Concentration and molecular weight distribution of dissolved organic carbon in a mangrove creek in the Hinchinbrook area,Australia

The concentration and molecular weight distribution of dissolved organic carbon (DOC) are reported for a mangrove creek in the Hinchinbrook area, Australia. DOC concentration ranged from 1.0mg Cl–1 near the creek mouth to 2.2mg Cl–1 at the innermost part of the creek. There was no apparent spatial trend in molecular weight distribution of DOC, with a >300gmol–1 fraction accounting for about 70% of the total in all samples. DOC concentration fluctuated between 0.5 and 1.2mg Cl–1 over one tidal cycle. The samples collected at low tide and during the rising tide were dominated by DOC of >300gmol–1 and <300gmol–1, respectively. This suggested the export of high molecular weight DOC, probably originating from litter leachates, and the import of low molecular weight DOC to the creek.     

Mangrove structure,litter and macroalgal productivity in a northern‐most forest of Florida

Rhizophora mangle L. dominated 10 overwash islands within Tampa Bay forming the northernmost mangrove forests on the west coast of Florida. The mean number of trees and basal area were 5040 trees ha^-1 and 20.5m²ha^-1, respectively. Basal areas ranged from 1.1 (Avicennia germinans (L.) Stern), to 2.6m²ha^-1 (Laguncularia racemosa Gaertner), to 16.8 (R. mangle). Cockroach Bay mangroves are small (5.8–7.0m tall) versus coastal forests of south Florida and the Caribbean. Total litter production for a 12 month period was maximal in September for fringing (7.4gdwtm^-2d^-1) and interior (8.7gdwtm^-2d^-1) areas with the two zones not being significantly different. Average litter fall (3.1gdwtm^-2d^-1) was similar to more tropical Caribbean mangals. Leaves accounted for 68 of the litter and reproductive material for 6, being similar to tropical riverine and overwash marine angiosperm communities on the Mexican coast. Although mangrove forests in Tampa Bay are small in stature and experience cold damage and occasional frosts, their litter fall is similar in biomass to that of more tropical mangals. However, their reproductive output is low based on litter fall versus more tropical mangals suggesting that the northern extension is less than optimum. Macroalgal diversity was low (10 species) as compared to Caribbean mangals. Macroalgal turf (0.8gCm^-2d^-1) and epiphyte communities of A.germinans pneumatophores (2.7gCm^-2d^-1) have productivity levels that are equal to or greater than those of Caribbean mangals.     

Preparation of liquid polyesterpolyols from glucose and its methyl derivative

Preparation of liquid polyols from d-(+)-glucose (Glc) and its derivative, methyl--d-glucoside (m-Glc), has been studied. Direct reaction of -caprolactone (CL) with Glc (CL:Glc = 2:1–5:1 in weight ratio) at 150°C using tin(II) 2-ethyl hexanoate (SnEht₂) (series A), in which melted Glc was suspended in CL, resulted in a dark-brown coloration of the reactants. The reaction was accompanied by formation of high molecular weight resins, a pH drop, production of water, and a considerable decrease in the hydroxyl value from the theoretically expected one. In the case of Glc/ethylene glycol (EG)/CL reaction system with SnEht₂ catalyst at 150°C (series B), in which the weight ratio of Glc to EG was fixed at 1:1, Glc dissolved in the EG/CL mixture, but the brown coloration of the reactant mixture still occurred. In this case, the formation of water was enhanced, but the other effects found in series A were suppressed to a considerable extent. In the m-Glc/CL/SnEht₂ reaction system (series C), in which m-Glc reacted with two to five times weight amounts of CL under the same conditions adopted in series A, development of the color, the production of high molecular weight materials and water, and the changes in pH and hydroxyl value were not observed. These results are discussed based on the chemical structural differences: Glc exists mostly in the hemiacetal form, but tautomerizes to the aldehyde, whereas m-Glc is an acetal and is protected from reversion to the aldehyde.     

Gamma radiation sensitivity of larvae and adults of the red flour beetle, <Emphasis Type="Italic">Tribolium castaneum</Emphasis> Herbst

In this study, the susceptibility of larvae and adults of Tribolium castaneum (Herbst) to gamma radiation was investigated in the laboratory in Turkey. Gamma radiation was applied at 6 dose levels between 20 and 200Gy to 13–15day-old adults and at 5 dose levels between 20 and 180Gy to 18–20day-old larvae of T. castaneum. All experiments were performed in growth chambers maintained at 27±1°C and 70±5% r.h. The larvae proved to be the more susceptible stage, survival to the adult stage being prevented by exposure of the eggs to 100Gy; the adult stage was less susceptible. LD₅₀ and LD₉₉ values were determined as 19,75 and 42,97Gy for larvae and 33,21 and 64,50Gy for adult stage, respectively. It was concluded that 100Gy is the effective dose for both larval and adult stages.     

In vitro propagation of <Emphasis Type="Italic">Oroxylum indicum</Emphasis> Vent. a medicinally important forest tree

In vitro propagation of Oroxylum indicum Vent. was carried out using cotyledonary node explants. Among the different types of cytokinins used for culture establishment, 6-benzyladenine exhibited the best response with higher concentrations (8.87µM or above) for inducing multiple shoots. Inclusion of indole-3-acetic acid (2.85µM) into 6-benzyladenine-supplemented medium triggered a high frequency of response as well as a proliferation of shoots. The best medium for proliferation was Murashige-Skoog (MS) medium with 6-benzyladenine (8.87µM) and indole-3-acetic acid (2.85µM). However, incorporation of gibberellic acid (1.44µM) was mandatory to enhance shoot elongation. Repeated subculturing of cotyledonary node and in vitro developed nodal segments in MS medium with 6-benzyladenine (4.44µM) at 4-week intervals resulted in continuous mass multiplication of shoots without any evidence of decline. Root induction was best (91.6%) when MS strength was reduced to one-quarter and combined with -naphthalene acetic acid (2.69µM) and indole-3-acetic acid (5.71µM), with a high survival rate (70–72%) of plantlets hardened in either soil rite or soil:sand:soil rite (1:1:2).     

Mangrove forest productivity and biomass accumulation in Hinchinbrook Channel,Australia

Data on stand structure and rates of photosynthesis were used to estimate net canopy carbon fixation and carbon accumulation as living biomass in mangrove forests in Hinchinbrook Channel, Australia. Total annual canopy net carbon fixation was estimated to be about 29tCha–1yr–1. This equates to about 204,000tCyr–1 for all mangrove forests in Hinchinbrook Channel. Of this, only about 12% was stored as living plant biomass. Although it is not yet possible to present a robust carbon balance for mangrove trees, the remainder is presumably lost through plant respiration, litter fall, root turnover and exudation of organic compounds from roots.     

Effect of thawing regime on growth and mortality of frozen-stored Norway spruce container seedlings planted in cold and warm soil

One-year-old frozen-stored Norway spruce (Picea abies (L.) Karst.) container seedlings were planted in a controlled environment providing an air temperature of 22°C and soil temperature of 9±1 or 18±1°C. At planting the root plugs were either frozen or had been thawing for 4 days at 9°C. During a 5-week growing period, in both cold and warm soil the root growth and height growth were less in frozen-planted seedlings than in thawed seedlings. In addition, frozen-planting delayed bud burst and increased mortality. Soil temperature, however, had no effect on bud burst or mortality. Low soil temperature retarded root growth of seedlings thawed before planting but resulted in both retarded root growth and height growth if root plugs were frozen when planted. These results indicate that planting Norway spruce seedlings with frozen root plugs constitutes a considerable risk for successful forest regeneration at soil temperatures normally prevailing in Fennoscandia in spring or early summer especially if the soil is dry at the time of the planting.     

Effects of nitrogen and phosphorus fertilization on the growth and nutrition of hybrid poplars on Vancouver Island

The effects of nitrogen (N) and phosphorus (P) rates, P source, and method of P application were tested on growth and nutrition of four clones of hybrid poplar (Populus trichocarpa Torr. & Gray×P. deltoides Bartr. ex Marsh or P. trichocarpa×P. maximowiczii A. Henry) in a plantation on Vancouver Island. Treatments were applied shortly after planting. Nitrogen (0, 500kgNha^–1) was supplied as ammonium sulfate (AS); half of the AS was added at the start of the second growing season. Phosphorus (0, 100, 200kgPha^–1) was supplied as triple super phosphate (TSP), rock phosphate (RP), or diammonium phosphate (DAP) and banded or broadcast. Over four growing seasons, stem volumes increased with AS and P additions. The effects of AS and P each were greatest when the other was also added. Volume was greater when P was applied at 100kgha^–1 than in the P control and did not significantly increase further at 200kgPha^–1. Phosphorus additions were more effective when added as TSP or DAP than when added as RP, but only in P100 and when banded. Banding increased volume when P was applied at 200kgha^–1, but increases were significant only for DAP fertilized trees. Roto-tilling associated with the banding treatment also increased volume when AS and P were not added. Rankings of clones with respect to stem volume varied with N supply and changed over time.     

Development of binderless particleboard from kenaf core using steam-injection pressing

Binderless particleboards were successfully developed from kenaf core using the steam-injection press. The effects of board density, steam pressure, and treatment time on the properties of the board were evaluated. The target board densities were relatively low, ranging from 0.40 to 0.70g/cm³. The properties [i.e., moduli of rupture (MOR) and elasticity (MOE) in both dry and wet conditions, internal bonding strength (IB), and water absorption (WA)] of the boards increased linearly with increasing board density. Steam pressure and treatment time also affected the board properties. The bending strength and IB were improved with increased steam pressure. A long steam treatment time contributed to low thickness swelling (TS) values and thus better dimensional stability. The appropriate steam pressure was 1.0MPa, and the treatment time was 10–15min. The properties for 0.55g/cm³ density boards under optimum conditions were MOR 12.6MPa, MOE 2.5GPa, IB 0.49MPa, TS 7.5%, and wet MOR 2.4MPa. Compared with the requirement of JIS 5908, 1994 for particleboard, kenaf binderless boards showed excellent IB strength but relatively poor durability.Part of this report was presented at the 19th Annual Meeting of the Japan Wood Technological Association, Tokyo, October 2001     

Compressive deformation of wood impregnated with low molecular weight phenol formaldehyde (PF) resin I: effects of pressing pressure and pressure holding

The deformation behavior of low molecular weight phenol formaldehyde (PF) resin-impregnated wood under compression in the radial direction was investigated for obtaining high-strength wood at low pressing pressures. Flat-sawn grain Japanese cedar (Cryptomeria japonica) blocks with a density of 0.34g/cm³ were treated with aqueous solution of 20% low molecular weight PF resin resulting in weight gain of 60.8%. Oven-dried specimens were compressed using hot plates fixed to a testing machine. The temperature was 150°C and the pressing speed was 5mm/min. The impregnation of PF resin caused significant softening of the cell walls resulting in collapse at low pressures. The cell wall collapse was strain-dependent and occurred at a strain of 0.05–0.06mm/mm regardless of whether the wood was treated with PF resin. Thus, pressure holding causing creep deformation of the cell walls was also effective in initiating cell wall collapse at low pressure. Utilizing a combination of low molecular weight PF resin impregnation and pressure holding at 2MPa resulted in a density increase of PF resin-treated wood from 0.45 to 1.1g/cm³. At the same time, the Youngs modulus and bending strength increased from 10GPa to 22GPa and 80MPa to 250MPa, respectively. It can be concluded that effective utilization of the collapse region of the cell wall is a desirable method for obtaining high-strength PF resin-impregnated wood at low pressing pressures.     

Nitrogen use by <Emphasis Type="Italic">Pinus densiflora</Emphasis> trees growing on a Mt. Fuji lava flow

To quantify the nitrogen (N) use by Pinus densiflora trees growing on an infertile lava surface, N pools, N requirement and N uptake through fine roots and N deposition from the atmosphere were estimated. The N requirement and the N uptake of fine roots were 55.5kgNha^–1year^–1 and 39.7kgNha^–1, respectively. Thus, the ratio of N uptake to N requirement of the fine roots was 71.5%. Including fine-root contribution, the total N requirement of the P. densiflora trees was 98.6kgNha^–1year^–1, and the total N uptake was 64.2kgNha^–1year^–1. Thus, the N uptake of the P. densiflora trees was 64.1% of the N requirement, indicating that P. densiflora trees growing on an infertile lava surface obtain some of their N from below-ground organic material layers every year and the contribution of N storage in trees for their growth is not any higher than indicated in previous reports that excluded fine-roots contribution. The wet N deposition of our research forest was only 5.8% of the N requirement of the P. densiflora trees and only 8.9% of the N uptake. Movement of the below-ground organic material layer N concentrations in the F- and L-layers coincides with needle development and fine-root growth, suggesting the possibility that P. densiflora trees extract N from the organic N of those layers for growth.     

Changes in the physical and chemical properties of six Japanese softwoods caused by lengthy smoke-heating treatment

The effects of prolonged smoke-heating treatments on wood quality were investigated. Six Japanese softwoods were smoke-heated for 100 and 200h at a temperature of 75° ± 5°C, which was recorded inside the log. After smoke heating, wood quality, including moisture content, amounts of chemical components, relative degree of crystallinity (RDC) of cellulose, and sapwood color were examined. Moisture content decreased as a result of smoke heating, especially in sapwood, leading to a uniform distribution of moisture content within a log. Almost no difference was found in the amounts of chemical components between the control woods and the woods that were smoke-heated for 100h. However, in the wood that was smoke-heated for 200h, the amounts of holocellulose decreased, suggesting that thermal deterioration and/or degradation of hemicelluloses had occurred. We assume that the increase in RDC was caused by smoke heating with the crystallization of cellulose and/or thermal degradation of hemicelluloses. Almost no differences were found in sapwood color between the control woods and the woods that were smoke-heated for 100h. In the wood that was smoke-heated for 200h, however, L*decreased, whereas a* and b* increased. As a result, E*ab, showing the total color change, increased, resulting in a deeper color. These results suggest that thermal degradation of hemicelluloses was caused by smoke heating for over 100h. Therefore, smoke heating of softwood logs using a commercial-scale kiln should not exceed 100h.     

Effects of soil solarization on nematodes in Croatia

For the first time soil solarization was investigated in Croatia both in the field and in the greenhouse in 1991, 1992, 1993 and 1994. For two months (July and August), the soil was mulched with transparent polyethylene (PE) sheets of 0.015 or 0.050mm thickness. Soil temperatures at depths of 5, 10 and 20cm were recorded daily. In order to assess nematode population densities, soil samples were analysed before mulching and at the end of the mulching treatment. The results of these experiments showed that soil solarization drastically reduced the population of plant-parasitic nematodes (Meloidogyne, Pratylenchus, Paratylenchus, Tylenchus, Tylenchorhynchus spp.) by about 97–100% at a depth of 10cm and 92–97% at a depth of 20cm in the field, while in the greenhouse, the population of plant-parasitic nematodes was reduced by about 89–100% at a depth of 10cm and 98–100% at a depth of 20cm.In the same experiments, the population of saprophytic nematodes in the field was reduced by about 86–90% at a depth of 10cm and 72–89% at a depth of 20cm. In the greenhouse, the population of saprophytic nematodes was reduced by about 87–97% at a depth of 10cm and 87–93% at a depth of 20cm. This data shows that soil solarization was less effective in the control of saprophytic nematodes, which is considered to be an advantage.     

Physiological and psychological responses to prolonged light floor-impact sounds generated by a tapping machine in a wooden house

We investigated the physiological and psychological responses of nine normal men to the prolonged light floor-impact sounds of 60dBA and 80dBA generated by a tapping machine in a two-story wooden house. Blood pressure was measured, and a sensory evaluation was also conducted using the semantic differential method. The results obtained were as follows: (1) the increase in systolic blood pressure immediately after exposure to the light floor-impact sounds depended on the level of the sounds, (2) the variations in feelings due to the prolonged light floor-impact sounds were identified by factor analysis, and (3) the subjects showed no difference in comfortable feeling for the prolonged light floor-impact sounds of 60dBA and 80dBA, but differences in the variation of the systolic blood pressure were detected.Part of this research was presented at the 47th Annual Meeting of the Japan Wood Research Society, Kochi, April 1997     

Water circulation, groundwater outflow and nutrient dynamics in Mida creek, Kenya

The relationship between physical hydrodynamic processes and nutrients dynamics was investigated in Mida creek, a groundwater influenced mangrovefringed creek in Kenya between March 1996 and May 1997. The research involved spot and timeseries measurement of nitrate–nitrite, ammonia, silicates, phosphates, salinity, temperature, sealevel as well as tidal currents at seven stations located in the front, middle and backwater zones of the creek. Groundwater level as well as total dissolved solids' concentration, salinity, temperature and nutrients' concentration were also measured once every month in shallow wells (watertable<5m) located in the upper region of the creek. Results of the study show that nutrient concentrations vary with the tide and that, though there is no river drainage, they are of the same magnitude as in mangrove creeks with substantial river runoff. The peak concentrations of NH ₄ ⁺ –N (5.45M), NO ₂ –NO ₃ (5.63M), PO ₄ ^3– –P (0.58M) and SiO ₃ ^2– –Si (81.36M) in the creek occurred during flood tide, 2–3h before high waters. The (NO ₂ ^– + NO ₃ ^– )–N concentrations declined rapidly during ebb tide, reaching the minimum levels during low water. Contribution of groundwater seepage to the net nutrients flux (particularly on nitrite–nitrates) is largest in dry seasons. The study shows that groundwater outflow sustains the mangroves during periods of severe salinity stress and nutrients deficiency in dry seasons. This is essentially by limiting salinity increase and by boosting nutrient supply in dry seasons.     

Biological performance of wood-based composites treated with a formulation of 3-iodo-2-propynyl butylcarbamate and silafluofen using supercritical carbon dioxide

Wood-based composites (medium density fiberboard, hardwood plywood, softwood plywood, particleboard, and oriented strand board) treated with a mixture formulation of 3-iodo-2-propynyl butylcarbamate (IPBC) and silafluofen using supercritical carbon dioxide as a carrier solvent were evaluated for their resistance to biological attack in a laboratory study. The formulation was pre-pared by mixing 10g of IPBC and 1g of silafluofen in ethanol solution (20ml). Treatments were conducted at 35°C/7.85MPa, 35°C/9.81MPa, and 55°C/11.77MPa with the direct introduction of 20ml of the formulation into the treatment vessel with a capacity of ca. 2000ml at a rate of 2ml/min. Laboratory tests indicated that the treatment conditions used significantly enhanced the resistance of the treated wood-based composites against fungal and termite attacks. Because no significant difference in efficacy against both biodegrading agents was noticed regardless of the treatment conditions, the treatment at 35°C/7.85MPa was thought to be the most economical in terms of energy consumption and performance of treated materials. However, the amount of biocides in a formulation must be carefully selected in accordance with the required treatment condition to ensure satisfactory performance of the treated wood-based composites against any biological agent.     

Dependence of reaction kinetics and physical and mechanical properties on the reaction systems of acetylation II: physical and mechanical properties

Acetylation of wood was carried out in acetic anhydride only, acetic anhydride/xylene 1:1 (v/v), and acetic anhydride/pyridine 4:1 (v/v) solutions. The antishrink efficiency (ASE), hygroscopic properties, vibrational properties, and bending strength were compared among the three reaction solutions. The ASE was a simple function of weight gain (WG); the equilibrium moisture content at a given WG differed among the reaction solutions. Based on this fact and the results of repeated water soaking and oven-drying tests, it was found that the bulking effect was a major factor, and that decreased hygroscopicity contributes only slightly to the dimensional stabilization by acetylation. The difference in equilibrium moisture content among reaction solutions appears more significant in block samples than wood meal, probably due to the fiber-to-fiber bonds in the former. The tendencies for change in the specific Youngs modulus and the loss tangent differed among reaction solutions, whereas in the static bending test the difference was not marked.Part of this report was represented at the 52nd Annual Meeting of the Japan Wood Research Society, Gifu, April 2002     

Effects of a nursery CO2 enriched atmosphere on the germination and seedling morphology of two Mediterranean oaks with contrasting leaf habit

The use of an enriched CO₂ atmosphere in tree nurseries has been envisaged as a promising technique to increase productivity and to obtain seedlings with a higher root/shoot ratio, an essential trait to respond to water stress in Mediterranean-type ecosystems. In that framework, we have analyzed the effects of three levels of atmospheric CO₂ concentration (350, 500 and 700ppm) on the germination rate, growth and morphology of seedlings of two Mediterranean oaks used in reforestation programs: the evergreen Quercus ilex L. and the deciduous Quercus cerrioides Wilk. et Costa. CO₂ enrichment increased the germination rate of Q. cerrioides (from 70±7 to 81±3%) while it decreased that of Q. ilex (from 71±10 to 41±12%). Seedlings of both species increased approximately 60% their total biomass in response to CO₂ enrichment but at two different CO₂ concentrations: 500ppm for Q. cerrioides and 700ppm for Q. ilex. This increase in seedlings biomass was entirely due to an augmentation of root biomass. Considering germination and biomass partitioning, an enriched CO₂ atmosphere might not be appropriate for growing Mediterranean evergreen oaks, such as Q. ilex, since it reduces acorn germination and the only gains in root biomass occur at a high concentration (700ppm). On the other hand, a moderate CO₂ enrichment (500ppm) appears as a promising nursery technique to stimulate the germination, growth and root/shoot ratio of deciduous oaks, such as Q. cerrioides.     

Interactions between the striped stem borer <Emphasis Type="Italic">Chilo suppressalis</Emphasis> (Walk.) (Lep., Pyralidae) larvae and rice plants in response to nitrogen fertilization

A screenhouse experiment was conducted to examine the damage and compensation in rice plants when injured by the striped stem borer, Chilo suppressalis (Walker), larvae at tillering stage, as well as larval survival and development of the insect at different nitrogen (N) fertilization levels. Potted plants were fertilized at late seedling stage at the rates 0, 200, 400, 600 and 800mgN/pot, respectively. More deadheads were caused as fertilization increased. Plants compensated well for injury at the fertilization concentrations of 200 and 400mgN/pot by producing new tillers, but such compensation did not take place at 600 and 800mgN/pot. Two weeks after infestation, the highest number of remaining healthy tillers was found in plants fertilized at 400mgN/pot. Larval survival varied little among the treatments 200 to 800mgN/pot. Larval weight attainment and/or developmental rate increased with increasing fertilization level from 200 to 600mgN/pot, but both declined rapidly as fertilization reached 800mgN/pot, indicating the great dependence of plant suitability on N fertilization levels. Conclusively, both the compensation response of rice plants and their suitability for C. suppressalis larvae could be significantly affected by N fertilization levels.     

Canopy cover effects on nitrogen and phosphorus status in understory vegetation in oak and pine stands

The rate of change of leaf mass, N and P levels in understory vegetation at various levels of canopy cover were measured for 2 years following canopy cover manipulations in northern red oak (Quercus rubra L.) and red pine (Pinus resinosa Ait.) stands in northern Lower Michigan, USA. Canopy cover treatments consisted of clearcut, 25% (50% during first sampling year), 75%, and uncut. Leaf mass, and N and P contents were significantly higher in the clearcut treatment than in other canopy cover treatments, except for the 25% treatment in red pine stands. Leaf N concentrations in understory vegetation were also significantly higher in the clearcut (1991, 20.8mgg^–1; 1992, 22.4mgg^–1) than in the uncut treatment (1991, 16.5mgg^–1; 1992, 16.9mgg^–1). Canopy type (northern red oak and red pine) had little influence on understory nutrient status and leaf mass. In addition, fronds of bracken ferns in all canopy cover treatments in both northern red oak and pine stands were a major sink of nutrients in the understory. The results of this study showed that partial canopy removal generally had only a minor impact on understory leaf production and nutrient status compared with clearcuts during the 2-year period following canopy removal.