共查询到19条相似文献,搜索用时 296 毫秒
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聚丙烯与木纤维的复合研究 总被引:3,自引:1,他引:3
通过检测以木纤维和聚丙烯为原料制造的木塑复合材料的抗拉强度,研究了木纤维和聚丙烯的复合性能,并分析了木纤维与聚丙烯的质量比、马来酸酐改性聚丙烯及偶联剂对复合材料抗拉强度的影响.试验结果表明,当聚丙烯与木纤维的混合比为10∶3、偶联剂加入量约为聚丙烯质量的3%~5%时,木塑复合材料的抗拉性能最佳. 相似文献
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以废旧高密度聚乙烯(HDPE)、竹粉(BF)为原料,马来酸酐接枝聚乙烯(MAH-g-PE)作为偶联剂,通过混炼、平板热压成型制备BF/HDPE复合材料。研究通过改变偶联剂的添加量(0%,2%,5%,8%)来检测产品的吸湿、吸水性、力学强度等指标,结果显示:MAH-g-PE能明显改善BF/HDPE复合材料的吸湿、吸水性能,以及提高产品的力学性能,当添加量为5%时,样品显示了最低的吸湿、吸水率,静曲强度与弹性模量分别提高60%和52%,拉伸强度与抗冲击强度分别增长48%和72%。红外光潜(VrIR)检测证实添加MAH-g-PE后,游离羟基与马来酸酐之间发生了酯化反应。 相似文献
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采用一步法连续挤出技术将杨木针状纤维与高密度聚乙烯(HDPE)进行熔融复合制备木塑复合材料(NF-WPC).用正交试验法分析纤维尺寸、纤维添加量、偶联剂含量和润滑剂含量4个因子对NF-WPC力学性能影响的显著性;用扫描电子显微镜观察分析NF-WPC中木纤维与HDPE的界面结合状况;提出优化的工艺配方并与相同木材含量的木粉/HDPE复合材料进行对比研究.结果表明:针状木纤维的含量对NF_WPC冲击强度影响显著,对弯曲性能和拉伸性能的影响高度显著;偶联剂马来酸酐接枝聚乙烯(MAPE)的添加量对NF_WPC的拉伸强度、断裂伸长率和冲击强度影响显著;在本文的试验范围内,木纤维尺寸和润滑剂石蜡的含量对NF-WPC力学性能的影响不显著.确定的优化工艺配方为:木纤维长度为3~4mm、长径比为8~11,木纤维含量60%,MAPE含量4%,石蜡含量0.3%;采用优化工艺制备的NF_WPC的弯曲强度、弯曲模量、拉伸强度、拉伸模量和冲击强度分别为58.7 MPa、3.0 GPa、39.6 MPa、4.0 GPa和12.7 kJ·m-2.除冲击韧性略低外,用优化工艺配方制备的NF_WPC其他力学性能均高于用同比例木粉制备的木塑复合材料. 相似文献
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研究了亚麻纤维(flaxfiber,FF)的含量和马来酸酐接枝聚丙烯(MAH-g-PP)对聚丙烯/亚麻纤维(PP/FF)复合材料各项性能的影响,通过扫描电镜研究了复合材料的界面结构.结果表明:随着FF含量增大,复合材料拉伸强度、硬度和热变形温度提高;添加MAH-g-PP提高了复合材料力学性能和热稳定性,降低了复合材料吸水性. 相似文献
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该文探讨了亚麻纤维对木材-聚丙烯(PP)复合材料力学性能的增强,尝试调节亚麻的添加量,对比亚麻纤维含量对复合材料的增强效果。并介绍了亚麻纤维增强木材-聚丙烯复合材料的挤出成型工艺流程。发现随着亚麻含量的增加,木材-聚丙烯复合材料的力学性能有先升后降的趋势,即亚麻纤维对木粉-聚丙烯复合材料有一定的增强效果;由本实验数据分析得出亚麻含量为50%时,复合材料的冲击强度、拉伸强度最大,亚麻含量为30%时,复合材料的弯曲强度最大。 相似文献
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YANG Wen-bin LI Jian LIU Yi-xing 《林业研究》2005,16(3):245-246
Three kinds of composites (fiber/Polypropylene, fiber/Polyethelene, and fiber/Polystyrene) were made by using hot pressing process for substrate of floorboard and the properties of each kind of composites were tested. MORs of PP/wood fiber, PS/fiber, and PE/fiber composites with coupling agent added were raised by 18.4%, 37.1%, and 42%. respectively, compared to those without coupling agent. Among the three kinds of fiber/plastic composites, fiber/PP composite has best mechanical properties, and it can meet quality standard of eligible grade product and come up to the excellent grade products of China when the coupling agent is added. The performance of composite made of PE/fiber or PS/fiber can exceed qualified product grade only with coupling agent added. 相似文献
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添加丙纶纤维及其改性处理对木塑复合材料性能的影响 总被引:3,自引:0,他引:3
就木塑纤维复合材料组分中添加丙纶纤维和对丙纶纤维进行改性预处理,改性剂的种类及改性剂的添加方式等引起材料物理力学性能和成网性能、模压性能的变化进行了研究。试验表明:添加丙纶纤维有助于改善材料的成网性能,使之成为具有良好模压性能的材料;对丙纶纤维进行改性的预处理可提高复合材料的物理力学性能;改性剂添加到木纤维中的工艺过程比对丙纶纤维进行预处理的工艺过程简单,并可以达到对丙纶纤维进行预处理的相同效果。 相似文献
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热塑性聚合物之间的熔融共混改性和木材纤维与热塑性聚合物之间的复合,加入偶联剂均可提高复合材料的润湿性,对材料的相容有利;在偶联剂加入量相同的情况下,增加木材纤维的用量可以加速材料的润湿速度,有利于提高材料的润湿性;在热塑性聚合物用量一定的前提下,改变加入的增强材料的形状,对材料润湿性有影响,木材纤维可以提高复合材料的润湿性. 相似文献
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Rashmi Kumari Hirokazu Ito Masahiro Takatani Miho Uchiyama Tadashi Okamoto 《Journal of Wood Science》2007,53(6):470-480
Although wood/cellulose-plastic composites (WPC) of low wood/cellulose content have been more accepted worldwide and are promoted
as low-maintenance, high-durability building products, composites containing high wood/cellulose content are not yet developed
on an industrial scale. In this study, flow properties, mechanical properties, and water absorption properties of the compounds
of cellulose microfiber/polypropylene (PP) and maleic anhydride-grafted polypropylene (MAPP) were investigated to understand
effects of the high cellulose content and the dimensions of the cellulose microfiber. The molding processes studied included
compression, injection, and extrusion. It was found that fluidity is not only dependent on resin content but also on the dimension
of the filler; fluidity of the compound declined with increased fiber length with the same resin content. Dispersion of the
composite was monitored by charge-coupled device (CCD) microscope. Increasing the plastic content in the cellulose-plastic
formulation improved the strength of mold in addition to the bond development between resin and filler, and the tangle of
fibers. The processing mode affected the physicomechanical properties of the cellulosic plastic. Compression-molded samples
exhibited the lowest modulus of rupture (MOR) and modulus of elasticity (MOE) and the highest water absorption, while samples
that were injection-molded exhibited the highest MOR (70 MPa) and MOE (7 GPa) and low water absorption (2%). 相似文献
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Kouichi SETOYAMA 《中国林业科技(英文版)》2002,(4)
The effect of wood species (Chinese fir and Poplar), wood fiber content (10%, 25%, 40%) and wood fiber sizes (16 to 32 mesh, 32-65 mesh, above 65 mesh) on the properties of the wood fiber-Polypropylene composites were studied in this paper. The results indicate that the effect of wood fiber content and size in composite were more important than that of chosen wood species. Compared with polypropylene without wood fiber, the flexural strength of the composites increased when adding wood fiber into polypropylene, but the tensile and unnotched charpy impact strength decreased. And the above strength decreased with the wood fiber content increasing. When the wood fiber size becoming smaller (in higher mesh), the strength increased. In the comparison of wood species, the properties of composite using Chinese fir wood were better than that of Poplar, but not significant. The dynamic mechanical properties of the composites and PP were also tested and analyzed in this paper. 相似文献
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SEBS-g-MAH和原位接枝MAH对木粉/废旧塑料混合物复合材料力学性能的影响研究 总被引:1,自引:0,他引:1
由聚丙烯(PP)、高密度聚乙烯(HDPE)和聚苯乙烯(PS)组成的混合废旧塑料与木粉经高速混合机混合后,采用双螺杆/单螺杆串联挤出机组制备了木粉/混合废旧塑料复合材料。探讨了马来酸酐接枝苯乙烯-乙烯/丁烯-苯乙烯嵌段共聚物(SEBS-g-MAH)和原位接枝马来酸酐(MAH)对木粉/混合废旧塑料复合材料力学性能的影响。结果表明,与使用MAH和DCP的原位反应共混相比,SEBS-g-MAH显著提高了复合材料的抗冲击性能,但对拉伸和弯曲性能的改善不如原位反应共混显著。总的来说,混合废旧塑料制备的复合材料的力学性能要低于纯塑料混合物制备的复合材料,尤其是拉伸断裂伸长率。微观形态研究表明,添加SEBS-g-MAH和原位接枝MAH均可提高木粉与塑料混合物之间的界面相容性,但与添加SEBS-g-MAH相比,原位接枝MAH能更好的改善PP、HDPE、PS与木粉之间的界面结合。原位接枝MAH可被看作是一种改善木粉与塑料混合物间界面相容性的有效途径。此外,采用动态力学分析(DMA)进一步表征了复合材料的储能模量和阻尼因子。 相似文献
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QIN Te-fu HUANG Luo-hua LI Gai-yun 《林业研究》2005,16(3):241-244
对以铝酸酯为偶联剂对木粉进行表面改性处理后制备的木粉/聚丙烯复合材料的力学性能和形态学特征进行了研究。结果表明:铝酸酯偶联剂可以增加木塑复合材料的抗冲击强度,但会对复合材料的抗拉强度和抗弯强度造成负面的影响。对木塑复合材料的动态力学性能和微分扫描热量分析研究表明,以铝酸酯作为偶联剂,对木塑复合材料的储存模量和损失模量有少许增加,同时可降低材料的熔点和熔解热。利用扫描电镜观察木塑复合材料的木材与塑料界面发现,经铝酸酯处理过的木材与聚丙烯复合界面之间具有更好的相容性。这些研究结果表明,在木塑复合材料制造过程中利用廉价的铝酸酯作为木材化学改性剂,对改善复合材料的性质同样起作良好的作用。图6 表2 参16。 相似文献