Soil as a sink for atmospheric carbon monoxide

The rate of carbon monoxide oxidation by soil increased with increasing carbon monoxide concentration in the gas phase, in line with Michaelis-Menten kinetics. Rates of carbon monoxide oxidation were determined for 20 soils at 0 degrees , 10 degrees , 20 degrees , and 30 degrees C. The observed oxidation rates were used to calculate a global soil uptake rate of atmospheric carbon monoxide of 4.1 x 10(14) grams per year, which is slightly less than the amount of carbon monoxide believed to be produced annually as a result of fossil fuel combustion.     

Recent changes in atmospheric carbon monoxide

Measurements of carbon monoxide (CO) in air samples collected from 27 locations between 71 degrees N and 41 degrees S show that atmospheric levels of this gas have decreased worldwide over the past 2 to 5 years. During this period, CO decreased at nearly a constant rate in the high northern latitudes. In contrast, in the tropics an abrupt decrease occurred beginning at the end of 1991. In the Northern Hemisphere, CO decreased at a spatially and temporally averaged rate of 7.3 (+/-0.9) parts per billion per year (6.1 percent per year) from June 1990 to June 1993, whereas in the Southern Hemisphere, CO decreased 4.2 (+/-0.5) parts per billion per year (7.0 percent per year). This recent change is opposite a long-term trend of a 1 to 2 percent per year increase inferred from measurements made in the Northern Hemisphere during the past 30 years.     

Carbon monoxide: residence time in the atmosphere

A lower limit of 0.1 year for the residence time of carbon monIoxide in the atmosphere is derived from radiocarbon measurements. The action of certain microorganisms and atmospheric photochemical reactions are possible mechanisms for the removal of carbon monoxide. This value can be compared with 2.7 years, a value deduced from estimated rates of carbon monoxide production and global measurements of atmospheric concentrations of carbon monoxide.     

Role of seasonality in the evolution of climate during the last 100 million years

A simple climate model has been used to calculate the effect of past changes in the land-sea distribution on the seasonal cycle of temperatures during the last 100 million years. Modeled summer temperatures decreased over Greenland by more than 10 degrees C and over Antarctica by 5 degrees to 8 degrees C. For the last 80 million years, this thermal response is comparable in magnitude to estimated atmospheric carbon dioxide effects. Analysis of paleontological data provides some support for the proposed hypothesis that large changes due to seasonality may have sometimes resulted in an ice-free state due to high summer temperature rather than year-round warmth. Such "cool" non-glacials may have prevailed for as much as one-third of the last 100 million years.     

Climate impact of increasing atmospheric carbon dioxide

The global temperature rose by 0.2 degrees C between the middle 1960's and 1980, yielding a warming of 0.4 degrees C in the past century. This temperature increase is consistent with the calculated greenhouse effect due to measured increases of atmospheric carbon dioxide. Variations of volcanic aerosols and possibly solar luminosity appear to be primary causes of observed fluctuations about the mean trend of increasing temperature. It is shown that the anthropogenic carbon dioxide warming should emerge from the noise level of natural climate variability by the end of the century, and there is a high probability of warming in the 1980's. Potential effects on climate in the 21st century include the creation of drought-prone regions in North America and central Asia as part of a shifting of climatic zones, erosion of the West Antarctic ice sheet with a consequent worldwide rise in sea level, and opening of the fabled Northwest Passage.     

Summer ice and carbon dioxide

The extent of Antarctic pack ice in the summer, as charted from satellite imagery, decreased by 2.5 million square kilometers between 1973 and 1980. The U.S. Navy and Russian atlases and whaling and research ship reports from the 1930's indicate that summer ice conditions earlier in this century were heavier than the current average. Surface air temperatures along the seasonally shifting belt of melting snow between 55 degrees and 80 degrees N during spring and summer were higher in 1974 to 1978 than in 1934 to 1938. The observed departures in the two hemispheres qualitatively agree with the predicted impact of an increase in atmospheric carbon dioxide. However, since it is not known to, what extent the changes in snow and ice cover and in temperature can be explained by the natural variability of the climate system or by other processes unrelated to carbon dioxide, a cause-and-effect relation cannot yet be established.     

全球变化研究热点——碳循环

40多年来,全世界的科研工作者已经在碳循环领域的各个方面做了大量的工作.本文总结了全球碳循环研究的最新进展,着重介绍了大气CO2浓度的变化及增长趋势,陆地生态系统和海洋对于大气CO2浓度变化及由此而引起的气候变化的反馈及其研究现状.同时,对许多固碳措施和技术方法也作了阐述.目前全球碳循环研究已经达到了系统集成的高度,因此集成研究将是21世纪碳循环研究的发展趋势.     

Transient climate response to increasing atmospheric carbon dioxide

The ocean's role in the delayed response of climate to increasing atmospheric carbon dioxide has been studied by means of a detailed three-dimensional climate model. A near-equilibrium state is perturbed by a fourfold, stepfunction increase in atmospheric carbon dioxide. The rise in the sea surface temperature was initially much more rapid in the tropics than at high latitudes. However, the fractional response, as normalized on the basis of the total difference between the high carbon dioxide and normal carbon dioxide climates, becomes almost uniform at all latitudes after 25 years. Because of the influence of a more rapid response over continents, the normalized response of the zonally averaged surface air temperature is faster and becomes nearly uniform with respect to latitude after only 10 years.     

温室效应对棉铃虫发生和危害的影响

就温室效应所引起的气候变化对棉铃虫发生的影响作了评述和讨论。当大气中ＣＯ＿２浓度倍增时，估计我国平均气温将升高２．６９℃。气候变暖将会导致棉铃虫发育速度加快，存活率和繁殖力提高；棉铃虫在全国四大棉区年发生世代数将普遍增加１代，此外，还会影响棉铃虫的滞育率和越冬基数，棉铃虫越冬界限将向北推移。气候变暖所引起的我国降水格局的改变也会影响棉铃虫的种群数量。     

Rising atmospheric CO2 reduces sequestration of root-derived soil carbon

Forests have a key role as carbon sinks, which could potentially mitigate the continuing increase in atmospheric carbon dioxide concentration and associated climate change. We show that carbon dioxide enrichment, although causing short-term growth stimulation in a range of European tree species, also leads to an increase in soil microbial respiration and a marked decline in sequestration of root-derived carbon in the soil. These findings indicate that, should similar processes operate in forest ecosystems, the size of the annual terrestrial carbon sink may be substantially reduced, resulting in a positive feedback on the rate of increase in atmospheric carbon dioxide concentration.     

Northern hemisphere controls on tropical southeast African climate during the past 60,000 years

The processes that control climate in the tropics are poorly understood. We applied compound-specific hydrogen isotopes (deltaD) and the TEX(86) (tetraether index of 86 carbon atoms) temperature proxy to sediment cores from Lake Tanganyika to independently reconstruct precipitation and temperature variations during the past 60,000 years. Tanganyika temperatures follow Northern Hemisphere insolation and indicate that warming in tropical southeast Africa during the last glacial termination began to increase approximately 3000 years before atmospheric carbon dioxide concentrations. deltaD data show that this region experienced abrupt changes in hydrology coeval with orbital and millennial-scale events recorded in Northern Hemisphere monsoonal climate records. This implies that precipitation in tropical southeast Africa is more strongly controlled by changes in Indian Ocean sea surface temperatures and the winter Indian monsoon than by migration of the Intertropical Convergence Zone.     

Identification of widespread pollution in the southern hemisphere deduced from satellite analyses

Vertical profiles of ozone obtained from ozonesondes in Brazzaville, Congo (4 degrees S, 15 degrees E), and Ascension Island (8 degrees S, 15 degrees W) show that large quantities of tropospheric ozone are present over southern Africa and the adjacent eastern tropical South Atlantic Ocean. The origin of this pollution is widespread biomass burning in Africa. These measurements support satellite-derived tropospheric ozone data that demonstrate that ozone originating from this region is transported throughout most of the Southern Hemisphere. Seasonally high levels of carbon monoxide and methane observed at middle- and high-latitude stations in Africa, Australia, and Antarctica likely reflect the effects of this distant biomass burning. These data suggest that even the most remote regions on this planet may be significantly more polluted than previously believed.     

Transient floral change and rapid global warming at the Paleocene-Eocene boundary

Rapid global warming of 5 degrees to 10 degrees C during the Paleocene-Eocene Thermal Maximum (PETM) coincided with major turnover in vertebrate faunas, but previous studies have found little floral change. Plant fossils discovered in Wyoming, United States, show that PETM floras were a mixture of native and migrant lineages and that plant range shifts were large and rapid (occurring within 10,000 years). Floral composition and leaf shape and size suggest that climate warmed by approximately 5 degrees C during the PETM and that precipitation was low early in the event and increased later. Floral response to warming and/or increased atmospheric CO2 during the PETM was comparable in rate and magnitude to that seen in postglacial floras and to the predicted effects of anthropogenic carbon release and climate change on future vegetation.     

Saturation of the southern ocean CO2 sink due to recent climate change

Based on observed atmospheric carbon dioxide (CO2) concentration and an inverse method, we estimate that the Southern Ocean sink of CO2 has weakened between 1981 and 2004 by 0.08 petagrams of carbon per year per decade relative to the trend expected from the large increase in atmospheric CO2. We attribute this weakening to the observed increase in Southern Ocean winds resulting from human activities, which is projected to continue in the future. Consequences include a reduction of the efficiency of the Southern Ocean sink of CO2 in the short term (about 25 years) and possibly a higher level of stabilization of atmospheric CO2 on a multicentury time scale.     

Air pollution and climate-forcing impacts of a global hydrogen economy

If today's surface traffic fleet were powered entirely by hydrogen fuel cell technology, anthropogenic emissions of the ozone precursors nitrogen oxide (NOx) and carbon monoxide could be reduced by up to 50%, leading to significant improvements in air quality throughout the Northern Hemisphere. Model simulations of such a scenario predict a decrease in global OH and an increased lifetime of methane, caused primarily by the reduction of the NOx emissions. The sign of the change in climate forcing caused by carbon dioxide and methane depends on the technology used to generate the molecular hydrogen. A possible rise in atmospheric hydrogen concentrations is unlikely to cause significant perturbations of the climate system.     

Carbon monoxide on jupiter and implications for atmospheric convection

A study of the equilibrium and disequilibrium thermochemistry of the recently discovered carbon monoxide on Jupiter suggests that the presence of this gas in the visible atmosphere is a direct result of very rapid upward mixing from levels in the deep atmosphere where the temperature is about 1100 degrees K and where carbon monoxide is thermodynamically much more stable. As a consequence the observed carbon monoxide mixing ratio is a sensitive function of the vertical eddy mixing coefficient. We infer a value for this latter coefficient which is about three to four orders of magnitude greater than that in the earth's troposphere. This result directly supports existing structural and dynamical theories implying very rapid convection in the deep Jovian atmosphere, driven by an internal heat source.     

Climate response times: dependence on climate sensitivity and ocean mixing

The factors that determine climate response times were investigated with simple models and scaling statements. The response times are particularly sensitive to (i) the amount that the climate response is amplified by feedbacks and (ii) the representation of ocean mixing. If equilibrium climate sensitivity is 3 degrees C or greater for a doubling of the carbon dioxide concentration, then most of the expected warming attributable to trace gases added to the atmosphere by man probably has not yet occurred. This yet to be realized warming calls into question a policy of "wait and see" regarding the issue of how to deal with increasing atmospheric carbon dioxide and other trace gases.     

Simulation of recent global temperature trends

Observations show that global average tropospheric temperatures have been rising during the past century, with the most recent portion of record showing a sharp rise since the mid-1970s. This study shows that the most recent portion of the global temperature record (1970 to 1992) can be closely reproduced by atmospheric models forced only with observed ocean surface temperatures. In agreement with a diverse suite of controversial observational evidence from the past 40 years, the upward trend in simulated tropospheric temperatures is caused by an enhancement of the tropical hydrologic cycle driven by increasing tropical ocean temperatures. Although it is possible that the observed behavior is due to natural climate variability, there is disquieting similarity between these model results, observed climate trends in recent decades, and the early expressions of the climatic response to increased atmospheric carbon dioxide in numerical simulations.     

Composition and structure of the martian upper atmosphere: analysis of results from viking

Densities for carbon dioxide measured by the upper atmospheric mass spectrometers on Viking 1 and Viking 2 are analyzed to yield height profiles for the temperature of the martian atmosphere between 120 and 200 kilometers. Densities for nitrogen and argon are used to derive vertical profiles for the eddy diffusion coefficient over the same height range. The upper atmosphere of Mars is surprisingly cold with average temperatures for both Viking 1 and Viking 2 of less than 200 degrees K, and there is significant vertical structure. Model calculations are presented and shown to be in good agreement with measured concentrations of carbon monoxide, oxygen, and nitric oxide.     

Dynamics of carbon monoxide binding by heme proteins

Rebinding of carbon monoxide to myoglobin and to cytochrome P-450 after removal by a light flash occurs down to 50 degrees K for myoglobin and 25 degrees K for cytochrome P-450 in glycerol-water solution. Above 240 degrees K the reaction is second order; between 240 degrees and 200 degrees K the rebinding becomes exponential and independent of the carbon monoxide concentration. Below 150 degrees K the reaction follows a power law and is approximately 10(3) times faster for cytochrome P-450 than for myoglobin.