repulsive pressure between adjacent soil particles in aggregates, and as a result, the soil erosion intensity increased. However, the surface charge density was not increased by the increased pH, specific adsorption, and dispersion force adsorption but possibly attributed to a non-classic induction force adsorption arising from the anionic non-classic polarization in the strong electric field around soil particle surface.

Conclusions

The application of phosphate decreased aggregate stability and stimulated soil erosion through increasing charge density of particle surface by a new non-classic induction adsorption of phosphate.

     

Organic Acids and Diffusive Flux of Organic and Inorganic Phosphorus in Sandy-Loam and Clayey Latosols

This study evaluated the effects of organic acids on the diffusive flux of phosphorus (DFP) along time. Treatments were a factorial 2?×?2?×?2?×?2?×?5 design: two soils (clayey Red Latosol and a sandy-loam Red-Yellow Latosol), two organic acids (citric acid, CA, and humic acid, HA), and two phosphorus (P) sources [monopotassium phosphate (KH₂PO₄) and inositol hexaphosphate (IHP)] either with or without heating (100 °C) of the soil. The soil plus treatments, in all combinations, were placed in contact with an anion exchange resin and the P in the resin was measured after 2, 4, 6, 10, and 15 days. The DFP was greater when the soils were treated with CA than when treated with HA. Citric acid was more effective in increasing the DFP from KH₂PO₄, whereas HA was the organic ligand that promoted a larger DFP when the source was IHP.     

Introduction of composted rock phosphate and poultry manure enhances winter wheat phosphorus use efficiency,grain yield and soil quality

This field study evaluates the integrated impact of poultry manure (PM), rock phosphate (RP), composted rock phosphate (CRP) and single super phosphate (SSP) on the growth, yield, and phosphorus use efficiency (PUE) of winter wheat and their effect on postharvest soil characteristics. The seven treatments were as follows: T₁ = control; T₂ = SSP full; T₃ = PM full; T₄ = RP full; T₅ = CRP full; T₆ = 50% SSP + 50% CRP (50:50); T₇ = 50% PM + 50% CRP (50:50) at a recommended P rate of 90 kg ha^?1. The combined treatment with PM + CRP produced the highest straw yield of 3582 kg ha^?1, grain yield of 2226 kg ha^?1, P uptake of 21.3 kg ha^?1, and PUE of 18%. The postharvest soil organic carbon, total nitrogen and soil available phosphorus were sig-nificantly higher in integrated treatments.