CuFe2O4纳米粒子增敏Luminol-EDTA化学发光体系研究及应用

基于CuFe₂O₄纳米粒子能显著增强Luminol-EDTA体系的发光,首次建立了Luminol-EDTA-CuFe₂O₄ NPs化学发光新体系。紫外吸收光谱和化学发光光谱表明纳米CuFe₂O₄注入Luminol-EDTA体系后,未生成新发光物质,结合纳米CuFe₂O₄的特性,提出了CuFe₂O₄ NPs参与Luminol-EDTA体系可能的发光机理。研究发现芦丁能抑制Luminol-EDTA-CuFe₂O₄ NPs体系的化学发光,结合流动注射技术,将此化学发光体系应用于芦丁片中芦丁含量的测定。在优化实验条件下,芦丁浓度在2×10^-8~2×10^-5 mol/L范围内芦丁浓度的对数和相对化学发光值呈线性,芦丁浓度检出限（LOD）为1.21×10^-9 mol/L。将本方法应用于芦丁片中的芦丁含量测定,回收率为97%~102%,RSD为2.54%（c=1×10^-7mol/L,n=11）。     

不同建筑热工分区办公建筑外围护结构负荷指标影响因素权重

为研究多因素对不同热工分区办公建筑总负荷指标的综合影响,在分析了单一因素对建筑总负荷指标影响规律的基础上,采用层次分析法对分别位于哈尔滨、兰州、重庆、广州的办公建筑负荷指标进行了评价。得到了窗户传热系数K_w、玻璃遮阳系数S_c、窗墙比R在不同热工分区办公建筑总负荷指标影响因素中的权重值,并对此进行了一致性检验。结果表明：对于严寒地区的哈尔滨和寒冷地区的兰州节能建筑,各因素重要程度为R > K_w > S_c;对于夏热冬冷地区的重庆和夏热冬暖地区的广州节能建筑,各因素重要程度为S_c > R > K_w。在建筑结构优化设计中应根据各热工分区负荷影响因素的比重不同进行优先控制相应因素。     

中国便利店的照明能耗预测模型与主观评价

便利店销售额在传统零售业中增幅最高,照明在所调研样本总室内能耗中占比为43%。基于全国257家便利店的数据,探讨便利店的照明特征。采用多重线性回归方法建立照明能耗预测模型,采用因子分析方法探讨客观参数与主观评价的联系。研究表明,对便利店,考虑照明节能时需同步关注其主观评价的变化;进行照明设计时需因地制宜;照明能耗预测模型为ln y=0.479 ln x₁+ 0.248ln x₂-0.217（y为照明功率密度,x₁为单位面积照明造价,x₂为典型货架位置水平照度平均值）;顾客对照明充足度的“敏感性”比照明均匀度高;提高照度平均值有助于提高主观评价。     

SBBR反应器SND脱氮的影响因素分析及响应曲面优化

采用活性炭涂层改性悬浮填料,在连续曝气的条件下,考察了SBBR反应器脱氮性能。结果表明,SBBR反应器表现出良好的同步硝化反硝化(SND)脱氮性能,对NH₃-N和TN的去除率分别为80.7%和63.1%。典型周期内反应器同步硝化反硝化率可达82.7%。单因素试验发现,脱氮率随着曝气时间t的增加而增加,随着溶解氧质量浓度ρ_DO和填料投加量δ增大而先增大后减小。同时,以溶解氧质量浓度、填料投加量和曝气时间为考察因素,脱氮率为评价指标,采用响应曲面法建立了二次多元回归模型。通过模型求解得出最佳工况:溶解氧浓度为2.37 mg/L,填料投加量为40.10%,曝气时间为5.17 h,此时,脱氮率得到最大值为69.28%。验证试验表明,回归模型的预测值与实测值偏差率为1.57%。     

氢还原竖炉的模拟分析

利用一组物料、热量守衡式及其他有关约束关系,建立了氢还原竖炉模拟模型,可定量考察消耗量、生成量和氮气、CO兑入成分、DRI金属化率、入炉煤气温度等的关系。模拟结果表明：兑入CO可使入炉煤气量从纯氢还原的1650 N·m³左右下降到1200 N·m³左右;当CO和H₂的体积之比V（CO）/V（H₂）约为0.6时,氮气兑入量约为0,竖炉能量利用最佳;当V（CO）/V（H₂）体积比为0.3时,最佳氮气兑入成分约为11%;纯氢还原最佳氮气兑入成分约为25%;兑入氮气可以减少入炉氢气的量,但不能减少入炉气体的总量。对氢还原竖炉模拟结果可为其工艺设计、操作和节能等提供参考信息。     

含水率和颗粒级配对稍密碎石土抗剪性能及地基承载力的影响

碎石土因特殊的工程特性而被科研人员关注,但对大粒径、粉质粘土填充、稍密状态下碎石土的力学性能涉足较少。根据该类型碎石土特点及大量勘察结果配置出两种比较典型级配的稍密碎石土,通过大型直剪试验仪测定了不同含水率状态下碎石土试样的抗剪强度,绘制剪应力与水平位移的关系图,通过一元回归得出稍密碎石的抗剪强度指标c、φ值,分析了不同含水率、不同级配对稍密碎石土抗剪性能的影响。结果表明：随着含水率的增大,碎石土粘聚力总体呈减小趋势,但变化趋势具有显著的阶段性且和粉质粘土的含量有关,含水率变化对碎石土内摩擦角的影响较小。用规范推荐方法计算了该类型碎石土地基承载力,并与地方规范经验取值和勘察工程实践取值进行了对比,结果表明：含水率对地基承载力影响较大,且与碎石土填充物的粉质粘土含量有关,粉质粘土含量越高,承载力影响越大。     

碱矿渣混凝土配合比参数选择与设计方法

通过系统研究各配制参数（如：碱组分、水胶比、胶凝材料用量等）对碱矿渣混凝土28 d抗压强度的影响,深入分析了28 d抗压强度分布规律与方差间的关系。结果表明：碱矿渣混凝土28 d抗压强度符合正态分布,且与水胶比呈明显反比关系。在此基础上,提出了适用于碱矿渣混凝土的回归方程,确定了公式中回归系数α_a和α_b分别为0.796和0.897,得出了碱矿渣混凝土配合比参数选择与设计的具体方法。     

武汉与重庆典型地质结构下的地埋管换热性能

地埋管地源热泵换热器的换热性能受到不同地质结构的影响。以武汉和重庆地区的典型地质构成为边界条件,建立了三维地埋管的单孔双U管换热模型,通过模型计算,获得了两种地质条件下的地埋管换热性能,以重庆地区的地源热泵热响应测试结果以及工程运行数据出发,对模型的计算结果进行了验证,结果表明,模型吻合度较好,可以应用于工程分析。以模型为条件,进行地质结构对换热性能的影响度分析,预测了两地地埋管地源热泵的换热性能并计算得到换热器的平均换热系数分别为武汉地区K₁=1.65（W/m·K）,重庆地区K₂=1.51（W/m·K）。     

原状黄土冻融过程抗剪强度劣化机理试验分析

通过对西安Q₃原状黄土在封闭系统冻融作用下的电镜扫描和直剪试验,研究了冻融作用对原状黄土微观结构和强度的影响。试验表明：冻融过程中原状黄土微观结构发生显著变化,大颗粒集粒数量明显减少,小粒径土颗粒所占比重增加,孔隙面积比增加。进一步基于损伤力学理论,得到微观结构冻融损伤度随冻融次数增加呈指数增加趋势,反映出冻融作用一定程度上破坏黄土体的结构强度,但多次冻融后黄土体结构强度趋于稳定的残余强度。冻融过程土样表面结构发生破坏,且含水率越高,土体表面特征破坏越严重。粘聚力随冻融次数增加呈指数衰减趋势,且含水率越高,粘聚力衰减幅值和速率越小;粘聚力随含水率增加表现出线性衰减特征,且冻融后粘聚力与含水率的变化规律近似重合;内摩擦角无明显规律性变化。粘聚强度冻融损伤系数随冻融次数增加呈指数增加趋势,随含水率升高有增大趋势。基于试验数据规律性,进一步提出了原状黄土粘聚强度劣化模型,该模型经试验验证可较好描述原状黄土粘聚强度劣化规律。     

传感器网络同步态的节点故障诊断算法

首先介绍了复杂网络同步态的概念,以传感器量测数据为节点,定义了随时间动态变化的传感器网络,采用数学分析方法定量描述了传感器网络的动力学机制,给出了传感器网络同步态的数学定义、计算方法及其实际的物理含义。理论推导表明,同步态从全局角度评价传感器网络的健康程度,以量测数据距离关联性定义复杂网络的耦合矩阵A=（a_ij）_N×N,并以该耦合矩阵零特征值对应的左特征向量（ξ₁,ξ₂,...,ξ_N）来刻画传感器网络节点的局部细节信息,进而衍生出基于传感器网络同步态的节点故障诊断算法,实现传感器网络的故障诊断。实验仿真了由100个传感器组成的复杂网络,采集了在稳定运动60 s期间的的量测数据,每个量测数据长度为5 000,其中有3个传感器处于间歇增益故障状态,以此来验证基于传感器网络同步态的节点故障诊断算法的有效性。结果表明,该算法不仅可以很好地跟踪整个传感器网络的工作状态,实时监测每个传感器网络节点的故障,而且可以利用传感器网络节点故障之间的相关性有效地识别出传感器量测数据的异常是由外界量测对象的改变还是由传感器本身故障引起的。该算法为全局评估传感器网络的工作状态和监测网络节点的局部故障提供了一个新颖可行的研究思路,期望为相关领域的研究学者提供有益的参考。     

Elastic-Perfectly Plastic Solution of Tunnel Surrounding Rocks Using Mogi-Coulomb Strength Criterion

Reasonable choice of rock strength criteria is crucial for stress and displacement prediction and support design in tunnel engineering. Based on Mogi-Coulomb strength criterion and elastic-perfectly plastic model, analytical solutions of stress and displacement for surrounding rocks around a circular tunnel were derived The intermediate principal stress coefficient was used to present the intermediate principal stress effect. The results in this study were compared with the current solutions in the literatures and the influence of intermediate principal stress and shear strength parameters of surrounding rocks was discussed. The results showed extensive applicability and the Mohr-Coulomb strength criterion and Matsuoka-Nakai criterion are two special cases; when the intermediate principal stress coefficient b was equals to 0.5, the results indicated that the intermediate principal stress effect and its range for rock strength; the influence of cohesion and internal friction angle on the plastic radius and tunnel wall displacement was significant; Care should be taken to the effects of intermediate principal stress and shear strength parameter variations of surrounding rocks on tunnel design and construction.     

Dynamic Influence of Sustained Small Rainfall Infiltration on Stability of Unsaturated Soil Slope

Taking the moisture content as main control parameter of shear strength of the soil, we analyze the variational properties of moisture content and shear strength with the change of rainfall time during the small sustained rainfall infiltration, and establish the relationships between total cohesion as well as effective angle of friction and the time of sustained small rainfall infiltration into an unsaturated slope. With the rainfall infiltration, the influence area of slope expands. Through the strength reduction method based on FLAC3D, the dynamic safety factor of slope in different time and the duration time before the failure of the slope are obtained. The results show that the slope critical sliding surface is yet unsaturated during a sustained small rainfall.     

Die kohäsion ungesättigter sandböden und deren beeinglussung durch organische substanz

It is well known in soil science, that organic matter contributes considerably to the stability of soil structure. There are also many methods to determine this stabilizing effect of soil organic matter. But as a matter of fact those methods are mostly developed under chemical or colloido-chemical aspects and do only satisfy the demands of special purposes. The physical and mechanical aspects are often neglected. In this work, however, the mechanical parameter “cohesion of soils” c is selected to describe the stabilizing effect of organic matter on soil structure of sandy soils.Organic matter (black peat) was mixed with a fine sand in gravimetric proportions of 0:100, 1:100, 3:100, 5:100, 8:100. The mixtures were then wetted with distilled water and left undisturbed for a few weeks. A natural sandy soil (Haplo-humod) was also taken, part of the sample was treated with H₂O₂ to destroy the organic matter, so the stabilizing effect of organic matter could be evaluated. The cohesion of all the samples was determined with an annular shearing apparatus under a constant soil water suction between 0 and 300 cm H₂O. Results were calculated using the Coulomb equation τ = c + σ_n tan ϕ⁰, where τ shear strength, c cohesion, σ_n normal stress, and ϕ⁰ friction angle respectively. The results show,

1. 1.1. all samples have no cohesion under saturated conditions (water suction = 0 cm H₂O);
2. 2.2. with all samples the cohesion at first increases with increasing soil water suction, reaches a maximum under a soil water suction of about 40 to 70 cm H₂O, and then decreases with further increasing soil water suction;
3. 3.3. organic matter enhances the cohesion of both the artificial mixtures of sand and organic matter as well as the natural sandy soil, the increase being the higher, the higher the content of organic matter.
4. 4.4. no difference between the artificial mixtures of sand and organic matter and the natural sandy soil was found.

     

Plastic upper bound theory reliability analysis of coal gangue hills

We established the plasticity limit analysis reliability limit state equation and the reliability calculating formula for gangue hills using the JC method. This work was based on the plasticity mechanics limit analysis upper bound theory and traditional slice methods. A reliability index of gangue hill stability was derived using this equation. It was found that the safety coefficient of gangue hills derived by the limit state equation risks failure if the variability of cohesion and internal friction angle are not considered. When the variability of the strength parameters rises, the reliability theory more consistently projects practicality than the limit state equation for gangue hill stability assessment.     

Effect of Rht Alleles on the Tolerance of Wheat Grain Set to High Temperature and Drought Stress During Booting and Anthesis

Factorial pot experiments were conducted to compare the responses of GA‐sensitive and GA‐insensitive reduced height (Rht) alleles in wheat for susceptibility to heat and drought stress during booting and anthesis. Grain set (grains/spikelet) of near‐isogenic lines (NILs) was assessed following three day transfers to controlled environments imposing day temperatures (t) from 20 to 40 °C. Transfers were during booting and/or anthesis and pots maintained at field capacity (FC) or had water withheld. Logistic responses (y = c/1+e^{‐b(t ‐m)}) described declining grain set with increasing t, and t₅ was that fitted to give a 5 % reduction in grain set. Averaged over NIL, t₅ for anthesis at FC was 31.7 ± 0.47 °C (S.E.M., 26 d.f.). Drought at anthesis reduced t₅ by <2 °C. Maintaining FC at booting conferred considerable resistance to high temperatures (t₅ = 33.9 °C) but booting was particularly heat susceptible without water (t₅ = 26.5 °C). In one background (cv. Mercia), for NILs varying at the Rht‐D1 locus, there was progressive reduction in t₅ with dwarfing and reduced gibberellic acid (GA) sensitivity (Rht‐D1a, tall, 32.7 ± 0.72; Rht‐D1b, semi‐dwarf, 29.5 ± 0.85; Rht‐D1c, severe dwarf, 24.2 ± 0.72). This trend was not evident for the Rht‐B1 locus or for Rht‐D1b in an alternative background (Maris Widgeon). The GA‐sensitive severe dwarf Rht12 was more heat tolerant (t₅ = 29.4 ± 0.72) than the similarly statured GA‐insensitive Rht‐D1c. The GA‐sensitive, semidwarfing Rht8 conferred greater drought tolerance in one experiment. Despite the effects of Rht‐D1 alleles in Mercia on stress tolerance, the inconsistency of the effects over background and locus led to the conclusion that semidwarfing with GA‐insensitivity did not necessarily increase sensitivity to stress at booting and flowering. In comparison with effects of semidwarfing alleles, responses to heat stress are much more dramatically affected by water availability and the precise growth stage at which the stress is experienced by the plants.     

砂土地基上圆形浅基础三维破坏包络面的理论研究

对砂土地基上圆形浅基础在竖向荷载V、水平荷载H及力矩M复合加载条件下的承载力进行了系统的三维有限元分析。在分析中,砂土假定为纯摩擦材料,遵循基于Mohr-Coulomb破坏准则的理想弹塑性本构关系。首先,对圆形浅基础的竖向承载力进行了有限元计算, 并与滑移线解法进行了对比,两种方法所得结果比较吻合。进而探讨了砂土内摩擦角对于基础在V-H、V-M荷载平面与V-H-M三维荷载空间内的破坏包络轨迹的影响。计算结果表明,与不排水情况下软黏土地基上基础破坏包络面相比,砂土地基上圆形浅基础的破坏包络面形状有较大差异, 但V-H和V-M平面内的破坏包络面形状仍具有较好的归一化特性。基于有限元计算结果,建立了圆形浅基础在V-H-M三维荷载空间内的破坏包络面方程, 该方程可用来合理评价复合加载条件下砂土地基上圆形浅基础的整体稳定性。     

污水环境对水泥土力学性能的影响试验研究

由于多数地下水泥土工程直接与地下腐蚀性介质环境接触,必将导致水泥土材料的逐步劣化甚至失效破坏。以某市区工地附近明渠排放的污水作为侵蚀性介质,制作了不同水泥掺量的水泥土试件,通过对比试验,研究了污水环境和清水环境下不同水泥掺量、不同龄期的水泥土抗压强度和抗剪强度。结果表明,在污水或清水环境下,相同水泥掺量水泥土30 d龄期的抗压强度几乎相等,随着龄期的增加其抗压强度均逐步增大,但污水环境下其抗压强度增长的幅度明显小于清水环境,90 d后清水环境的水泥土抗压强度不再增长,而污水环境的抗压强度开始降低;污水环境和清水环境下的水泥土内摩擦角和黏聚力随龄期、水泥掺量的增加均逐步增大,污水环境下龄期90 d后的内摩擦角和黏聚力均开始降低。     

基于随机场的岩石边坡三维稳定性分析

基于随机场理论,考虑了岩石材料属性的空间变异性对岩石边坡稳定性的影响,将边坡主滑面上的摩擦系数和粘聚力视为高斯随机变量,确定了主滑面上的摩擦系数和粘聚力的均值、方差和协方差,获得了两个随机量之间的相关系数和互相关长度。在此基础上,对岩石边坡进行了三维稳定性分析,确定了岩石边坡的稳定系数和失效概率。数值计算结果表明,摩擦系数和粘聚力的空间变异性对边坡稳定性有重要影响。     

Internal CO2 Concentration as a Selection Criterion for Storage Respiration Rate in Sugarbeet

Respiration is responsible for much of the sucrose loss that occurs during sugarbeet (Beta vulgans L.) storage. Genotypes with reduced storage respiration rates would provide an efficient method for reducing sucrose losses. However, the current techniques for measuring storage respiration are not adapted easily to breeding programs. Internal CO₂ concentration has been recommended as an efficient method for measuring the respiration rate of individual sugar-beet roots in storage. This study examined the effectiveness of internal CO₂ concentration as a selection criterion for reducing respiration rate of sugarbeet during storage. Lines resulting from four cycles of divergent selection for internal CO₂ concentration were evaluated along with commercial hybrids and low internal CO₂ germplasm lines. Selection was effective in shifting internal CO₂ concentration. Relative differences in internal CO₂ concentration were consistent throughout the 3-year study. Neither the fourth-cycle selections for low nor the fourth-cycle selections for high internal CO₂ concentration were significantly different from the original population for evolved CO₂. This lack of a close relationship between internal and evolved CO₂ indicated that internal CO₂ concentration is not an effective selection criterion in a breeding program.     

Epistasis for crown disease in the oil palm (Elaeis guineensis Jacq.)

Summary The presence of crown disease (cc) in the oil palm can be masked by an intermediate gene (I _c). Presence of the gene inI _c i _c-condition results in incomplete genetic penetrance in thecc-genotypes. No penetrance is observed in theccI _c I _c-palms. The existance of theI _c-gene complicates selection work as a testcross with acci _c i _c-genotype is required to identify the genotype of the selections. This procedure requires 3 years.